Potassium osmate(VI) dihydrate - ≥99% , CAS No.10022-66-9

CAS: 10022-66-9 Cat. No.: P109046 Molecular Weight: 368.45 EC Number: 628-964-3

GRADE & PURITY ≥99%

Synonyms

dipotassium;dioxido(dioxo)osmium;dihydrate | Osmic acid (H2OsO4), dipotassium salt, dihydrate | Potassium osmate(vi)dihydrate | DGODWNOPHMXOTR-UHFFFAOYSA-N | Dipotassium tetrahydroxodioxoosmate | Potassium osmate (K2OsO4), dihydrate | Potassium Osmate (VI

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

Reagent for the oxidative cleavage of olefins to ketones and carboxylic acids. Also employed in an intramolecular amidohydroxylation of carbamoyloxy-tethered olefins providing hydroxy oxazolidinones

Specifications

Synonyms

dipotassium;dioxido(dioxo)osmium;dihydrate | Osmic acid (H2OsO4), dipotassium salt, dihydrate | Potassium osmate(vi)dihydrate | DGODWNOPHMXOTR-UHFFFAOYSA-N | Dipotassium tetrahydroxodioxoosmate | Potassium osmate (K2OsO4), dihydrate | Potassium Osmate (VI

Specifications & Purity

≥99%

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥99%

Names and Identifiers

• Canonical Smiles: O.O.[O-][Os](=O)(=O)[O-].[K+].[K+]
• IUPAC Name: dipotassium;dioxido(dioxo)osmium;dihydrate
• InChIKey: DGODWNOPHMXOTR-UHFFFAOYSA-N
• INCHI: 1S/2K.2H2O.4O.Os/h;;2*1H2;;;;;/q2*+1;;;;;2*-1
• Isomeric SMILES: O.O.[O-][Os](=O)(=O)[O-].[K+].[K+]
• WGK Germany: 3
• Molecular Weight: 368.45
• Reaxy-Rn: 11325441
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=11325441&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Class Alkali metal organides
      • Subclass Alkali metal oxides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Class: Alkali metal organides
• Subclass: Alkali metal oxides
• Intermediate Tree Nodes: Not available
• Direct Parent: Alkali metal oxides
• Alternative Parents: Inorganic salts Inorganic oxides
• Molecular Framework: Not available
• Substituents: Alkali metal oxide - Inorganic oxide - Inorganic salt
• Description: This compound belongs to the class of inorganic compounds known as alkali metal oxides. These are inorganic compounds containing an oxygen atom of an oxidation state of -2, in which the heaviest atom bonded to the oxygen is an alkali metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Soluble in water. Slowly decomposes in aqueous solution forming the tetroxide. Insoluble in alcohol, ether.
• Sensitivity: Hygroscopic
• Molecular Weight: 368.500 g/mol
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 369.89 Da
• Monoisotopic Mass: 369.89 Da
• Topological Polar Surface Area: 82.300 Ų
• Heavy Atom Count: 9
• Formal Charge: 0
• Complexity: 62.200
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 5

XLogP3

References

1. Qian Li, Pan Qiao, Xiu Chen, Jing Wang, Liujiao Bian, Xiaohui Zheng.  (2017)  Affinity chromatographic methodologies based on immobilized voltage dependent anion channel isoform 1 and application in protein-ligand interaction analysis and bioactive compounds screening from traditional medicine.  JOURNAL OF CHROMATOGRAPHY A,      [PMID:28342583] [10.1016/j.chroma.2017.03.023]