5-Chloro-2-thienylmagnesium bromide - 0.5M slurry in THF , CAS No.111762-30-2

CAS: 111762-30-2 Cat. No.: C465863 Molecular Weight: 221.79 EC Number: 806-316-2

GRADE & PURITY 0.5M slurry in THF

Synonyms

Magnesium, bromo(5-chloro-2-thienyl)- | MFCD02260211 | 5-Chloro-2-thienyl magnesium bromide | 5-Chloro-2-thienylmagnesium bromide 0.25 M in Tetrahydrofuran | magnesium;5-chloro-2H-thiophen-2-ide;bromide | 5-Chloro-2-thienylmagnesium bromide | 5-chloro-2-t

Storage

Store at 2-8°C

Shipped In

Wet ice

Specifications

Synonyms

Magnesium, bromo(5-chloro-2-thienyl)- | MFCD02260211 | 5-Chloro-2-thienyl magnesium bromide | 5-Chloro-2-thienylmagnesium bromide 0.25 M in Tetrahydrofuran | magnesium;5-chloro-2H-thiophen-2-ide;bromide | 5-Chloro-2-thienylmagnesium bromide | 5-chloro-2-t

Specifications & Purity

0.5M slurry in THF

Legal Information

Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标

Storage

Store at 2-8°C

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Names and Identifiers

• Canonical Smiles: C1=[C-]SC(=C1)Cl.[Mg+2].[Br-]
• IUPAC Name: magnesium;5-chloro-2H-thiophen-2-ide;bromide
• InChIKey: XALGVPKDKLSEQN-UHFFFAOYSA-M
• INCHI: 1S/C4H2ClS.BrH.Mg/c5-4-2-1-3-6-4;;/h1-2H;1H;/q-1;;+2/p-1
• Isomeric SMILES: C1=[C-]SC(=C1)Cl.[Mg+2].[Br-]
• WGK Germany: 3
• UN Number: 2924
• Packing Group: II
• Molecular Weight: 221.79

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organohalogen compounds
    • Class Aryl halides
      • Subclass Aryl chlorides

• Kingdom: Organic compounds
• Superclass: Organohalogen compounds
• Class: Aryl halides
• Subclass: Aryl chlorides
• Intermediate Tree Nodes: Not available
• Direct Parent: Aryl chlorides
• Alternative Parents: Thiophenes Heteroaromatic compounds Organic metal halides Organic metal bromide salts Organochlorides Organic bromide salts Hydrocarbon derivatives Organic cations
• Molecular Framework: Aromatic heteromonocyclic compounds
• Substituents: Aryl chloride - Heteroaromatic compound - Thiophene - Organic metal halide - Organic metal bromide salt - Organoheterocyclic compound - Hydrocarbon derivative - Organic bromide salt - Organic salt - Organochloride - Organic cation - Aromatic heteromonocyclic compound
• Description: This compound belongs to the class of organic compounds known as aryl chlorides. These are organic compounds containing the acyl chloride functional group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Flash Point(°F): 1.4 °F
• Flash Point(°C): -17 °C
• Melt Point(°C): 65°C
• Molecular Weight: 221.790 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 219.86 Da
• Monoisotopic Mass: 219.86 Da
• Topological Polar Surface Area: 25.300 Ų
• Heavy Atom Count: 8
• Formal Charge: 0
• Complexity: 113.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 3

XLogP3

References

1. Zhengyang Fan, Jie Chen, Huaming Mao, Jungang Yin, Wei Dai, Linlin He, Hongwei Yang.  (2021)  Synthesis and the growth mechanism of ultrafine silver nanowires by using 5-chloro-2-thienylmagnesium bromide as the additive.  RSC Advances,  11  (59): (37063-37066).  [PMID:35496428] [10.1039/D1RA07432F]