10mM in DMSO for sensitive chromatographic and analytical workflows requiring minimal baseline interference.
Argon charged,Store at -80°C Ships Dry ice packs + Cold packs Check lot-specific COA for exact specifications.
SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.
Cited in 38 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.
Usually used in the synthesis of 1-hydroxybenzotriazole derivatives.
| Isomeric SMILES | C1=CC=C(C(=C1)[N+](=O)[O-])Cl |
|---|---|
| WGK Germany | 2 |
| RTECS | CZ0875000 |
| UN Number | 1578 |
| Packing Group | II |
| Molecular Weight | 157.55 |
| Beilstein | 509273 |
| Reaxy-Rn | 509273 |
| Reaxys-RN_link_address | https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=509273&ln= |
Comprehensive hazard, handling, storage, and regulatory compliance document.
Download SDS →Lot-specific quality data. Enter your lot number to retrieve the exact COA.
Look up COA →Full quality attributes and acceptance criteria for this grade.
View spec sheet →| Solubility | Insoluble in water; Degree of Solubility in water: 0.59 g/l 25 °C; Very soluble in Acetone; Soluble in Toluene,Ether,Benzene,Alcohol |
|---|---|
| Sensitivity | Air Sensitive. |
| Freezing Point(°C) | 32 °C |
| Flash Point(°F) | 258.8 °F - closed cup |
| Flash Point(°C) | 126 °C - closed cup |
| Boil Point(°C) | 245-246°C |
| Melt Point(°C) | 32-33°C |
| 1. Hongbo Yu, Shuibo Wang, Lin Zhu, Chunzheng Wu. (2023) One-pot synthesis of Pt@Sn core-shell nanocatalysts for the hydrogenation of halonitrobenzene to produce haloaniline with ultra-high selectivity. APPLIED SURFACE SCIENCE, [PMID:] [10.1016/j.apsusc.2023.158729] |
| 2. Kai Sun, Yuewen Shao, Cong Ming, Mengjiao Fan, Huailin Fan, Lijun Zhang, Shu Zhang, Yi Wang, Guozhu Chen, Xun Hu. (2023) Copper-based catalysts synthesized during hydrogenation. CHEMICAL ENGINEERING SCIENCE, [PMID:] [10.1016/j.ces.2023.118819] |
| 3. Jiasheng Wang, Ying Zhang, Xiaonan Xu, Ming Bao. (2023) Oxygen Vacancy-Rich Ni–CeO2 Heterojunction Catalyst for Hydrogenating Halogenated Nitroarenes with High Activity and Selectivity. ACS Applied Materials & Interfaces, [PMID:36637974] [10.1021/acsami.2c21272] |
| 4. Jiarui Zhao, Lingzhe Fang, Junhong Fu, Jian Wang, Qike Jiang, Tao Li, Jiahui Huang. (2022) Highly selective IrMo/TiO2 catalyst for hydrogenation of nitroarenes. Molecular Catalysis, [PMID:] [10.1016/j.mcat.2022.112705] |
| 5. Yebin Zhou, Ling Li, Yi Liu, Hongzheng Wang, Zhenlong Feng, Feng Feng, Qunfeng Zhang, Wucan Liu, Wenfeng Han, Chunshan Lu, Xiaonian Li. (2022) Palladium Nanoparticles Inset into the Carbon Sphere with Robust Acid Resistance for Selective Hydrogenation of Chloronitrobenzene. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, [PMID:] [10.1021/acs.iecr.1c04983] |
| 6. Hongbo Yu, Chunzheng Wu, Shiwei Wang, Tong Li, Hongfeng Yin. (2021) Transition Metal Oxide-Modified Ir Nanoparticles Supported on SBA-15 Silica for Selective Hydrogenation of Substituted Nitroaromatics. ACS Applied Nano Materials, [PMID:] [10.1021/acsanm.1c01164] |
| 7. Qiuyang Zhang, Caiyun Xu, Hongfeng Yin, Shenghu Zhou. (2019) Enhanced Catalytic Hydrogenation Performance of Rh-Co2O3 Heteroaggregate Nanostructures by in Situ Transformation of Rh@Co Core–Shell Nanoparticles. ACS Omega, [PMID:31858069] [10.1021/acsomega.9b03340] |
| 8. Jun He, Lining Yu, Xuebin Huang, Meiling Qi. (2019) Triptycene-based stationary phases for gas chromatographic separations of positional isomers. JOURNAL OF CHROMATOGRAPHY A, [PMID:31000208] [10.1016/j.chroma.2019.04.018] |
| 9. Hongbo Yu, Weiqiang Tang, Kaijie Li, Shuangliang Zhao, Hongfeng Yin, Shenghu Zhou. (2019) Enhanced Catalytic Performance for Hydrogenation of Substituted Nitroaromatics over Ir-Based Bimetallic Nanocatalysts. ACS Applied Materials & Interfaces, [PMID:30674185] [10.1021/acsami.8b19056] |
| 10. Hongbo Yu, Weiqiang Tang, Kaijie Li, Hongfeng Yin, Shuangliang Zhao, Shenghu Zhou. (2018) Design of Cu-based intermetallic nanocrystals for enhancing hydrogenation selectivity. CHEMICAL ENGINEERING SCIENCE, [PMID:] [10.1016/j.ces.2018.11.024] |
| 11. Miaomiao Liu, Weiqiang Tang, Zhaohui Xie, Hongbo Yu, Hongfeng Yin, Yisheng Xu, Shuangliang Zhao, Shenghu Zhou. (2017) Design of Highly Efficient Pt-SnO2 Hydrogenation Nanocatalysts using Pt@Sn Core–Shell Nanoparticles. ACS Catalysis, [PMID:] [10.1021/acscatal.6b03109] |
| 12. Mengjiao Fan, Yuewen Shao, Kai Sun, Yuchen Jiang, Shu Zhang, Yi Wang, Song Hu, Jun Xiang, Xun Hu. (2023) Bio-oil as a carbon source for synthesis of pin-like cobalt catalyst for hydrogenation of o-chloronitrobenzene. FUEL PROCESSING TECHNOLOGY, [PMID:] [10.1016/j.fuproc.2023.107814] |
| 13. Yalan Hu, Youyou Li, Yueru Shi, Yixin Kuang, Suxin Zhou, Yuan Peng, Yuefan Liu, Luyi Chen, Ningbo Zhou, Juan Zheng, Fang Zhu, Gangfeng Ouyang. (2023) A robust and ultra-high-surface hydrogen-bonded organic framework promoting high-efficiency solid phase microextraction of multiple persistent organic pollutants from beverage and tea. FOOD CHEMISTRY, [PMID:36868067] [10.1016/j.foodchem.2023.135790] |
| 14. Ziqi Sun, Meiling Qi. (2022) High separation performance of carbon dioxide-based poly(ether-carbonate) copolymer for gas chromatographic analyses. JOURNAL OF CHROMATOGRAPHY A, [PMID:36166885] [10.1016/j.chroma.2022.463493] |
| 15. Lihua Zhu, Huan Zhang, Huaze Zhu, Huan Fu, Anna Kroner, Zhiqing Yang, Hengqiang Ye, Bing Hui Chen, Rafael Luque. (2022) Controlling nanostructures of PtNiCo/C trimetallic nanocatalysts and relationship of structure-catalytic performance for selective hydrogenation of nitroarenes. JOURNAL OF CATALYSIS, [PMID:] [10.1016/j.jcat.2022.08.012] |
| 16. Fan Yang, Hongbo Yu, Chunzheng Wu, Shiwei Wang, Tong Li, Hongfeng Yin. (2022) RhCu Bimetallic Nanoparticles in Hollow Carbon Spheres for Catalytic Halonitrobenzene Chemoselective Hydrogenation. ACS Applied Nano Materials, [PMID:] [10.1021/acsanm.2c02358] |
| 17. Zhijun Li, Mingyang Zhang, Xiuli Dong, Siqi Ji, Lili Zhang, Leipeng Leng, Honghong Li, J. Hugh Horton, Qian Xu, Junfa Zhu. (2022) Strong electronic interaction of indium oxide with palladium single atoms induced by quenching toward enhanced hydrogenation of nitrobenzene. APPLIED CATALYSIS B-ENVIRONMENTAL, [PMID:] [10.1016/j.apcatb.2022.121462] |
| 18. Liang Zhu, Xuecui Mei, Zhengchun Peng, Jiao Yang, Yingchun Li. (2022) A paper-based microfluidic sensor array combining molecular imprinting technology and carbon quantum dots for the discrimination of nitrophenol isomers. JOURNAL OF HAZARDOUS MATERIALS, [PMID:35504132] [10.1016/j.jhazmat.2022.129012] |
| 19. Lixia Li, Qinkai Guo, Baohe Lv, Minxue Zheng, Wang Zhan, Yanhong Liu, Wanzhen Xu, Ruiwei Wang, Hongbo Zeng, Baodong Mao. (2022) Surface modified silver/magnetite nanocomposite activating hydrogen peroxide for efficient degradation of chlorophenols. JOURNAL OF COLLOID AND INTERFACE SCIENCE, [PMID:35278862] [10.1016/j.jcis.2022.02.137] |
| 20. Wei Li, Jieli Lyu, Haimao Song, Zetao Song, Ruoyu Wang, Lei Ye, Zhongshan Liu, Yu Fang, Junxia Peng. (2021) Covalent Organic Polymer Nanoparticle-Supported Monolithic Foams for Separation of Nitrotoluene Isomers. ACS Applied Nano Materials, [PMID:] [10.1021/acsanm.1c02260] |
| 21. Peng Zhang, Shaonan Xu, Yan Wang, Wei Zhang, Wenqing Li, Cundi Wei, Peiping Zhang, Shiding Miao. (2021) Fabrication of Pd/Mg2P2O7 via a Struvite-Template Way from Wastewater and Application as Chemoselective Catalyst in Hydrogenation of Nitroarenes. CHEMISTRY-A EUROPEAN JOURNAL, 27 (41): (10666-10676). [PMID:34009699] [10.1002/chem.202100684] |
| 22. Yiran Wang, Yuewen Shao, Lijun Zhang, Shu Zhang, Yi Wang, Jun Xiang, Song Hu, Guangzhi Hu, Xun Hu. (2021) Co-presence of hydrophilic and hydrophobic sites in Ni/biochar catalyst for enhancing the hydrogenation activity. FUEL, [PMID:] [10.1016/j.fuel.2021.120426] |
| 23. Xue Xiong, Meiling Qi. (2020) A novel column fabrication approach for capillary gas chromatography via a cross-linked organogel network with high stability and inertness. NEW JOURNAL OF CHEMISTRY, 44 (25): (10621-10627). [PMID:] [10.1039/D0NJ02185G] |
| 24. Yan Zhao, Min Song, Qi Cao, Peizhe Sun, Yonghao Chen, Fanyue Meng. (2020) The superoxide radicals’ production via persulfate activated with CuFe2O4@Biochar composites to promote the redox pairs cycling for efficient degradation of o-nitrochlorobenzene in soil. JOURNAL OF HAZARDOUS MATERIALS, [PMID:32947726] [10.1016/j.jhazmat.2020.122887] |
| 25. Li Hong-Xing, Xie Tian-Peng, Xie Sheng-Ming, Wang Bang-Jin, Zhang Jun-Hui, Yuan Li-Ming. (2020) Enantiomeric Separation on a Homochiral Porous Organic Cage-Based Chiral Stationary Phase by Gas Chromatography. CHROMATOGRAPHIA, 83 (6): (703-713). [PMID:] [10.1007/s10337-020-03895-y] |
| 26. Li Hong-Xing, Xie Tian-Peng, Yan Ke-Qian, Xie Sheng-Ming, Wang Bang-Jin, Zhang Jun-Hui, Yuan Li-Ming. (2020) A hydroxyl-functionalized homochiral porous organic cage for gas chromatographic separations. MICROCHIMICA ACTA, 187 (5): (1-10). [PMID:32291536] [10.1007/s00604-020-04252-4] |
| 27. Yueling Cao, Kangkai Liu, Chen Wu, Hepeng Zhang, Qiuyu Zhang. (2020) In situ-formed cobalt embedded into N-doped carbon as highly efficient and selective catalysts for the hydrogenation of halogenated nitrobenzenes under mild conditions. APPLIED CATALYSIS A-GENERAL, [PMID:] [10.1016/j.apcata.2020.117434] |
| 28. Caiyun Xu, Qi Li, Qiuyang Zhang, Kaijie Li, Hongfeng Yin, Shenghu Zhou. (2019) Structural Identification and Enhanced Catalytic Performance of Alumina-Supported Well-Defined Rh-SnO2 Close-Contact Heteroaggragate Nanostructures. ACS Applied Nano Materials, [PMID:] [10.1021/acsanm.9b01000] |
| 29. Xiao-Ling Huang, Hai-Hang Lan, Yi-Lun Yan, Gui Chen, Zi-Hao He, Kai Zhang, Song-Liang Cai, Sheng-Run Zheng, Jun Fan, Wei-Guang Zhang. (2019) Fabrication of a hydrazone-linked covalent organic framework-bound capillary column for gas chromatography separation. Separation Science Plus, 2 (4): (120-128). [PMID:] [10.1002/sscp.201800146] |
| 30. Yanan Dou, Lan Guo, Guoliang Li, Xiaoxia Lv, Lian Xia, JinmaoYou. (2019) Amino group functionalized metal-organic framework as dispersive solid-phase extraction sorbent to determine nitrobenzene compounds in water samples. MICROCHEMICAL JOURNAL, [PMID:] [10.1016/j.microc.2019.01.035] |
| 31. Kai Zhang, Song-Liang Cai, Yi-Lun Yan, Zi-Hao He, Hui-Mei Lin, Xiao-Ling Huang, Sheng-Run Zheng, Jun Fan, Wei-Guang Zhang. (2017) Construction of a hydrazone-linked chiral covalent organic framework–silica composite as the stationary phase for high performance liquid chromatography. JOURNAL OF CHROMATOGRAPHY A, [PMID:28899554] [10.1016/j.chroma.2017.09.007] |
| 32. Jifen Liang, Xiaoming Zhang, Lingyan Jing, Hengquan Yang. (2017) N-doped ordered mesoporous carbon as a multifunctional support of ultrafine Pt nanoparticles for hydrogenation of nitroarenes. CHINESE JOURNAL OF CATALYSIS, [PMID:] [10.1016/S1872-2067(17)62833-X] |
| 33. Xinhuan Lu, Yang chen, Zhenshuang Zhao, Hao Deng, Dan Zhou, Changcheng Wei, Renfeng Nie, Qinghua Xia. (2016) Highly selective one-step hydrogenation of nitrobenzene to cyclohexylamine over the supported 10% Ni/carbon catalysts doped with 3‰ Rh. RSC Advances, 6 (19): (15354-15361). [PMID:] [10.1039/C5RA27202E] |
| 34. Leiduan Hao, Yanfei Zhao, Bo Yu, Hongye Zhang, Huanjun Xu, Jilei Xu, Zhimin Liu. (2014) Polyurea-supported metal nanocatalysts: Synthesis, characterization and application in selective hydrogenation of o-chloronitrobenzene. JOURNAL OF COLLOID AND INTERFACE SCIENCE, [PMID:24767496] [10.1016/j.jcis.2014.03.015] |
| 35. Zhi-Li Fang, Sheng-Run Zheng, Jing-Bo Tan, Song-Liang Cai, Jun Fan, Xia Yan, Wei-Guang Zhang. (2013) Tubular metal–organic framework-based capillary gas chromatography column for separation of alkanes and aromatic positional isomers. JOURNAL OF CHROMATOGRAPHY A, [PMID:23473507] [10.1016/j.chroma.2013.02.024] |
| 36. Zitao Shen, Zhuo Wang, Pengfei Ye, Lihong Guo, Sheng Peng, Yuefan Liu, Yongsheng Cui, Juan Zheng, Gangfeng Ouyang. (2025) Highly hydrophobic calixarene polymers for efficient enrichment of polar nitrobenzene compounds. TALANTA, [PMID:39778492] [10.1016/j.talanta.2025.127555] |
| 37. Jia Xu, Tao Li, Wei E. Huang, Ning-Yi Zhou. (2024) Semi-rational design of nitroarene dioxygenase for catalytic ability toward 2,4-dichloronitrobenzene. APPLIED AND ENVIRONMENTAL MICROBIOLOGY, [PMID:38709097] [10.1128/aem.01436-23] |
| 38. Jun-Hui Zhang, Sheng-Ming Xie, Bang-Jin Wang, Pin-Gang He, Li-Ming Yuan. (2015) Highly selective separation of enantiomers using a chiral porous organic cage. JOURNAL OF CHROMATOGRAPHY A, [PMID:26632517] [10.1016/j.chroma.2015.11.038] |
