Methyltrioctylammonium chloride - ≥97% , CAS No.5137-55-3

CAS: 5137-55-3 Cat. No.: M106664 Molecular Weight: 404.16 Beilstein Registry Number: 4039255 EC Number: 225-896-2

GRADE & PURITY ≥97%

Synonyms

EINECS 225-896-2 | SCHEMBL108549 | Tricaprylylmethylammonium chloride | XKBGEWXEAPTVCK-UHFFFAOYSA-M | Aliquat(R) 336 | aliquat-336 | AMMONIUM, METHYLTRIOCTYL-, CHLORIDE | methyltrioctylazanium chloride | trioctyl methylammonium chloride | 1-Octanaminium,

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

Methyltrioctylammonium chloride can be used:

• As a catalyst in the synthesis of acridine dione derivatives from aromatic aldehyde, dimedone and amines under ultrasonic irradiations.

• As a catalyst in the synthesis of extended π-systems using aromatic aldehydes and methyldiazines.

• As a component of a catalytic system used in the Suzuki-Miyaura cross-coupling reaction of a variety of aryl and heteroaryl chlorides in H2O.

Specifications

Synonyms

EINECS 225-896-2 | SCHEMBL108549 | Tricaprylylmethylammonium chloride | XKBGEWXEAPTVCK-UHFFFAOYSA-M | Aliquat(R) 336 | aliquat-336 | AMMONIUM, METHYLTRIOCTYL-, CHLORIDE | methyltrioctylazanium chloride | trioctyl methylammonium chloride | 1-Octanaminium,

Specifications & Purity

≥97%

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥97%

Names and Identifiers

• Pubchem Sid: 504753026
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504753026
• Canonical Smiles: CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC.[Cl-]
• IUPAC Name: methyl(trioctyl)azanium;chloride
• InChIKey: XKBGEWXEAPTVCK-UHFFFAOYSA-M
• INCHI: 1S/C25H54N.ClH/c1-5-8-11-14-17-20-23-26(4,24-21-18-15-12-9-6-2)25-22-19-16-13-10-7-3;/h5-25H2,1-4H3;1H/q+1;/p-1
• Isomeric SMILES: CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC.[Cl-]
• WGK Germany: 3
• RTECS: BR8575000
• Alternate CAS: 22061-11-6
• UN Number: 2810
• Molecular Weight: 404.16
• Beilstein: 4039255
• Reaxy-Rn: 4039255
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=4039255&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic nitrogen compounds
    • Class Organonitrogen compounds
      • Subclass Quaternary ammonium salts

• Kingdom: Organic compounds
• Superclass: Organic nitrogen compounds
• Class: Organonitrogen compounds
• Subclass: Quaternary ammonium salts
• Intermediate Tree Nodes: Not available
• Direct Parent: Tetraalkylammonium salts
• Alternative Parents: Organopnictogen compounds Organic chloride salts Hydrocarbon derivatives Amines
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Tetraalkylammonium salt - Organopnictogen compound - Hydrocarbon derivative - Organic chloride salt - Organic salt - Amine - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as tetraalkylammonium salts. These are organonitrogen compounds containing a quaternary ammonium substituted with four alkyl chains.
• External Descriptors: organic chloride salt - quaternary ammonium salt

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Hygroscopic.
• Flash Point(°F): 235.4 °F
• Flash Point(°C): 132℃
• Molecular Weight: 404.200 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 21
• Exact Mass: 403.394 Da
• Monoisotopic Mass: 403.394 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 27
• Formal Charge: 0
• Complexity: 220.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

References

1. Junyi Huang, Jianfeng Ding, Furui Tan, Yueyue Gao, Xiayao Lu, Chen Dong, Gentian Yue, Xiaobao Xu, Liming Ding.  (2023)  A hybrid quantum dot:MXene bulk heterojunction for an efficient infrared self-powered photodetector.  Journal of Materials Chemistry C,  11  (48): (17106-17114).  [PMID:] [10.1039/D3TC03254J]

2. Nian Zhang, Fujian Li, Haiyang Xue, Zhongzhi Wang, Sen Qiu, Bangyu Fan, Yanyan Cheng, Xiangping Zhang.  (2023)  High-efficiency process of aluminum removal from rare earth solutions using a readily industrialized ionic liquid.  HYDROMETALLURGY,      [PMID:] [10.1016/j.hydromet.2023.106224]

3. Jiangping Cao, Lei Shi, Yifei He, Tingting Wang, Baizhao Zeng, Faqiong Zhao.  (2023)  An effervescence-assisted microextraction for parabens in foodstuffs based on deep eutectic solvent composed of methyltrioctyl ammonium chloride and decanoic acid.  FOOD CHEMISTRY,      [PMID:37683492] [10.1016/j.foodchem.2023.137348]

4. Jia-qi Wen, Qing-nan Chen, Hui-xin Ji, Xiao-ting Zhang, Shuang Hu, Yun-e Bai, Jian-ping Gao.  (2023)  Simultaneous determination of five compounds in Codonopsis Radix using a hydrophobic deep eutectic solvent based on vortex-assisted dispersive liquid-liquid microextraction coupled with HPLC.  MICROCHEMICAL JOURNAL,      [PMID:] [10.1016/j.microc.2023.109197]

5. Fu Wan, Cong Zhou, Afang Liu, Tiantai Kang, Pengcheng Liao, Shuping Liu, Shihui Si.  (2023)  Salting-out assisted acidic deep eutectic solvent Liquid-Liquid extraction of 2,3-Butanediol from aqueous Solutions: Green and sustainable approach.  MICROCHEMICAL JOURNAL,      [PMID:] [10.1016/j.microc.2023.109101]

6. Long Wu, Zan Ge, Wei Li, Feng Chen, Zeping Zhou.  (2023)  Multi-stimuli Responsive Composite for heavy metal detection Based on Mesoporous Silica and Polyelectrolyte Brush.  International Journal of Electrochemical Science,      [PMID:] [10.20964/2020.01.85]

7. Yuzhen Wang, Pengfei Wang, Huihui Xie, Ming Tan, Lingyun Wang, Yang Liu, Yang Zhang.  (2023)  Mechanistic investigation of intensified separation of molybdenum(VI) and vanadium(V) using polymer inclusion membrane electrodialysis.  JOURNAL OF HAZARDOUS MATERIALS,      [PMID:37236110] [10.1016/j.jhazmat.2023.131671]

8. Min Wang, Luyao Zhao, Yu Niu, Shu Qin, Lixin Zhang, Liyan Jia, Xu Jing.  (2023)  Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography.  Food Chemistry-X,      [PMID:37397198] [10.1016/j.fochx.2023.100711]

9. Yu Xu, Ang Li, Song Xue, Sihui Ding, Qi Zhang.  (2023)  Chiral separation by capillary electrokinetic chromatography with hydrophobic deep eutectic solvents as pseudo-stationary phases.  TALANTA,      [PMID:37121143] [10.1016/j.talanta.2023.124556]

10. Huan-Xing Zhou, Qing-Qing Sun, Zhong-Qiu Liu, Jie-Wen Duan, Tingjun Fu, Yujing Liu, Anguo Ying.  (2023)  Polyacrylonitrile fiber with light-driven intelligent reversible and switchable wettability as an environmental benign solid base for biodiesel production.  Journal of Cleaner Production,      [PMID:] [10.1016/j.jclepro.2023.137101]

11. Zihao Ma, Ying Han, Fuqiong Xu, Xing Wang.  (2023)  Lignin-based hydrophobic DESs extracts Sudan dyes from aqueous solution.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:37003380] [10.1016/j.ijbiomac.2023.124265]

12. Yu Qin, Run-Qin Wang, Rong-Rong Xing, Li Yang, Xuan Chen, Shuang Hu.  (2023)  Dispersive liquid-liquid microextraction based on a supramolecular solvent followed by high-performance liquid chromatographic analysis of lignans in Forsythiae Fructus.  JOURNAL OF SEPARATION SCIENCE,  46  (5): (2200719).  [PMID:36597011] [10.1002/jssc.202200719]

13. Peng Cao, Xue Bai, Yufeng He, Pengfei Song, Rongmin Wang, Junchao Huang.  (2022)  Nano-assemblies of phosphonium-functionalized diblock copolymers with fabulous antibacterial properties and relationships of structure-activity.  Journal of Materials Chemistry B,  10  (44): (9202-9215).  [PMID:36317705] [10.1039/D2TB01778D]

14. Keyu Zhu, Qifeng Wei, Kang Liu, Huaquan Li, Xiulian Ren.  (2022)  Design and combination of magnetic ionic liquids and hydrophobic deep eutectic solvents for safer extraction of titanium: physicochemical properties and toxicity studies.  GREEN CHEMISTRY,  24  (19): (7481-7491).  [PMID:] [10.1039/D2GC01874H]

15. Liu Hongyan, Guo Chengxin, Cui Yingna, Yin Jingmei, Li Shenmin.  (2022)  Experimental and modeling investigation of organic modified montmorillonite with octyl quaternary ammonium salt.  Scientific Reports,  12  (1): (1-10).  [PMID:35995917] [10.1038/s41598-022-18253-1]

16. Wenfeng Xue, Ronghao Liu, Xiaoxia Liu, Yangyang Wang, Ping Lv, Yanzhao Yang.  (2022)  Selective extraction of Nd(III) by novel carboxylic acid based ionic liquids without diluent from waste NdFeB magnets.  JOURNAL OF MOLECULAR LIQUIDS,      [PMID:] [10.1016/j.molliq.2022.119919]

17. Yuanzuo Zou, Dan Wang, Jingzhou Guo, Junwei Yang, Yuan Pu, Jian-Feng Chen.  (2022)  Synthesis of poly(9,9-dioctylfluorene) in a rotating packed bed with enhanced performance for polymer light-emitting diodes.  Polymer Chemistry,  13  (23): (3506-3512).  [PMID:] [10.1039/D2PY00297C]

18. Fuqiong Xu, Zihao Ma, Xing Wang, Qingyu Wang, Ying Han, Yao Li, Guangwei Sun.  (2022)  From liquid hot water pretreatment solution to lignin-based hydrophobic deep eutectic solvent for highly efficient extraction of Cr (VI).  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:35367274] [10.1016/j.ijbiomac.2022.03.190]

19. Ningyue Yu, Linzhou Zhao, Danling Cheng, Mengbin Ding, Yan Lyu, Jinhua Zhao, Jingchao Li.  (2022)  Radioactive organic semiconducting polymer nanoparticles for multimodal cancer theranostics.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:35397457] [10.1016/j.jcis.2022.03.107]

20. Han Jia, Shaoyan Wang, Zhe Wang, Qiang Wang, Haidong Jia, Lin Song, Xuwen Qin, Fangning Fan, Zhe Li, Pan Huang.  (2021)  Investigation of anionic group effects on the shale inhibition performance of fatty acid-based ionic liquids and their inhibition mechanism.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2021.128135]

21. Weitai Yu, Zhan Wei, Jiaqi Chen, Pengcheng Lin, Xi Zhao, Ying Chen.  (2021)  Magnetic all-inorganic perovskite nanocrystals demonstrating well-defined hybrid structure and superhydrophobic behavior towards movable and stable photoluminescence.  JOURNAL OF LUMINESCENCE,      [PMID:] [10.1016/j.jlumin.2021.118629]

22. Han Jia, Shaoyan Wang, Yingbiao Xu, Tingyi Wang, Lingyu Zhang, Jinyong Song, Xuehao Zhang, Lin Song, Haidong Jia, Hui Yan.  (2021)  Systematic investigation on the abnormal surface and interfacial activity of fatty acid ionic liquids.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2021.127902]

23. Zhao-chan Liu, Li Yang, Rong-rong Xing, Xuan Chen, Xiao-hong Bai, Shuang Hu.  (2021)  Three phase dispersive liquid-liquid microextraction (DLLME) based on reverse micelles for the enrichment of Q-markers of cinnamic acids in traditional Chinese medicine.  INSTRUMENTATION SCIENCE & TECHNOLOGY,      [PMID:] [10.1080/10739149.2021.1935273]

24. Setareh Rostami-Javanroudi, Masoud Moradi, Kiomars Sharafi, Nazir Fattahi.  (2021)  Novel hydrophobic deep eutectic solvent for vortex-assisted liquid phase microextraction of common acaricides in fruit juice followed by HPLC-UV determination.  RSC Advances,  11  (48): (30102-30108).  [PMID:35480276] [10.1039/D1RA04781G]

25. Xingyun Li, Bin Han, Yaojie Xu, Xiao Liu, Chunhui Zhao, Jun Xu.  (2021)  Conjugated polymer coating enabled light-resistant black phosphorus with enhanced stability.  Nanoscale Advances,  3  (19): (5650-5655).  [PMID:36133262] [10.1039/D1NA00403D]

26. Jing Li, Yanjun Jiao, Qin Luo, Weixin Hu, Shenwen Fang, Chunling Tang, Qiang Liu.  (2021)  Treatment of oil-based drill cuttings by hydrophobic deep eutectic solvents.  CANADIAN JOURNAL OF CHEMICAL ENGINEERING,  100  (8): (1747-1754).  [PMID:] [10.1002/cjce.24263]

27. Fujian Li, Junjun Yan, Xiangping Zhang, Na Wang, Haifeng Dong, Lu Bai, Hongshuai Gao.  (2021)  Removal of Trace Aluminum Impurity for High-Purity GdCl3 Preparation using an Amine-Group-Functionalized Ionic Liquid.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.1c00870]

28. Ying Chu, Ximing Cui, Weilun Kong, Keya Du, Liang Zhen, Liqiu Wang.  (2021)  A robust polymeric binder based on complementary multiple hydrogen bonds in lithium-sulfur batteries.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2021.130844]

29. Liu Weiwei, Li Qian, Zhang Yin, Liu Tengfei, Wang Li, Li Huayi, Hu Youliang.  (2021)  Continuous-flow RAFT copolymerization of styrene and maleic anhydride: acceleration of reaction and effect of polymerization conditions on reaction kinetics.  Journal of Flow Chemistry,  11  (4): (867-875).  [PMID:] [10.1007/s41981-021-00167-0]

30. Qingbin He, Yanjie Zhang, Haolong Li, Quan Chen.  (2020)  Rheological Properties of ABA-Type Copolymers Physically End-Cross-Linked by Polyoxometalate.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.0c01817]

31. Shuyue Zhao, Wenjun Huang, Changrong Wang, Yaping Wang, YuFeng Zhang, Zhanpeng Ye, Jianhua Zhang, Liandong Deng, Anjie Dong.  (2020)  Screening and Matching Amphiphilic Cationic Polymers for Efficient Antibiosis.  BIOMACROMOLECULES,      [PMID:33226784] [10.1021/acs.biomac.0c01330]

32. Lei Tian, LinQing Huang, Jiacong Xu, Xiaoqiang Yu, Zhifeng Xu.  (2020)  Study on the solvent extraction of thioarsenite in alkaline solutions with transformed quaternary ammonium salt.  HYDROMETALLURGY,      [PMID:] [10.1016/j.hydromet.2020.105528]

33. Menglei Zhang, Hao Song, Chenghang Zheng, Zhenglong Lin, Yi Liu, Weihong Wu, Xiang Gao.  (2020)  Highly efficient recovery of molybdenum from spent catalyst by an optimized process.  JOURNAL OF THE AIR & WASTE MANAGEMENT ASSOCIATION,      [PMID:32633619] [10.1080/10962247.2020.1792377]

34. Qiyu Meng, Jiemiao Yu, Liangrong Yang, Yanqing Li, Mo Xian, Huizhou Liu.  (2020)  Efficient recovery of bio-based 1,2,4-butanetriol by using boronic acid anionic reactive extraction.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2020.117728]

35. Shaoping Ma, Fenfang Li, Liangliang Liu, Liping Liao, Li Chang, Zhijian Tan.  (2020)  Deep-eutectic solvents simultaneously used as the phase-forming components and chiral selectors for enantioselective liquid-liquid extraction of tryptophan enantiomers.  JOURNAL OF MOLECULAR LIQUIDS,      [PMID:] [10.1016/j.molliq.2020.114106]

36. Tiemei Li, Yuefei Song, Zhaoqi Dong, Yueyue Shi, Jing Fan.  (2020)  Hydrophobic deep eutectic solvents as extractants for the determination of bisphenols from food-contacted plastics by high performance liquid chromatography with fluorescence detection.  JOURNAL OF CHROMATOGRAPHY A,      [PMID:32327226] [10.1016/j.chroma.2020.461087]

37. Wenjing Li, Xuelin Dong, Lihua Zhu, Heqing Tang.  (2020)  Highly selective separation of Re(VII) from Mo(VI) by using biomaterial-based ionic gel adsorbents: Extractive adsorption enrichment of Re and surface blocking of Mo.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2020.124078]

38. Tiemei Li, Yuefei Song, Jingmai Li, Mengnan Zhang, Yueyue Shi, Jing Fan.  (2019)  New low viscous hydrophobic deep eutectic solvents in vortex-assisted liquid-liquid microextraction for the determination of phthalate esters from food-contacted plastics.  FOOD CHEMISTRY,      [PMID:31670128] [10.1016/j.foodchem.2019.125752]

39. Zhao-chan Liu, Shu-mei Zhang, Run-qin Wang, Xuan Chen, Shuang Hu, Xiao-hong Bai.  (2019)  Comparison of three-phase hollow fiber liquid-phase microextraction based on reverse micelle with conventional two-phase hollow fiber liquid-phase microextraction and their applications for analysis of cinnamic acids in traditional Chinese medicines.  JOURNAL OF SEPARATION SCIENCE,  42  (18): (2977-2984).  [PMID:31273922] [10.1002/jssc.201900472]

40. Miao Luo, Sheng Wang, Chengpeng Li, Wangen Miao, Xiang Ma.  (2019)  Aggregation-induced emission organogel formed by both sonication and thermal processing based on tetraphenylethylene and cholesterol derivative.  DYES AND PIGMENTS,      [PMID:] [10.1016/j.dyepig.2019.02.041]

41. Tiemei Li, Yuefei Song, Jingjie Xu, Jing Fan.  (2018)  A hydrophobic deep eutectic solvent mediated sol-gel coating of solid phase microextraction fiber for determination of toluene, ethylbenzene and o-xylene in water coupled with GC-FID.  TALANTA,      [PMID:30625546] [10.1016/j.talanta.2018.11.085]

42. Ying Chu, Ximing Cui, Qinmin Pan.  (2018)  Realizing High-Performance Sulfur Cathodes through a Self-Healing and Confining Strategy.  ACS Applied Energy Materials,      [PMID:] [10.1021/acsaem.8b01324]

43. Yinge Bai, Ruiyi Yan, Feng Huo, Jianguo Qian, Xiangping Zhang, Suojiang Zhang.  (2017)  Recovery of methacrylic acid from dilute aqueous solutions by ionic liquids though hydrogen bonding interaction.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2017.05.013]

44. Kaisheng Yao, Zhiyong Li, Xinying Li, Weiwei Lu, Airong Xu, Hucheng Zhang, Jianji Wang.  (2017)  Tunable Synthesis of Ag Films at the Interface of Ionic Liquids and Water by Changing Cationic Structures of Ionic Liquids.  CRYSTAL GROWTH & DESIGN,      [PMID:] [10.1021/acs.cgd.6b01196]

45. Yue Yang, Boyi Xie, Ruixiang Wang, Shengming Xu, Jianlong Wang, Zhenghe Xu.  (2016)  Extraction and separation of tungsten from acidic high-phosphorus solution.  HYDROMETALLURGY,      [PMID:] [10.1016/j.hydromet.2016.05.018]

46. Miao Luo, Sheng Wang, Meiling Wang, Shaorong Huang, Chengpeng Li, Lin Chen, Xiang Ma.  (2016)  Novel organogel harnessing Excited-State Intramolecular Proton Transfer process with aggregation induced emission and photochromism.  DYES AND PIGMENTS,      [PMID:] [10.1016/j.dyepig.2016.04.036]

47. Pei Yuanchao, Cao Yuan, Huang Yanjie, Song Xinxin, Wang Huiyong, Zhao Yuling, Wang Jianji.  (2016)  Tunable LCST-type phase behavior of [FeCl4]--based ionic liquids in water.  Science China-Chemistry,  59  (5): (587-593).  [PMID:] [10.1007/s11426-016-5577-0]

48. Qiang Huang, Jianping Liu.  (2013)  Facile and Clean Solution Synthesis of Large-Scale ZnO Nanorods Assisted with Aliquat 336.  Journal of Chemistry,      [PMID:] [10.1155/2013/409639]

49. Ze Zhong, Jian Liu, Zhi Yuan Xie, Zhi Yuan Wang.  (2013)  Significant Efficiency Enhancement of Bulk Heterojunction Organic Photovoltaics Using Solution-Processable Interfacial Bilayers.  ChemElectroChem,  1  (2): (471-475).  [PMID:] [10.1002/celc.201300002]

50. Chao Cui, Bin Hu, Beibei Chen, Man He.  (2013)  Ionic liquid-based magnetic solid phase extraction coupled with inductively coupled plasma-optical emission spectrometry for the determination of Cu, Cd, and Zn in biological samples.  JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY,  28  (7): (1110-1117).  [PMID:] [10.1039/C3JA50108F]

51. Yang Gao, Yihu Song, Qiang Zheng.  (2012)  Miniemulsion polymerized titania/polystyrene core–shell nanocomposite particles based on nanotitania powder: Morphology, composition and suspension rheology.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2012.06.043]

52. Tianlei Yang, Shen Zhao, Jie Wang, Mingqi Guo, Yueping Guan, Tao Li.  (2025)  An innovative microextraction material for efficient and selective extraction of gold: Magnetic oil-based gel microspheres containing Aliquat 336.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.161165]

53. Wenli He, Yaqin Sun, Xu Zhou, Lusheng Huang, Zhilong Xiu.  (2025)  Partition behavior and extraction mechanism of carboxylic acids in hydrophobic deep eutectic solvents of TOMAC and medium-chain fatty acids.  CHEMICAL ENGINEERING SCIENCE,      [PMID:] [10.1016/j.ces.2025.121231]

54. Xiangbin Sun, Xiaobing Ma, Yufeng He, Pengfei Song, Rongmin Wang.  (2025)  pH triggered polycarvacrol-based antibacterial microspheres: Integrated offensive and defensive platform.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2025.113811]

55. Guomeng Li, Xudong Zheng, Xi Zhang, Youming Zhu, Lin Guo, Jinfeng Mei, Xiukun Ge, Zhongyu Li.  (2024)  Preparation of imprinted cryogels of cellulose cross-linked ionic liquids for selective separation of Gd(III) from rare earth leachate.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2024.129445]

56. Kejia Ning, Jingzheng Wang, Li Zhang, Mengting Hong, Biao Fu, Jiushuai Deng, Xiahui Gui, Yaowen Xing, Guixia Fan, Hongxiang Xu.  (2025)  The Separation of Y and Er Based on the Synergistic Effect of [N1444][P507] and TRPO.  Minerals,  15  (2): (153).  [PMID:] [10.3390/min15020153]

57. Li Jigang, Zhao Panchao, Yi Wei.  (2025)  Purification and densification of Ir by hydrometallurgical combined with powder metallurgical process.  Discover Nano,  20  (1): (1-17).  [PMID:40758199] [10.1186/s11671-025-04310-x]

58. Xin Di, Xiaojun Zhao, Xiaoli Guo.  (2020)  Hydrophobic deep eutectic solvent as a green extractant for high-performance liquid chromatographic determination of tetracyclines in water samples.  JOURNAL OF SEPARATION SCIENCE,  43  (15): (3129-3135).  [PMID:32506795] [10.1002/jssc.202000477]

59. Yao Ma, Qing-nan Chen, Rui Liao, Yun-e Bai, Jian-kuan Li, Shuang Hu, Jian-ping Gao.  (2025)  A cyclodextrin-deep eutectic solvent-based dispersive liquid-liquid microextraction method for quantitative determination of small molecules in fresh-cut Codonopsis Radix.  JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES,      [PMID:41223717] [10.1016/j.jchromb.2025.124844]

60. Gaojin Zhou, Zhaojin Zhang, Subhan Mahmood, Jie Tang, Shun Yao.  (2025)  Combined use of ionic liquid micelles and natural carbon dots@deep eutectic solvent (CDs@DES) to extract and separate flavonoids and terpenoids from Ginkgo biloba leaves.  JOURNAL OF CHROMATOGRAPHY A,      [PMID:41275820] [10.1016/j.chroma.2025.466553]

61. Ranran Cao, Mantang Chen, Haidong Gao, Wei Luo, Huapeng Cui, Xuejie Li, Xiaoyu Wang, Fuwei Xie, Cong Nie, Libin Wan.  (2026)  Recovery of the Template in Molecular Imprinting: Liquid-Phase Microextraction or Electromembrane Extraction?.  ACS Omega,      [PMID:41726595] [10.1021/acsomega.5c11315]

62. Xiuting Wu, Tianjun Hu, Qingsong Shan, Hong Zhong, Yuqin Su, Linxiang Yang, Beichen Yuan, Junhui Dai, Yuhao Zhang, Qiangyu Dai, Xiaoming Li, Haibo Zeng.  (2026)  Ligand-Mediated Intergrain Isolation Strategy for Narrow-Emission Deep-Blue Perovskite Quantum Dot Light-Emitting Diodes.  ACS Photonics,      [PMID:] [10.1021/acsphotonics.6c00072]