Methyl nadic anhydride - ≥95%, mixture of isomers , CAS No.25134-21-8

CAS: 25134-21-8 Cat. No.: M106667 Molecular Weight: 178.18 Beilstein Registry Number: 162395 EC Number: 246-644-8
AVAILABLE TO ORDER
GRADE & PURITY ≥95% mixture of isomers
Synonyms
Methyl-3,6-endomethylenetetrahydrophthalic Anhydride | Methylnadic Anhydride | Methyl-5-norbornene-2,3-dicarboxylic Anhydride | MNA
Storage
Argon charged,Room temperature
Shipped In
Normal
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Size
Status
Price
Qty
25g
M106667-25g
3
$9.90
100g
M106667-100g
3
$11.90
500g
M106667-500g
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$46.90
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Why this grade

≥95%, mixture of isomers for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Argon charged,Room temperature Ships Normal Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 19 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Epoxy embedding medium is generally used for biological tissues during study by electron microscopy. Usually, it consists of three components; Epon 812 resin, an anhydride hardener and an accelerator.

It was used during transmission electron microscopy done for the analysis of epithelial cells; during a study performed to understand the epithelial cell growth and stratification in minimal culture conditions.

Specifications

Synonyms
Methyl-3, 6-endomethylenetetrahydrophthalic Anhydride | Methylnadic Anhydride | Methyl-5-norbornene-2, 3-dicarboxylic Anhydride | MNA
Specifications & Purity
≥95%, mixture of isomers
Storage
Argon charged, Room temperature
Shipped In
Normal
Purity
≥95%
Names and Identifiers
WGK Germany 3
RTECS RB9100000
UN Number 3265
Molecular Weight 178.18
Beilstein 162395

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

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✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

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📊 Datasheet

Quick-reference summary of product specifications and applications.

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🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

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Advanced Data

Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

34 results found

Lot NumberCertificate TypeDateItem
B2602164Certificate of AnalysisJan 22, 2026 M106667
B2602219Certificate of AnalysisJan 22, 2026 M106667
B2602221Certificate of AnalysisJan 22, 2026 M106667
B2602227Certificate of AnalysisJan 22, 2026 M106667
A2218601Certificate of AnalysisNov 05, 2025 M106667
A2218588Certificate of AnalysisNov 05, 2025 M106667
I2107315Certificate of AnalysisJun 10, 2025 M106667
I2107314Certificate of AnalysisJun 10, 2025 M106667
F2504471Certificate of AnalysisMay 26, 2025 M106667
F2504470Certificate of AnalysisMay 26, 2025 M106667
F2504469Certificate of AnalysisMay 26, 2025 M106667
H2419377Certificate of AnalysisAug 06, 2024 M106667
F2427236Certificate of AnalysisMar 26, 2024 M106667
D2412379Certificate of AnalysisMar 26, 2024 M106667
D2424476Certificate of AnalysisMar 26, 2024 M106667
D2428365Certificate of AnalysisMar 15, 2024 M106667
C2408466Certificate of AnalysisMar 04, 2024 M106667
G2430492Certificate of AnalysisMar 04, 2024 M106667
C2408481Certificate of AnalysisMar 04, 2024 M106667
F2405492Certificate of AnalysisMar 04, 2024 M106667
F2420038Certificate of AnalysisMar 04, 2024 M106667
F2420039Certificate of AnalysisMar 04, 2024 M106667
C2408488Certificate of AnalysisMar 04, 2024 M106667
C2408491Certificate of AnalysisMar 04, 2024 M106667
L2311290Certificate of AnalysisNov 24, 2023 M106667
L2311292Certificate of AnalysisNov 24, 2023 M106667
L2311294Certificate of AnalysisNov 24, 2023 M106667
L2311298Certificate of AnalysisNov 24, 2023 M106667
L2311300Certificate of AnalysisNov 24, 2023 M106667
D2109300Certificate of AnalysisMay 19, 2023 M106667
E2327328Certificate of AnalysisMay 06, 2023 M106667
E2326811Certificate of AnalysisMay 06, 2023 M106667
E2326803Certificate of AnalysisMay 06, 2023 M106667
A2218603Certificate of AnalysisDec 18, 2021 M106667

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Chemical and Physical Properties
SolubilityMiscible with acetone, benzene, naphtha and xylene.
SensitivityMoisture sensitive
Refractive Index1.506-1.508
Flash Point(°F)275 °F
Flash Point(°C)135℃
Boil Point(°C)140°C
Documents & Articles
Citations of This Product
References
1. Tian Zhao, Yalin Zhao, Zhicong Miao, Zhen Geng, Zhengrong Zhou, Tao Wang, Rongjin Huang, Laifeng Li.  (2023)  Synthesis and cryogenic performance of closed-loop recycled Al2O3/epoxy resins composites.  Materials Today Sustainability,      [PMID:] [10.1016/j.mtsust.2023.100628]
2. Meiying Ge, Guozheng Liang, Aijuan Gu.  (2023)  Structural design strategy of biobased propargyl ether-functionalized epoxy monomer to access low viscosity resin with excellent heat resistance and mechanical properties for advanced composite via VARTM.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2023.146269]
3. Jiaming Liu, Xiaohong Liu, Xiaohua Cui, Jingjing Qin, Mengqin Wu, Lifu Fu, Min Shi, Dingsong Wang, Liyan Liang.  (2023)  Investigation on the properties and structures of resveratrol-derived epoxy thermosets cured with an active ester.  Polymer Chemistry,  14  (14): (1665-1679).  [PMID:] [10.1039/D2PY01579J]
4. Yuan Wang, Liwei Yan, Youquan Ling, Ying Ge, Congshu Huang, Shengtai Zhou, Shuang Xia, Mei Liang, Huawei Zou.  (2022)  Enhanced mechanical and adhesive properties of PDMS coatings via in-situ formation of uniformly dispersed epoxy reinforcing phase.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2022.107319]
5. Dengkang Guo, Sheng Yang, Feng Fu, Gaiyun Li, Fuxiang Chu.  (2022)  New strategy for the preparation of ultra-high-strength wood-epoxy polymer composites.  COMPOSITES COMMUNICATIONS,      [PMID:] [10.1016/j.coco.2022.101191]
6. Dengkang Guo, Nai Guo, Feng Fu, Sheng Yang, Gaiyun Li, Fuxiang Chu.  (2022)  Preparation and mechanical failure analysis of wood-epoxy polymer composites with excellent mechanical performances.  COMPOSITES PART B-ENGINEERING,      [PMID:] [10.1016/j.compositesb.2022.109748]
7. Yuan Wang, Yuanbo Cai, Hao Zhang, Ji Zhou, Shengtai Zhou, Yang Chen, Mei Liang, Huawei Zou.  (2021)  Mechanical and thermal degradation behavior of high-performance PDMS elastomer based on epoxy/silicone hybrid network.  POLYMER,      [PMID:] [10.1016/j.polymer.2021.124299]
8. Ji Bingqiang, Wu Yeping, Zhang Ping, Zhao Xiuli.  (2020)  Mussel inspired interfacial modification of boron nitride/carbon nanotubes hybrid fillers for epoxy composites with improved thermal conductivity and electrical insulation properties.  JOURNAL OF POLYMER RESEARCH,  27  (8): (1-12).  [PMID:] [10.1007/s10965-020-02189-z]
9. Xiaoqian Mi, Liuyue Zhong, Fang Wei, Liang Zeng, Junheng Zhang, Daohong Zhang, Tiwen Xu.  (2019)  Fabrication of halloysite nanotubes/reduced graphene oxide hybrids for epoxy composites with improved thermal and mechanical properties.  POLYMER TESTING,      [PMID:] [10.1016/j.polymertesting.2019.04.007]
10. Bing Tang, Xiaobing Liu, Xiuli Zhao, Junhua Zhang.  (2014)  Highly efficient in situ toughening of epoxy thermosets with reactive hyperbranched polyurethane.  JOURNAL OF APPLIED POLYMER SCIENCE,  131  (16):   [PMID:] [10.1002/app.40614]
11. Jingpeng Li, Xiao Han, Sisi Yao, Dengkang Guo, Fuxiang Chu.  (2024)  Reinforcing flame retardancy, dimensional stability, and high strength of woods for structural applications through surface densification and chemical modification.  INDUSTRIAL CROPS AND PRODUCTS,      [PMID:] [10.1016/j.indcrop.2024.120175]
12. Wenbo Tian, Yu Han, Fei Song, Jialin Fu, Ke Wang, Dongxing Song.  (2025)  Solid-State Norbornadiene Photothermal Films for Efficient Solar Energy Storage.  ADVANCED FUNCTIONAL MATERIALS,  35  (45): (2507162).  [PMID:] [10.1002/adfm.202507162]
13. Jianjun Zhou, Xing Liu, Jianqing Zhao.  (2025)  Design and Synthesis of Reliable Paraffin/Epoxy Phase Change Materials With Excellent Shape Stability and Working Durability for Thermal Energy Regulation.  JOURNAL OF APPLIED POLYMER SCIENCE,      [PMID:] [10.1002/app.57090]
14. Mengke Jing, Shujie Zhang, Sichang Zhang, Mingzhou Li, Fan Chen, Yuchen Ma, Bo Sun.  (2025)  Low MXene Loading of Epoxy Composite with Enhanced Hydrothermal Resistance.  Polymers,  17  (9): (1229).  [PMID:40363019] [10.3390/polym17091229]
15. Zhaohui Lu, Han Zhang, Zhao Lu, Hongbin Tian, Yuan Wang, Shengtai Zhou, Huawei Zou.  (2025)  Achieving Improved Ablative Performance by Enhancing the Interfacial Interaction between Silicone Rubber and Carbon Fiber Reinforcements.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.5c01021]
16. Yang Zhang, Shitian Han, Bojie Fu, Shuai Li, Ziwen Sun, Zhengguang Heng, Shuang Xia, Yang Chen, Liwei Yan, Mei Liang, Huawei Zou.  (2025)  Preparation of Robust Thermal Protection Silicone Rubber by Constructing Interconnected C–Si Hybrid IPNs.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.5c03410]
17. Mengtong Wang, Hao Zhang, Liang Shen, Yingying Du, Changqing Fu.  (2025)  The influence of dicarboxylic acid derivatives synthesized with different anhydride structures on the performance of waterborne epoxy coatings.  Surfaces and Interfaces,      [PMID:] [10.1016/j.surfin.2025.108256]
18. Kai Zhu, Dengyun Li, Baiwen Du, Changxi Yue, Xueyou Zhang, Yin Gao.  (2025)  Semi-conductive Polyethersulfone/Epoxy Coatings with High Heat Resistance and Tensile Shear Strength.  MACROMOLECULAR CHEMISTRY AND PHYSICS,      [PMID:] [10.1002/macp.202500325]
19. Yabing Tian, Peng Wang, Jing Wang, Xujuan Huang, Shibin Shang, Jianxin Jiang, Haibo Zhang, Yuxiang Chen.  (2026)  High-strength and upcyclable bio-based epoxy foams enabled by dynamic networks for multifunctional applications.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2026.175268]
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