Pentamethylcyclopentadienylrhodium(III) chloride dimer - ≥99% , CAS No.12354-85-7

CAS: 12354-85-7 Cat. No.: P124122 Molecular Weight: 618.08 EC Number: 625-704-0
AVAILABLE TO ORDER
GRADE & PURITY ≥99%
Synonyms
Chiralyst P618
Storage
Argon charged,Room temperature
Shipped In
Normal
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Size
Status
Price
Qty
100mg
P124122-100mg
3
$199.90
250mg
P124122-250mg
3
$314.90
500mg
P124122-500mg
3
$602.90
1g
P124122-1g
3
$1,199.90
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Why this grade

≥99% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Argon charged,Room temperature Ships Normal Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

📚

Literature proof

Cited in 9 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Catalyst for: Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond Amidation reactions Reductive alkylation reactions


Product class
M-C, Homogeneous Catalysts, Arene/Aryl Ligands

Reaction type
Hydrogenation, CH-Activation, Transfer Hydrogenation, Oxidation

Chemical properties

Chemical formula

C20H30Cl4Rh2

Empirical formula

[Rh(C5Me5)Cl2]2

Molecular weight

618.08

Metal

Rh

Theoretical metal content

33

Physical state

crystalline

Color

red

Specifications

Synonyms
Chiralyst P618
Specifications & Purity
≥99%
Legal Information
Product of Umicore
Storage
Argon charged, Room temperature
Shipped In
Normal
Purity
≥99%
Names and Identifiers
Canonical SmilesCl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChIKeyQNIVKTTWBMFSBR-UHFFFAOYSA-J
INCHI1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
WGK Germany 3
Molecular Weight 618.08

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

14 results found

Lot NumberCertificate TypeDateItem
F2216190Certificate of AnalysisMar 09, 2026 P124122
F2216191Certificate of AnalysisMar 09, 2026 P124122
F2216192Certificate of AnalysisMar 09, 2026 P124122
J2116336Certificate of AnalysisJul 23, 2025 P124122
J2116337Certificate of AnalysisJul 23, 2025 P124122
J2116341Certificate of AnalysisJul 23, 2025 P124122
J2116589Certificate of AnalysisJul 23, 2025 P124122
F2130227Certificate of AnalysisApr 03, 2025 P124122
F2130241Certificate of AnalysisApr 03, 2025 P124122
L1827081Certificate of AnalysisOct 18, 2022 P124122
J2510044Certificate of AnalysisFeb 21, 2022 P124122
F2421031Certificate of AnalysisSep 15, 2021 P124122
L2320108Certificate of AnalysisSep 15, 2021 P124122
L2320142Certificate of AnalysisSep 15, 2021 P124122

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Chemical and Physical Properties
SolubilitySoluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
SensitivityAir and moisture sensitive
Melt Point(°C)>300°C
Documents & Articles
Citations of This Product
References
1. Ying Zhang, Bin Wei, Hao Liang.  (2023)  Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization.  ACS Applied Materials & Interfaces,      [PMID:36609187] [10.1021/acsami.2c18440]
2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang.  (2022)  Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications.  ANALYTICA CHIMICA ACTA,      [PMID:36192064] [10.1016/j.aca.2022.340393]
3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li.  (2022)  Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer.  ACS Applied Materials & Interfaces,      [PMID:35986690] [10.1021/acsami.2c11174]
4. Yuanyuan Zhang, Jian Liu.  (2022)  Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction.  CHEMISTRY-A EUROPEAN JOURNAL,  28  (55): (e202201430).  [PMID:35758216] [10.1002/chem.202201430]
5. Fang Lan, Qin Wang, Hui Chen, Yi Chen, Yuanyuan Zhang, Bowen Huang, Hongbo Liu, Jian Liu, Run Li.  (2020)  Preparation of Hydrophilic Conjugated Microporous Polymers for Efficient Visible Light-Driven Nicotinamide Adenine Dinucleotide Regeneration and Photobiocatalytic Formaldehyde Reduction.  ACS Catalysis,      [PMID:] [10.1021/acscatal.0c03652]
6. Yizhou Wu, Jesse Ward-Bond, Donglin Li, Shaohua Zhang, Jiafu Shi, Zhongyi Jiang.  (2018)  g-C3N4@α-Fe2O3/C Photocatalysts: Synergistically Intensified Charge Generation and Charge Transfer for NADH Regeneration.  ACS Catalysis,      [PMID:] [10.1021/acscatal.8b00070]
7. Shihao Li, Jiafu Shi, Yu Chen, Xinyu Mao, Shusong Liu, Yang Yang, Hong Wu, Zhongyi Jiang.  (2025)  Light-Driven Synthesis of 2-Aminoethanol from Formaldehyde and Ammonia.  ACS Catalysis,      [PMID:] [10.1021/acscatal.5c00337]
8. Xinyu Chen, Jiahui Xie, Hui Wang, Yujie Tang, Yezhou Yang, Pilang Zheng, Qihua Yang, Xin Liu, Xiaobo Li.  (2025)  Multifunctional Nano-COF-Embedded Silica Composite for Efficient Photocatalytic NADH Regeneration.  CHEMISTRY-A EUROPEAN JOURNAL,      [PMID:40350757] [10.1002/chem.202500115]
9. Shihao Li, Jiafu Shi, Yu Chen, Hong Wu, Zhongyi Jiang.  (2026)  Engineering substrate reduction and product oxidation in photocatalytic NADH synthesis via interface–pore co-confinement.  AICHE JOURNAL,      [PMID:] [10.1002/aic.70263]
Solution Calculators
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