Tris(trimethylsilyl) Phosphite - ≥95% , CAS No.1795-31-9

CAS: 1795-31-9 Cat. No.: T161994 Molecular Weight: 298.54 Beilstein Registry Number: 2043810 EC Number: 679-684-3 PubChem CID: 137213

GRADE & PURITY ≥95%

Synonyms

Trimethylsilanol phosphite | TRIS(TRIMETHYLSILYL)PHOSPHITE | Silanol, trimethyl-, phosphite (3:1) | Silanol, 1,1,1-trimethyl-, 1,1',1''-phosphite | Phosphorous Acid Tris(trimethylsilyl) Ester | Tris(trimethylsilyl) phosphite | tritrimethylsilyl phosphite

Storage

Argon charged,Room temperature

Shipped In

Normal

Overview

Tris(trimethylsilyl)phosphate is tris(trimethylsilyl)ester of phosphoric acid. It is an important raw material and intermediate inorganic synthesis. It is used in the preparation of bis(trimethylsilyl)phosphonate esters by the Arbuzov reaction with halogen-containing compounds. 

Application：
Tris(trimethylsilyl) phosphite is used as a:
Film-forming additive to enhance the electrochemical performance of the NMC811[LiNi0.8Mn0.1Co0.1O2]/Si-Grcell.

Specifications

Synonyms

Trimethylsilanol phosphite | TRIS(TRIMETHYLSILYL)PHOSPHITE | Silanol, trimethyl-, phosphite (3:1) | Silanol, 1, 1, 1-trimethyl-, 1, 1', 1''-phosphite | Phosphorous Acid Tris(trimethylsilyl) Ester | Tris(trimethylsilyl) phosphite | tritrimethylsilyl phosphite

Specifications & Purity

≥95%

Storage

Argon charged, Room temperature

Shipped In

Normal

Purity

≥95%

Names and Identifiers

• Pubchem Sid: 504757113
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504757113
• Canonical Smiles: C[Si](C)(C)OP(O[Si](C)(C)C)O[Si](C)(C)C
• IUPAC Name: tris(trimethylsilyl) phosphite
• InChIKey: VMZOBROUFBEGAR-UHFFFAOYSA-N
• INCHI: 1S/C9H27O3PSi3/c1-14(2,3)10-13(11-15(4,5)6)12-16(7,8)9/h1-9H3
• Isomeric SMILES: C[Si](C)(C)OP(O[Si](C)(C)C)O[Si](C)(C)C
• WGK Germany: 3
• PubChem CID: 137213
• Molecular Weight: 298.54
• Beilstein: 2043810
• Reaxy-Rn: 2043814

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic oxygen compounds
    • Class Organic oxoanionic compounds
      • Subclass Organic phosphites

• Kingdom: Organic compounds
• Superclass: Organic oxygen compounds
• Class: Organic oxoanionic compounds
• Subclass: Organic phosphites
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic phosphites
• Alternative Parents: Trialkylheterosilanes Organic metalloid salts Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkylheterosilane - Organic phosphite - Organoheterosilane - Organic metalloid salt - Hydrocarbon derivative - Organic salt - Organosilicon compound - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as organic phosphites. These are organic compounds containing the phosphite oxoanion, with the formula [PO3]3-.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Air Sensitive,Moisture Sensitive
• Refractive Index: 1.41
• Flash Point(°F): 235.4 °F
• Flash Point(°C): 113 °C
• Boil Point(°C): 78-81 °C/8 mmHg(lit.)
• Molecular Weight: 298.540 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 298.101 Da
• Monoisotopic Mass: 298.101 Da
• Topological Polar Surface Area: 27.700 Ų
• Heavy Atom Count: 16
• Formal Charge: 0
• Complexity: 179.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3