Pentamethylcyclopentadienylrhodium(III) chloride dimer - ≥99.95% metals basis , CAS No.12354-85-7

CAS: 12354-85-7 Cat. No.: P284028 Molecular Weight: 618.08 EC Number: 625-704-0
AVAILABLE TO ORDER
GRADE & PURITY ≥99.95% metals basis
Synonyms
Chiralyst P618
Storage
Room temperature,Argon charged
Shipped In
Normal
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Status
Price
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100mg
P284028-100mg
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$219.90
250mg
P284028-250mg
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$388.90

$453.90
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1g
P284028-1g
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$1,459.90

$1,703.90
Save $244.00 (14.32%)
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Why this grade

≥99.95% metals basis for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Room temperature,Argon charged Ships Normal Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 9 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Catalyst for: Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond Amidation reactions Reductive alkylation reactions


Product class
M-C, Homogeneous Catalysts, Arene/Aryl Ligands

Reaction type
Hydrogenation, CH-Activation, Transfer Hydrogenation, Oxidation

Chemical properties

Chemical formula

C20H30Cl4Rh2

Empirical formula

[Rh(C5Me5)Cl2]2

Molecular weight

618.08

Metal

Rh

Theoretical metal content

33

Physical state

crystalline

Color

red

Metal purity

99.95

Specifications

Synonyms
Chiralyst P618
Specifications & Purity
≥99.95% metals basis
Legal Information
Product of Umicore
Storage
Room temperature, Argon charged
Shipped In
Normal
Purity
≥99.95% metals basis
Names and Identifiers
Canonical SmilesCl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
InChIKeyQNIVKTTWBMFSBR-UHFFFAOYSA-J
INCHI1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
WGK Germany 3
Molecular Weight 618.08

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:
Chemical and Physical Properties
SolubilitySoluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
SensitivityAir and moisture sensitive
Melt Point(°C)>300°C
Documents & Articles
Citations of This Product
References
1. Ying Zhang, Bin Wei, Hao Liang.  (2023)  Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization.  ACS Applied Materials & Interfaces,      [PMID:36609187] [10.1021/acsami.2c18440]
2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang.  (2022)  Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications.  ANALYTICA CHIMICA ACTA,      [PMID:36192064] [10.1016/j.aca.2022.340393]
3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li.  (2022)  Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer.  ACS Applied Materials & Interfaces,      [PMID:35986690] [10.1021/acsami.2c11174]
4. Yuanyuan Zhang, Jian Liu.  (2022)  Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction.  CHEMISTRY-A EUROPEAN JOURNAL,  28  (55): (e202201430).  [PMID:35758216] [10.1002/chem.202201430]
5. Fang Lan, Qin Wang, Hui Chen, Yi Chen, Yuanyuan Zhang, Bowen Huang, Hongbo Liu, Jian Liu, Run Li.  (2020)  Preparation of Hydrophilic Conjugated Microporous Polymers for Efficient Visible Light-Driven Nicotinamide Adenine Dinucleotide Regeneration and Photobiocatalytic Formaldehyde Reduction.  ACS Catalysis,      [PMID:] [10.1021/acscatal.0c03652]
6. Yizhou Wu, Jesse Ward-Bond, Donglin Li, Shaohua Zhang, Jiafu Shi, Zhongyi Jiang.  (2018)  g-C3N4@α-Fe2O3/C Photocatalysts: Synergistically Intensified Charge Generation and Charge Transfer for NADH Regeneration.  ACS Catalysis,      [PMID:] [10.1021/acscatal.8b00070]
7. Shihao Li, Jiafu Shi, Yu Chen, Xinyu Mao, Shusong Liu, Yang Yang, Hong Wu, Zhongyi Jiang.  (2025)  Light-Driven Synthesis of 2-Aminoethanol from Formaldehyde and Ammonia.  ACS Catalysis,      [PMID:] [10.1021/acscatal.5c00337]
8. Xinyu Chen, Jiahui Xie, Hui Wang, Yujie Tang, Yezhou Yang, Pilang Zheng, Qihua Yang, Xin Liu, Xiaobo Li.  (2025)  Multifunctional Nano-COF-Embedded Silica Composite for Efficient Photocatalytic NADH Regeneration.  CHEMISTRY-A EUROPEAN JOURNAL,      [PMID:40350757] [10.1002/chem.202500115]
9. Shihao Li, Jiafu Shi, Yu Chen, Hong Wu, Zhongyi Jiang.  (2026)  Engineering substrate reduction and product oxidation in photocatalytic NADH synthesis via interface–pore co-confinement.  AICHE JOURNAL,      [PMID:] [10.1002/aic.70263]
Solution Calculators
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