(1R,4R,8R)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene - ≥95% , CAS No.948594-95-4

CAS: 948594-95-4 Cat. No.: R467477 Molecular Weight: 310.47

GRADE & PURITY ≥95%

Synonyms

(1R,4R,8R)-5-Benzyl-8-methoxy-1,8-dimethyl-2-(2-methylpropyl)bicyclo[2.2.2]octa-2,5-diene | W-204122 | (1R,4R,8R)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethyl-2-bicyclo[2.2.2]octa-2,5-diene | DTXSID50584825 | (1R,4R,8R)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dim

Storage

Room temperature

Overview

Description

(1R, 4R, 8R) Carreira DOLEFIN Ligand is a chiral diene ligand that can be used in:The asymmetric Rh-catalyzed arylation of alkenylheterocycles by conjugate additions with various aryl boronic acids.The enantioselective synthesis of 3,3-diarylpropanals by conjugate addition of aromatic boronic acids to cinnamaldehyde derivatives in the presence of a rhodium catalyst.The asymmetric synthesis of pyrrolizidinones by rhodium-catalyzed 1,4-addition of aryl boronic acids to pyrrolidine acceptor.Carreira DOLEFIN Ligands

Specifications

Synonyms

(1R, 4R, 8R)-5-Benzyl-8-methoxy-1, 8-dimethyl-2-(2-methylpropyl)bicyclo[2.2.2]octa-2, 5-diene | W-204122 | (1R, 4R, 8R)-5-Benzyl-2-isobutyl-8-methoxy-1, 8-dimethyl-2-bicyclo[2.2.2]octa-2, 5-diene | DTXSID50584825 | (1R, 4R, 8R)-5-Benzyl-2-isobutyl-8-methoxy-1, 8-dim

Specifications & Purity

≥95%

Storage

Room temperature

Purity

≥95%

Names and Identifiers

• Canonical Smiles: CC(C)CC1=CC2C(=CC1(CC2(C)OC)C)CC3=CC=CC=C3
• IUPAC Name: (1R,4R,8R)-5-benzyl-8-methoxy-1,8-dimethyl-2-(2-methylpropyl)bicyclo[2.2.2]octa-2,5-diene
• InChIKey: ACWLDJOHMGJACE-BHIFYINESA-N
• INCHI: 1S/C22H30O/c1-16(2)11-19-13-20-18(12-17-9-7-6-8-10-17)14-21(19,3)15-22(20,4)23-5/h6-10,13-14,16,20H,11-12,15H2,1-5H3/t20-,21+,22-/m1/s1
• Isomeric SMILES: CC(C)CC1=C[C@@H]2C(=C[C@]1(C[C@@]2(C)OC)C)CC3=CC=CC=C3
• WGK Germany: 3
• Molecular Weight: 310.47
• Reaxy-Rn: 19011630
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=19011630&ln=