Hoveyda-Grubbs Catalyst® M722 - ≥99.95% metals basis , CAS No.635679-24-2

CAS: 635679-24-2 Cat. No.: H283998 Formula: C₃₇H₅₀Cl₂N₂ORu Molecular Weight: 710.78

GRADE & PURITY ≥99.95% metals basis

Synonyms

635679-24-2|Dichloro[1,3-bis(2,6-isopropylphenyl)-2-imidazolidinylidene](2-isopropoxyphenylmethylene)ruthenium(II)|{1,3-Bis[2,6-di(propan-2-yl)phenyl]imidazolidin-2-ylidene}(dichloro)({2-[(propan-2-yl)oxy]phenyl}methylidene)ruthenium|Grubbs Catalyst(TM) C

Storage

Store at 2-8°C

Shipped In

Wet ice

Overview

Application

Preferred catalyst for making trisubstituted olefins by cross metathesis.

Product class
Carbene Ligands, M-C, Homogeneous Catalysts, Hoveyda-Grubbs Catalyst® 2nd Generation, Alkoxybenzylidene Ligands

Reaction type
Alkene Metathesis, Acyclic Diene Metathesis, Cross Metathesis, Ring Arrangement Metathesis , Ring Closing Metathesis, Self Metathesis

Chemical properties

Chemical formula

C37H50Cl2N2ORu

Empirical formula

Molecular weight

710.78

Metal

Ru

Theoretical metal content

14

Physical state

powder

Color

green

Metal purity

99.95

Specifications

Synonyms

635679-24-2 | Dichloro[1,3-bis(2,6-isopropylphenyl)-2-imidazolidinylidene](2-isopropoxyphenylmethylene)ruthenium(II) | {1,3-Bis[2,6-di(propan-2-yl)phenyl]imidazolidin-2-ylidene}(dichloro)({2-[(propan-2-yl)oxy]phenyl}methylidene)ruthenium | Grubbs Catalyst(TM) C

Specifications & Purity

≥99.95% metals basis

Legal Information

This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through aladdin, its affiliates or their autho

Storage

Store at 2-8°C

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥99.95% metals basis

Names and Identifiers

• Canonical Smiles: CC(C)C1=C(C(=CC=C1)C(C)C)N2CCN(C2=[Ru](=CC3=CC=CC=C3OC(C)C)(Cl)Cl)C4=C(C=CC=C4C(C)C)C(C)C
• IUPAC Name: [1,3-bis[2,6-di(propan-2-yl)phenyl]imidazolidin-2-ylidene]-dichloro-[(2-propan-2-yloxyphenyl)methylidene]ruthenium
• InChIKey: ONAWWBRGWXRMAF-UHFFFAOYSA-L
• INCHI: 1S/C27H38N2.C10H12O.2ClH.Ru/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-8(2)11-10-7-5-4-6-9(10)3;;;/h9-14,18-21H,15-16H2,1-8H3;3-8H,1-2H3;2*1H;/q;;;;+2/p-2
• Isomeric SMILES: CC(C)C1=C(C(=CC=C1)C(C)C)N2CCN(C2=[Ru](=CC3=CC=CC=C3OC(C)C)(Cl)Cl)C4=C(C=CC=C4C(C)C)C(C)C
• Molecular Weight: 710.78
• Reaxy-Rn: 38868997
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=38868997&ln=

Chemical and Physical Properties

• Melt Point(°C): 242-246 °C