Iodotrimethylsilane (TMIS) - ≥97%, stabilized with copper scrap , CAS No.16029-98-4

CAS: 16029-98-4 Cat. No.: I100104 Molecular Weight: 200.09 Beilstein Registry Number: 1731136 EC Number: 240-171-0

GRADE & PURITY ≥97%, stabilized with copper scrap

Synonyms

A810132 | Iodotrimethylsilane, purum, >=98.0% (AT) | DTXSID4065997 | F15417 | UNII-7A65KRZ6NV | iodo trimethylsilane | SCHEMBL216 | FT-0656496 | tms-iodide | Iodotrimethylsilane | iodo-trimethylsilane | Iodo-trimethyl-silane | iodotrimethyl-silane | BCP18

Storage

Protected from light,Store at -20°C,Argon charged

Shipped In

Ice chest + Ice pads

Overview

Iodotrimethylsilane is an efficient reagent for ether, ester, carbamate, ketal, and lactone cleavage.Reagent was recently reported to convert allyl- and benzylphosphotriesters to the corresponding iodides. For the introduction of the TMS group, e.g., TMS enol ethers.
An efficient reagent for ether, ester, carbamate, ketal, and lactone cleavage；Efficient reagent for cleaving ethers, esters, carbamates, ketals, and lactones. For the introduction of the TMS group, e.g., TMS enol ethers.Key reagent for the selective deprotection of an N-Cbz group in the presence of a trimethyltin moiety. Reagent was recently reported to convert allyl- and benzylphosphotriesters to the corresponding iodides.

Iodotrimethylsilane is used for the introduction of trimethylsilyl group in organic synthesis. It is also useful for gas chromatography analysis by converting alcohol into a silyl ether derivative, thereby making it more volatile than the original molecule.

Specifications

Synonyms

A810132 | Iodotrimethylsilane, purum, >=98.0% (AT) | DTXSID4065997 | F15417 | UNII-7A65KRZ6NV | iodo trimethylsilane | SCHEMBL216 | FT-0656496 | tms-iodide | Iodotrimethylsilane | iodo-trimethylsilane | Iodo-trimethyl-silane | iodotrimethyl-silane | BCP18

Specifications & Purity

≥97%, stabilized with copper scrap

Storage

Protected from light, Store at -20°C, Argon charged

Shipped In

Ice chest + Ice pads

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥97%

Names and Identifiers

• Canonical Smiles: C[Si](C)(C)I
• IUPAC Name: iodo(trimethyl)silane
• InChIKey: CSRZQMIRAZTJOY-UHFFFAOYSA-N
• INCHI: 1S/C3H9ISi/c1-5(2,3)4/h1-3H3
• Isomeric SMILES: C[Si](C)(C)I
• WGK Germany: 3
• UN Number: 2924
• Molecular Weight: 200.09
• Beilstein: 1731136
• Reaxy-Rn: 1731136
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1731136&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Class Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Organoheterosilanes
          • Level6 Trialkylheterosilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Class: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Organoheterosilanes
• Direct Parent: Trialkylheterosilanes
• Alternative Parents: Silyl monohalides Organic metalloid salts Alkylhalosilanes Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkylheterosilane - Silyl monohalide - Organic metalloid salt - Alkylhalosilane - Hydrocarbon derivative - Organic salt - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as trialkylheterosilanes. These are organoheterosilanes, bearing a silicon atom linked to three alkyl groups and one heteroatom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Miscible with water.
• Sensitivity: Moisture & Light Sensitive
• Refractive Index: 1.47-1.48
• Flash Point(°F): 28°F
• Flash Point(°C): -2℃
• Boil Point(°C): 106°C
• Molecular Weight: 200.090 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 199.952 Da
• Monoisotopic Mass: 199.952 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 5
• Formal Charge: 0
• Complexity: 28.400
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

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