5,10,15,20-Tetrakis(4-aminophenyl)porphyrin - ≥95% , CAS No.22112-84-1

CAS: 22112-84-1 Cat. No.: T123122 Molecular Weight: 674.81 EC Number: 678-632-7 PubChem CID: 135411734

GRADE & PURITY ≥95%

Synonyms

4-[10,15,20-tris(4-aminophenyl)-21,23-dihydroporphyrin-5-yl]aniline | TPAPP | 5,10,15,20-Tetrakis(4-aminophenyl)porphyrin | YSZC137 | Tetra(p-aminophenyl)porphyrin | 5,10,15,20-Tetrakis(4-aminophenyl)-21H,23H-porphine | Tetra-(4-aminophenyl)porphine

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice

Overview

5,10,15,20-Tetrakis(4-aminophenyl)porphyrin is porphyrin compound that is substituted with four 4-aminophenyl moieties. This porphyrin has been described as a useful ligand for the design of catalysts, and was used to prepare a manganese (III) complex for catalyzing oxidative decarboxylations of carboxylic acids with sodium periodate.
A 4-aminophenyl substituted porphyrin.

Specifications

Synonyms

4-[10, 15, 20-tris(4-aminophenyl)-21, 23-dihydroporphyrin-5-yl]aniline | TPAPP | 5, 10, 15, 20-Tetrakis(4-aminophenyl)porphyrin | YSZC137 | Tetra(p-aminophenyl)porphyrin | 5, 10, 15, 20-Tetrakis(4-aminophenyl)-21H, 23H-porphine | Tetra-(4-aminophenyl)porphine

Specifications & Purity

≥95%

Storage

Store at 2-8°C, Protected from light, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥95%

Names and Identifiers

• Canonical Smiles: C1=CC(=CC=C1C2=C3C=CC(=C(C4=NC(=C(C5=CC=C(N5)C(=C6C=CC2=N6)C7=CC=C(C=C7)N)C8=CC=C(C=C8)N)C=C4)C9=CC=C(C=C9)N)N3)N
• IUPAC Name: 4-[10,15,20-tris(4-aminophenyl)-21,23-dihydroporphyrin-5-yl]aniline
• InChIKey: REPFNYFEIOZRLM-UHFFFAOYSA-N
• INCHI: 1S/C44H34N8/c45-29-9-1-25(2-10-29)41-33-17-19-35(49-33)42(26-3-11-30(46)12-4-26)37-21-23-39(51-37)44(28-7-15-32(48)16-8-28)40-24-22-38(52-40)43(36-20-18-34(41)50-36)27-5-13-31(47)14-6-27/h1-24,49,52H,45-48H2
• Isomeric SMILES: C1=CC(=CC=C1C2=C3C=CC(=C(C4=NC(=C(C5=CC=C(N5)C(=C6C=CC2=N6)C7=CC=C(C=C7)N)C8=CC=C(C=C8)N)C=C4)C9=CC=C(C=C9)N)N3)N
• PubChem CID: 135411734
• Molecular Weight: 674.81
• Reaxy-Rn: 3643149

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organoheterocyclic compounds
    • Class Tetrapyrroles and derivatives
      • Subclass Porphyrins

• Kingdom: Organic compounds
• Superclass: Organoheterocyclic compounds
• Class: Tetrapyrroles and derivatives
• Subclass: Porphyrins
• Intermediate Tree Nodes: Not available
• Direct Parent: Porphyrins
• Alternative Parents: Aniline and substituted anilines Pyrroles Heteroaromatic compounds Azacyclic compounds Primary amines Hydrocarbon derivatives
• Molecular Framework: Aromatic heteropolycyclic compounds
• Substituents: Porphyrin - Aniline or substituted anilines - Benzenoid - Monocyclic benzene moiety - Heteroaromatic compound - Pyrrole - Azacycle - Organic nitrogen compound - Hydrocarbon derivative - Primary amine - Organonitrogen compound - Amine - Aromatic heteropolycyclic compound
• Description: This compound belongs to the class of organic compounds known as porphyrins. These are compounds containing a fundamental skeleton of four pyrrole nuclei united through the alpha-positions by four methine groups to form a macrocyclic structure.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Associated Targets(non-human)

Pseudomonas aeruginosa (123386 Activities)

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Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Staphylococcus aureus (210822 Activities)

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Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Escherichia coli (133304 Activities)

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Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Mechanisms of Action

Chemical and Physical Properties

• Sensitivity: Light sensitive；Hygroscopic
• Molecular Weight: 674.800 g/mol
• XLogP3: 7.700
• Hydrogen Bond Donor Count: 6
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 4
• Exact Mass: 674.291 Da
• Monoisotopic Mass: 674.291 Da
• Topological Polar Surface Area: 161.000 Ų
• Heavy Atom Count: 52
• Formal Charge: 0
• Complexity: 965.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

References

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2. Huan Lin, Xin Cheng, Ming-Jie Yin, Zhouzhou Bao, Xunbin Wei, Bobo Gu.  (2020)  Flexible porphyrin doped polymer optical fibers for rapid and remote detection of trace DNT vapor.  ANALYST,  145  (15): (5307-5313).  [PMID:32555787] [10.1039/D0AN00706D]

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