Nickel(II) bromide - PrimorTrace™, anhydrous, ≥99.99% metals basis, powder , CAS No.13462-88-9

CAS: 13462-88-9 Cat. No.: N431943 Molecular Weight: 218.50 EC Number: 236-665-0

GRADE & PURITY Anhydrous Grade, PrimorTrace™, ≥99.99% metals basis, powder

Synonyms

Nickel bromide (NiBr2), hydrate (9CI) | Nickelous bromide | Dibromonickel | Nickel(II) bromide, anhydrous, powder, >=99.9% trace metals basis | UNII-41SGH8A2S6 | AKOS015833436 | Br2Ni | FT-0689160 | nicke l bromide | NICKEL BROMIDE [MI] | EINECS 236-665-0

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice

Specifications

Synonyms

Nickel bromide (NiBr2), hydrate (9CI) | Nickelous bromide | Dibromonickel | Nickel(II) bromide, anhydrous, powder, >=99.9% trace metals basis | UNII-41SGH8A2S6 | AKOS015833436 | Br2Ni | FT-0689160 | nicke l bromide | NICKEL BROMIDE [MI] | EINECS 236-665-0

Specifications & Purity

PrimorTrace™, anhydrous, ≥99.99% metals basis, powder

Storage

Store at 2-8°C, Protected from light, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Grade

Anhydrous Grade, PrimorTrace™

Purity

≥99.99% metals basis

Names and Identifiers

• Canonical Smiles: [Ni](Br)Br
• IUPAC Name: dibromonickel
• InChIKey: IPLJNQFXJUCRNH-UHFFFAOYSA-L
• INCHI: 1S/2BrH.Ni/h2*1H;/q;;+2/p-2
• Isomeric SMILES: [Ni](Br)Br
• WGK Germany: 3
• UN Number: 3288
• Packing Group: I
• Molecular Weight: 218.50
• Reaxy-Rn: 3902852
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=3902852&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Class Transition metal salts
      • Subclass Transition metal bromides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Class: Transition metal salts
• Subclass: Transition metal bromides
• Intermediate Tree Nodes: Not available
• Direct Parent: Transition metal bromides
• Alternative Parents: Inorganic salts Inorganic nickel compounds
• Molecular Framework: Not available
• Substituents: Transition metal bromide - Inorganic salt - Inorganic nickel compound
• Description: This compound belongs to the class of inorganic compounds known as transition metal bromides. These are inorganic compounds in which the largest halogen atom is Bromine, and the heaviest metal atom a transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Moisture sensitive; Light sensitive
• Melt Point(°C): 963℃
• Molecular Weight: 218.500 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 217.77 Da
• Monoisotopic Mass: 215.772 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 3
• Formal Charge: 0
• Complexity: 2.800
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

References

1. Sibo Zhao, Hengbin Mao, Weishan Ma, Mingliang Li, Shao Gang, Bingbing Fan, Hailong Wang, Hongliang Xu, Hongxia Lu.  (2023)  Enhanced luminescence stability of high-entropy dual-phase Cs(Pb1/5Mn1/5Ni1/5Zn1/5Cd1/5)Br3/Cs(Pb1/5Mn1/5Ni1/5Zn1/5Cd1/5)2Br5 perovskite nanocrystals coated with SiO2 and EVA.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2023.10.257]

2. Shiwei Xue, Hengbin Mao, Junhui Li, Xinge Sun, Ziyu Gong, Bingbing Fan, Gang Shao, Hailong Wang, Hongliang Xu, Rui Zhang, Hongxia Lu.  (2023)  One-step synthesis of all-inorganic high-entropy dual-phase Cs‘B’Br3/Cs‘B’2Br5 perovskite nanocrystals by high-energy ball milling.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2023.08.193]

3. Keqiang Chen, Zixin Gu, Zhiqing Wang, Mengyu Guan, Xiu Tan, Wanqing Xu, Xinyu Ji, Weiqi Lu, Yueli Liu, Guogang Li.  (2023)  Surface polarization-induced emission and stability enhancement of CsPbX3 nanocrystals.  Chemical Science,  14  (33): (8914-8923).  [PMID:37621427] [10.1039/D3SC02109B]

4. Ji'an Song, Yan Gao, Zhichao Meng, Zelong Jiang, Xiaobing Cao, Qingguang Zeng, Tao Hu.  (2023)  Nickel-bromide passivation strategy enabled highly efficient blue-emitting CsPbBr3 nanoplates for monochrome LED application.  OPTICAL MATERIALS,      [PMID:] [10.1016/j.optmat.2023.113611]

5. Hengbin Mao, Lei Wang, Junhui Li, Xin Jiang, Shiwei Xue, Mingliang Li, Jinpeng Zhu, Bingbing Fan, Tingting Xu, Gang Shao, Hongliang Xu, Hailong Wang, Rui Zhang, Hongxia Lu.  (2022)  High-Entropy Cs(Pb1/3Mn1/3Ni1/3)Br3 Perovskite Nanocrystals Prepared by High Energy Ball Milling and their Luminescence Properties.  PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION,  39  (9): (2200073).  [PMID:] [10.1002/ppsc.202200073]

6. Wenbo Du, Handou Zheng, Yinwu Li, Chi Shing Cheung, Donghui Li, Heng Gao, Huiyun Deng, Haiyang Gao.  (2022)  Neutral Tridentate α-Sulfonato-β-diimine Nickel Catalyst for (Co)polymerizations of Ethylene and Acrylates.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.2c00268]

7. Jiangyong Pan, Zihan Zhao, Fan Fang, Lixi Wang, Guangzhao Wang, Chengjun Liu, Qianqian Huang, Jinyi Sun, Yuling Huang, Lei Mao, Jing Xie, Ying Xue, Jing Chen, Wei Lei.  (2022)  A Synergetic Codoping Strategy Enabling Performance Improvement of Pure-Blue Perovskite Quantum Dots Light-Emitting Diodes.  Advanced Optical Materials,  10  (9): (2102569).  [PMID:] [10.1002/adom.202102569]

8. Jiangyong Pan, Zihan Zhao, Fan Fang, Lixi Wang, Guangzhao Wang, Chengjun Liu, Jing Chen, Jing Xie, Jiayun Sun, Kai Wang, Xiang Liu, Zhi Tao, Jianguo Zhao, Qinqin Wu, Jianhua Chang, Ye Wang, Wei Lei, Wei Zhang, Xiao Wei Sun, Dewei Zhao.  (2020)  Multiple Cations Enhanced Defect Passivation of Blue Perovskite Quantum Dots Enabling Efficient Light-Emitting Diodes.  Advanced Optical Materials,  8  (24): (2001494).  [PMID:] [10.1002/adom.202001494]

9. Yunxiang Chen, Jingting Zhu, Haibin Ma, Longlong Chen, Rong Li, Ping Jin.  (2019)  VO2/Nickel-bromine-ionic liquid composite film for thermochromic application.  SOLAR ENERGY MATERIALS AND SOLAR CELLS,      [PMID:] [10.1016/j.solmat.2019.03.047]

10. Tie Jun Lin, Xuan Meng, Li Shi.  (2014)  Catalytic hydrocarboxylation of acetylene to acrylic acid using Ni2O3 and cupric bromide as combined catalysts.  JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,      [PMID:] [10.1016/j.molcata.2014.09.027]

11. Qin Ye, Penghao Zhu, Xianghe Meng, Jie Li, Yuanchao Lu.  (2025)  A CsPb0.95Ni0.05Br3 NCs-based fluorescence sensor for rapidly and accurately evaluating trace water in edible oils along with the structure destruction and dissolution.  Food Chemistry-X,      [PMID:39901948] [10.1016/j.fochx.2025.102196]

12. Yang Hao, Hao Wang, Rui Han, Caixia Liu, Qingling Liu.  (2024)  Low concentration adsorption of ammonia using metal halide loaded biogas residue-based carbon materials.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2024.128164]

13. Zi-Yan Li, Jing-Ru Zhang, Qing-Yi Ma, Wen-Qian Leng, Fei-Peng Du, Hao-Han Zhou, Yun-Fei Zhang.  (2025)  Optimization of Thermoelectric Properties of Single-Walled Carbon Nanotubes by Transition Metal Ion Doping and Application to Waste Heat Power Generation.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.5c01988]

14. Mingze Li, Maxim S. Molokeev, Jing Zhao, Zhiguo Xia.  (2020)  Optical Functional Units in Zero-Dimensional Metal Halides as a Paradigm of Tunable Photoluminescence and Multicomponent Chromophores.  Advanced Optical Materials,  8  (8): (1902114).  [PMID:] [10.1002/adom.201902114]

15. Jia Hongnan, Yao Na, Jin Yiming, Wu Liqing, Zhu Juan, Luo Wei.  (2024)  Stabilizing atomic Ru species in conjugated sp2 carbon-linked covalent organic framework for acidic water oxidation.  Nature Communications,  15  (1): (1-13).  [PMID:38926414] [10.1038/s41467-024-49834-5]

16. Bing Han, Yizhao Qing, Runnan Yu, Zhuoxu Liu, Qian Dang, Hui Li, Qianglong Lv, Chen Zhang, Yuyi Han, Yang Zhang, Peijin Ma, Changxiao Li, Shihao Sha, Qirui Hou, Biao Zhao, Zhan'ao Tan.  (2025)  Cation-Mediated Low-Frequency Phonon Suppression in Lead-free Manganese Halides for High-efficiency Green Light-emitting Diodes.  ADVANCED MATERIALS,      [PMID:41074100] [10.1002/adma.202510599]

17. Huaiyuan Wang, Baiqi Zhang, Jie Wang, Yuanwei Lu, Tao Qi, Xuefeng Tian, Meiqi Wang, Zhibin Qu, Wei Zhou, Fei Sun, Jihui Gao, Guangbo Zhao.  (2025)  Hydrated Ionic Polymer with Optimized Halogen Ligand for Thermochromic Smart Windows: Enhanced Luminous Transmittance and Solar Modulation.  Small,      [PMID:40495631] [10.1002/smll.202504399]

18. Xin An, Xiaoqi Guo, Shuhan Zhu, Bingbing Fan, Jinpeng Zhu, Gang Shao, Hongliang Xu, Hailong Wang, Hongxia Lu.  (2025)  High-entropy lead-free perovskite nanoparticles as efficient photocatalysis with a wide visible-light absorption band.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2025.181680]