1-Methylpyrrolidine - 10mM in DMSO , CAS No.120-94-5

CAS: 120-94-5 Cat. No.: M420916 Molecular Weight: 85.15 Beilstein Registry Number: 102445 EC Number: 204-438-5
AVAILABLE TO ORDER
GRADE & PURITY 10mM in DMSO
Synonyms
CAS-120-94-5 | NCGC00255880-01 | EC 204-438-5 | N-methyl pyrollidine | FT-0608097 | W-108468 | M0415 | N-methylpyrrolidin | DTXSID8042210 | NSC 65579 | N-Methyltetrahydropyrrole | AKOS015850845 | InChI=1/C5H11N/c1-6-4-2-3-5-6/h2-5H2,1H | 06509TZU6C | UNII
Storage
Store at -80°C
Shipped In
Dry ice packs + Cold packs
 ·  off list, applied to all prices below.
Size
Status
Price
Qty
1ml
M420916-1ml
1

$58.90

$69.90
Save $11.00 (15.74%)
Enter a quantity for the sizes you want to add.
🧪

Why this grade

10mM in DMSO for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Store at -80°C Ships Dry ice packs + Cold packs Check lot-specific COA for exact specifications.

📋

Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

📚

Literature proof

Cited in 40 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

1-Methylpyrrolidine is extensively used in the synthesis of pyrrolidine based ionic liquids.

Some of the other reported applications include:

• Synthesis of ionic liquid electrolytes for primary Li/CFx batteries.

• Preparation of ionic liquid as a reaction medium to carry out sulfuric acid-catalyzed conversion of alkynes to ketones.

• MCM-47, a highly crystalline ferrierite layered silicate, can be synthesized using a diquaternary ammonium salt prepared from the reaction of 1-methylpyrrolidine with 1,4-dibromobutane.

Specifications

Synonyms
CAS-120-94-5 | NCGC00255880-01 | EC 204-438-5 | N-methyl pyrollidine | FT-0608097 | W-108468 | M0415 | N-methylpyrrolidin | DTXSID8042210 | NSC 65579 | N-Methyltetrahydropyrrole | AKOS015850845 | InChI=1/C5H11N/c1-6-4-2-3-5-6/h2-5H2, 1H | 06509TZU6C | UNII
Specifications & Purity
10mM in DMSO
Storage
Store at -80°C
Shipped In
Dry ice packs + Cold packs
This product requires cold chain shipping. Ground and other economy services are not available.
Names and Identifiers
Isomeric SMILES CN1CCCC1
WGK Germany 3
RTECS UY1420500
UN Number 2924
Molecular Weight 85.15
Beilstein 102445
Reaxy-Rn 102445
Reaxys-RN_link_address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=102445&ln=

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Mechanisms of Action
Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:
Chemical and Physical Properties
SensitivityAir Sensitive
Refractive Index 1.4237-1.4257
Flash Point(°F)1.4 °F
Flash Point(°C)-21℃
Boil Point(°C)80-81°C
Melt Point(°C)-90°C
Molecular Weight85.150 g/mol
XLogP30.900
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count1
Rotatable Bond Count0
Exact Mass85.0891 Da
Monoisotopic Mass85.0891 Da
Topological Polar Surface Area3.200 Ų
Heavy Atom Count6
Formal Charge0
Complexity37.200
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
The total count of all stereochemical bonds0
Covalently-Bonded Unit Count1
Documents & Articles
Citations of This Product
References
1. Chao Ma, Xiaona Liu, Yang Hong, Nana Yan, Chenyang Nie, Jing Wang, Peng Guo, Zhongmin Liu.  (2023)  Fluoride- and Seed-Free Synthesis of Pure-Silica Zeolite Adsorbent and Matrix Using OSDA-Mismatch Approach.  Journal of the American Chemical Society,      [PMID:37877469] [10.1021/jacs.3c08484]
2. Duo Li, Xiaoli Wang, Kaishuo Han, Yaqian Sun, Ting Ren, Guohui Sun, Na Zhang, Lijiao Zhao, Rugang Zhong.  (2023)  Hypoxia and CD44 receptors dual-targeted nano-micelles with AGT-inhibitory activity for the targeting delivery of carmustine.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:37399878] [10.1016/j.ijbiomac.2023.125657]
3. Xuan Tang, Yugao Wang, Mengni Wei, Xueqin Zhang, Ye Li, Xiaomin Li, Jinping Li, Jiangfeng Yang.  (2023)  Synthesis of nanosized IM-5 zeolite and its CH4/N2 adsorption and separation.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2023.124003]
4. Jie Wei, Jin Liu, Ximan Sun, Jialin Miao, Dawei Fang.  (2023)  Transport properties and ionicity in allyl-/alkylether-based ILs and their binary systems with acetonitrile as the potential electrolytes: Correlation with interactions and structures.  JOURNAL OF MOLECULAR LIQUIDS,      [PMID:] [10.1016/j.molliq.2023.121586]
5. Yingying Zhang, Yuxin Zhang, Anlei Yi, Jie Wei, Dawei Fang.  (2023)  Volumetric Properties, Molar Surface Gibbs Energy, and Its Application of Binary Systems Containing Ether-Group Functionalized Ionic Liquid with Monohydric Alcohols.  JOURNAL OF CHEMICAL AND ENGINEERING DATA,      [PMID:] [10.1021/acs.jced.2c00677]
6. Xiaoxia Liu, Yangyang Wang, Ronghao Liu, Ping Lv, Wenfeng Xue, Jinxin Guo, Huiying Wei, Yanzhao Yang.  (2023)  Selective and Efficient Gold Extraction from E-Waste by Pyrrolidinium-Based Ionic Liquids with Various N-Substituents.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.2c05455]
7. Shenghua Du, Shuai Huang, Ning Xie, Tong Zhang, Yaoyao Xu, Xingming Ning, Pei Chen, Xinbing Chen, Zhongwei An.  (2022)  New block poly(ether sulfone) based anion exchange membranes with rigid side-chains and high-density quaternary ammonium groups for fuel cell application.  Polymer Chemistry,  13  (30): (4395-4405).  [PMID:] [10.1039/D2PY00588C]
8. Xin Kou, Yutian Ma, Congming Pan, Yong Huang, Yulai Duan, Ying Yang.  (2022)  Effects of the Cationic Structure on the Adsorption Performance of Ionic Polymers toward Au(III): an Experimental and DFT Study.  LANGMUIR,      [PMID:35512263] [10.1021/acs.langmuir.2c00482]
9. Shenghua Du, Songsong Li, Ning Xie, Yaoyao Xu, Qiang Weng, Xingming Ning, Pei Chen, Xinbing Chen, Zhongwei An.  (2022)  Development of rigid side-chain poly(ether sulfone)s based anion exchange membrane with multiple annular quaternary ammonium ion groups for fuel cells.  POLYMER,      [PMID:] [10.1016/j.polymer.2022.124919]
10. Wenjie Xiong, Zhuoheng Tu, Zengyu Yin, Xiaomin Zhang, Xingbang Hu, Youting Wu.  (2021)  Supported Ionic Liquid Gel Membranes Enhanced by Ionization Modification for Sodium Metal Batteries.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.1c02983]
11. Huixing Cao, Ji Pan, Hairong Zhu, Zhe Sun, Bowen Wang, Junliang Zhao, Feng Yan.  (2021)  Interaction Regulation Between Ionomer Binder and Catalyst: Active Triple-Phase Boundary and High Performance Catalyst Layer for Anion Exchange Membrane Fuel Cells.  Advanced Science,  (19): (2101744).  [PMID:34339101] [10.1002/advs.202101744]
12. Chenhua Shu, Faying Lai, Feng Zhu, Dan Luo.  (2020)  Optimal extractive and reductive desulfurization process using sodium borohydride in situ generated via sodium metaborate electroreduction in ionic liquid.  Chemical Engineering and Processing-Process Intensification,      [PMID:] [10.1016/j.cep.2020.107869]
13. Yang Yu, Zeyu Yang, Shujing Ren, Yanan Gao, Liqiang Zheng.  (2019)  Multifunctional hydrogel based on ionic liquid with antibacterial performance.  JOURNAL OF MOLECULAR LIQUIDS,      [PMID:] [10.1016/j.molliq.2019.112185]
14. Yuliang Jiang, Chao Wang, Jiefeng Pan, Arcadio Sotto, Jiangnan Shen.  (2019)  Constructing an internally cross-linked structure for polysulfone to improve dimensional stability and alkaline stability of high performance anion exchange membranes.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2019.02.098]
15. Sijian Li, Kaihua Yang, Zhengxi Zhang, Li Yang, Shin-ichi Hirano.  (2018)  Organic Ionic Plastic Crystal-Poly(ethylene oxide) Solid Polymer Electrolytes: Application in All-Solid-State Lithium Batteries.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.8b01964]
16. Huimin Zang, Shun Yao, Yingjie Luo, Dan Tang, Hang Song.  (2018)  Complex-precipitation using functionalized chiral ionic liquids with L-proline anion and chromatographic analysis for enantioseparation of racemic amino acids.  CHIRALITY,  30  (11): (1182-1194).  [PMID:30188593] [10.1002/chir.23011]
17. Congfei Yao, Yucui Hou, Shuhang Ren, Youan Ji, Weize Wu, Hui Liu.  (2018)  Efficient separation of phenolic compounds from model oils by dual-functionalized ionic liquids.  Chemical Engineering and Processing-Process Intensification,      [PMID:] [10.1016/j.cep.2018.04.026]
18. Yunfei Yang, Yixin Xu, Niya Ye, Dengji Zhang, Jingshuai Yang, Ronghuan He.  (2018)  Alkali Resistant Anion Exchange Membranes Based on Saturated Heterocyclic Quaternary Ammonium Cations Functionalized Poly(2,6-dimethyl-1,4-phenylene oxide)s.  JOURNAL OF THE ELECTROCHEMICAL SOCIETY,  165  (5): (F350).  [PMID:] [10.1149/2.1031805jes]
19. Yilin Wang, Yunchen Wang, Jie Su, Xiaowei Song, Wei Wan, Jihong Yu.  (2017)  Interrupted silicogermanate with 10-ring channels: synthesis and structure determination by combining rotation electron diffraction and powder X-ray diffraction.  Inorganic Chemistry Frontiers,  (10): (1654-1659).  [PMID:] [10.1039/C7QI00309A]
20. Kaisheng Yao, Zhiyong Li, Xinying Li, Weiwei Lu, Airong Xu, Hucheng Zhang, Jianji Wang.  (2017)  Tunable Synthesis of Ag Films at the Interface of Ionic Liquids and Water by Changing Cationic Structures of Ionic Liquids.  CRYSTAL GROWTH & DESIGN,      [PMID:] [10.1021/acs.cgd.6b01196]
21. Tongtong Tian, Jieqiong Qin, Yan'an Gao, Li Yu.  (2016)  Experimental and DFT studies on aggregation behavior of dodecylsulfonate-based surface active ionic liquids in water and ethylammonium nitrate.  JOURNAL OF MOLECULAR LIQUIDS,      [PMID:] [10.1016/j.molliq.2016.02.074]
22. Jessica Juweriah Ibrahim, Shurong Gao, Ahmed A. Abdeltawab, Salem S. Al-Deyab, Liang Yu, Guangren Yu, Xiaochun Chen, Xingyue Yong.  (2015)  Extractive Desulfurization of Fuel Oils with Dicyano(nitroso)methanide-based Ionic Liquids.  SEPARATION SCIENCE AND TECHNOLOGY,      [PMID:] [10.1080/01496395.2014.960051]
23. Shidong Tian, Yucui Hou, Weize Wu, Shuhang Ren, Jianguo Qian.  (2014)  Hydrophobic task-specific ionic liquids: Synthesis, properties and application for the capture of SO2.  JOURNAL OF HAZARDOUS MATERIALS,      [PMID:24998204] [10.1016/j.jhazmat.2014.06.037]
24. Chenhua Shu, Tonghua Sun, Hongbo Zhang, Jinping Jia, Ziyang Lou.  (2013)  A novel process for gasoline desulfurization based on extraction with ionic liquids and reduction by sodium borohydride.  FUEL,      [PMID:] [10.1016/j.fuel.2013.12.037]
25. Benlian Lu, Airong Xu, Jianji Wang.  (2013)  Cation does matter: how cationic structure affects the dissolution of cellulose in ionic liquids.  GREEN CHEMISTRY,  16  (3): (1326-1335).  [PMID:] [10.1039/C3GC41733F]
26. Jinglin Tan, Depeng Ma, Shengyu Feng, Changqiao Zhang.  (2012)  Effect of headgroups on the aggregation behavior of cationic silicone surfactants in aqueous solution.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2012.10.041]
27. Jingjing Jiao, Bin Dong, Huina Zhang, Yingyuan Zhao, Xiaoqing Wang, Rui Wang, Li Yu.  (2012)  Aggregation Behaviors of Dodecyl Sulfate-Based Anionic Surface Active Ionic Liquids in Water.  JOURNAL OF PHYSICAL CHEMISTRY B,      [PMID:22204280] [10.1021/jp209276c]
28. Deping Huang, Xiangtao Bai, Liqiang Zheng.  (2011)  Ultrafast Preparation of Three-Dimensional Dendritic Gold Nanostructures in Aqueous Solution and Their Applications in Catalysis and SERS.  Journal of Physical Chemistry C,      [PMID:] [10.1021/jp2037284]
29. Wenwen Yin, Xing Zhi, Yanyan Li, Jiawei Ma, Bernt Johannessen, Fangxi Xie, Mingmei Wu.  (2025)  Bimetallic Alloy Air Cathode Promoting Superoxide Formation for High-Performance Na-Air Batteries.  Small,      [PMID:40035589] [10.1002/smll.202500109]
30. Minmin Liu, Bingxi Song, Yanhui Hu, Xianglei Meng, Renzheng Jiang, Yanyan Diao, Yuting Song.  (2024)  Efficient dimerization of perfluoroolefin catalyzed by strong nucleophilic bifunctional ionic liquids.  Reaction Chemistry & Engineering,      [PMID:] [10.1039/D4RE00088A]
31. Wenwen Song, Haodong Xie, Li Liu, Xiang Ni, Yuan Xue, Yan Liu, Junwen Chen, Lei Wang, Hongjun Zhu.  (2025)  Iron-loaded pure silica -SVR zeolite for the hydroxylation of phenol.  Reaction Chemistry & Engineering,      [PMID:] [10.1039/D5RE00013K]
32. Liang You, Lujia Deng, Zhenyu Zhang, Jianhong Li, Xia Liao, Rui Yang, Xiang Ke, Rengui Xiao.  (2025)  Natural small molecule-based recoverable polymer binders for intact and efficient recycling of lithium-ion batteries.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:40117879] [10.1016/j.jcis.2025.137349]
33. Shuang Liang, Guanzhihui Wang, Likun Dong, Xiaobo Yang, Bao Zhou, Zhuoqi Duan, Zaixin Xie, Yongmao Hu.  (2024)  NiCo-MOFs derived carbon matrix composites: A promising electrode construction for high-performance supercapacitors.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2024.161602]
34. Jinjing Qiu, Qi Chen, Cheng Liu, Yueling Chen, Jionghua Wu, Kaiqiang Jing, Jimmy C. Yu, Ling Wu, Xianzhi Fu.  (2025)  Ru single atom modified DUT-67(Zr) with unsaturated Zr for high-efficiency photocatalytic nitrogen reduction.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2025.125034]
35. Xinyu Feng, Siwen Zhang, Jiazhuo Li, Yingfang Hu, Rongyuan Ge, Yaowen Shi, Yali Yao, Bosi Yin, Tianyi Ma.  (2024)  Yttrium doping stabilizes the structure of Ni3(NO3)2(OH)4 cathodes for application in advanced Ni–Zn batteries.  Nanoscale,  16  (36): (16933-16941).  [PMID:39189424] [10.1039/D4NR02011A]
36. Wenwen Yin, Jiawei Ma, Yanyan Li, Qing Cheng, Bernt Johannessen, Fangxi Xie, Mingmei Wu.  (2025)  Breaking scaling relations via Fe/Ni diatomic catalysts towards highly efficient electrocatalysts for rechargeable Na-air batteries.  Journal of Materials Chemistry A,      [PMID:] [10.1039/D5TA03806E]
37. Minjun Yin, Hongting Pu.  (2025)  Robust and self-healable polybenzimidazole membranes via Diels–Alder chain extension.  RSC Advances,  15  (42): (34861-34873).  [PMID:40995340] [10.1039/D5RA05834A]
38. Fang Hua Liu, Chen Xiao Lin, En Ning Hu, Qian Yang, Qiu Gen Zhang, Ai Mei Zhu, Qing Lin Liu.  (2018)  Anion exchange membranes with well-developed conductive channels: Effect of the functional groups.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2018.07.038]
39. Huiyao Yang, Bingxi Song, Peihong Zhang, Qijie Zhu, Fu Ding, Yao-Feng Wang, Guliang Liu, Yanyan Diao, Hongyan Wang.  (2025)  Catalytic selectivity in hexafluoropropylene trimerization using tailored nucleophilic ionic liquids.  NEW JOURNAL OF CHEMISTRY,      [PMID:] [10.1039/D5NJ00490J]
40. Chuang Zhao, Jiale Song, Yaoyang Liu, Yu Zhou, Tingting Liu, Meng Zhang, Caishan Jiao, Yang Gao, Qun-Yan Wu, Weifang Zheng.  (2026)  The Interplay of Steric hindrance and Electronic Effects in Asymmetric diglycolamides, Revealed through Their Ln(III) Coordination and Extraction Behavior.  DALTON TRANSACTIONS,      [PMID:41790049] [10.1039/D6DT00071A]
Solution Calculators
Reviews

Customer Reviews

Shall we send you a message when we have discounts available?

Remind me later

Thank you! Please check your email inbox to confirm.

Oops! Notifications are disabled.