Ruthenium acetylacetonate - ≥99.8% metals basis , CAS No.14284-93-6

CAS: 14284-93-6 Cat. No.: R639975 Molecular Weight: 398.39 EC Number: 238-193-0 PubChem CID: 5462865
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GRADE & PURITY ≥99.8% metals basis
Synonyms
Ru(acac)3 | Ruthenium(III) acetylacetonate | Tris(2,4-pentanedionato)ruthenium(III) | Acetylacetone Ruthenium(III) Salt
Storage
Room temperature,Argon charged
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R639975-5g
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Why this grade

≥99.8% metals basis for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Room temperature,Argon charged Ships Normal Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 36 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Catalyzes the hydrogenation of dimethyl oxalate to ethylene glycol under mild conditions.


Product class
M-O, Homogeneous Catalysts, Acetylacetonate Ligands


Chemical properties

Chemical formula

C15H21O6Ru

Empirical formula

[Ru(acac)3]

Molecular weight

398.40

Metal

Ru

Theoretical metal content

25

Physical state

powder

Color

red

Specifications

Synonyms
Ru(acac)3 | Ruthenium(III) acetylacetonate | Tris(2, 4-pentanedionato)ruthenium(III) | Acetylacetone Ruthenium(III) Salt
Specifications & Purity
≥99.8% metals basis
Storage
Room temperature, Argon charged
Shipped In
Normal
Purity
≥99.8% metals basis
Names and Identifiers
Pubchem Sid504763838
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/504763838
Canonical SmilesCC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Ru]
IUPAC Name(Z)-4-hydroxypent-3-en-2-one;ruthenium
InChIKeyIYWJIYWFPADQAN-LNTINUHCSA-N
INCHI1S/3C5H8O2.Ru/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/b3*4-3-;
Isomeric SMILES C/C(=C/C(=O)C)/O.C/C(=C/C(=O)C)/O.C/C(=C/C(=O)C)/O.[Ru]
WGK Germany 3
PubChem CID 5462865
Molecular Weight 398.39
Reaxy-Rn 14836316

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

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✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

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📊 Datasheet

Quick-reference summary of product specifications and applications.

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🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

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Advanced Data

3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

12 results found

Lot NumberCertificate TypeDateItem
E2508355Certificate of AnalysisFeb 15, 2025 R639975
E2508375Certificate of AnalysisFeb 15, 2025 R639975
G2508103Certificate of AnalysisFeb 15, 2025 R639975
G2516048Certificate of AnalysisFeb 15, 2025 R639975
K2514074Certificate of AnalysisFeb 15, 2025 R639975
A2515092Certificate of AnalysisJun 06, 2024 R639975
F2420313Certificate of AnalysisJun 06, 2024 R639975
K2422244Certificate of AnalysisJun 06, 2024 R639975
A2416683Certificate of AnalysisJan 31, 2024 R639975
A2416684Certificate of AnalysisJan 31, 2024 R639975
A2416685Certificate of AnalysisJan 31, 2024 R639975
A2416686Certificate of AnalysisJan 31, 2024 R639975

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Chemical and Physical Properties
SolubilitySoluble in most organic solvents such as acetone, chlorinated hydrocarbons, alcohols, cyclohexane and benzene. Insoluble in water.
Melt Point(°C)260°C
Documents & Articles
Citations of This Product
References
1. Xue Yanrong, Zhao Jiwu, Huang Liang, Lu Ying-Rui, Malek Abdul, Gao Ge, Zhuang Zhongbin, Wang Dingsheng, Yavuz Cafer T., Lu Xu.  (2023)  Stabilizing ruthenium dioxide with cation-anchored sulfate for durable oxygen evolution in proton-exchange membrane water electrolyzers.  Nature Communications,  14  (1): (1-13).  [PMID:38062017] [10.1038/s41467-023-43977-7]
2. Qian Chen, Ruonan Wang, Lin Liu, Zhiming Guan, Zhibin Zhu, Lixin Cao, Bohua Dong.  (2023)  Ultra-thin carbon-shell coated Ru/RuO2@C with rich grain boundaries for efficient and durable acidic water oxidation.  CRYSTENGCOMM,  25  (38): (5420-5427).  [PMID:] [10.1039/D3CE00695F]
3. Ruijin Zeng, Linghui Lin, Hexiang Gong, Yuxuan Li, Jianhui Xu, Lingting Huang, Weijun Wang, Sen Lin, Dianping Tang, Shaojun Guo.  (2023)  Tuning the rate-determining step of uric acid electrooxidation over single-atom-site metal centers for high-performing sensing.  Chem Catalysis,      [PMID:] [10.1016/j.checat.2023.100514]
4. Jiancheng Lin, Jingjing Liu, Jin Xu.  (2022)  Ultrasensitive electrochemical immunoassay for screening the influenza A (H1N1) virus based on atomically Ru-dispersed nitrogen-doped carbon.  NEW JOURNAL OF CHEMISTRY,  47  (4): (1685-1690).  [PMID:] [10.1039/D2NJ05383G]
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12. Wei Li, Shuang Wang, Jinping Li.  (2019)  Highly Effective Ru/BaCeO3 Catalysts on Supports with Strong Basic Sites for Ammonia Synthesis.  Chemistry-An Asian Journal,  14  (16): (2815-2821).  [PMID:31187596] [10.1002/asia.201900618]
13. Fan Ye, Fang Wang, Chenchen Meng, Lijie Bai, Junying Li, Pingxing Xing, Botao Teng, Leihong Zhao, Song Bai.  (2018)  Crystalline phase engineering on cocatalysts: A promising approach to enhancement on photocatalytic conversion of carbon dioxide to fuels.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2018.02.046]
14. Zhuoqing Lin, Wenlong Chen, Ying Jiang, Ting Bian, Hui Zhang, Jianbo Wu, Yong Wang, Deren Yang.  (2016)  Facile synthesis of Ru-decorated Pt cubes and icosahedra as highly active electrocatalysts for methanol oxidation.  Nanoscale,  (25): (12812-12818).  [PMID:27297644] [10.1039/C6NR03303B]
15. Yue Shi, Jiawei Fei, Hongdong Li, Caixia Li, Tianrong Zhan, Jianping Lai, Lei Wang.  (2024)  Amorphous Ru-based metallene with monometallic atomic interfaces for electrocatalytic hydrogen evolution in anion exchange membrane electrolyzer.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2024.124465]
16. Yi Liu, Lianrui Cheng, Shuqing Zhou, Chenggong Niu, Tayirjan Taylor Isimjan, Xiulin Yang.  (2024)  Built-in electric field-driven electron transfer behavior at Ru-RuP2 heterointerface fosters efficient and CO-resilient alkaline hydrogen oxidation.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2024.124709]
17. Meng-yuan Ding, Ming-ze Jia, Juan Wang.  (2024)  Insights into performance and mechanism of improving methanol photoreforming on the ternary catalysts with p-n junction.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2024.12.054]
18. Zhiqian Lin, Haoxian Zhu, Liyuan Qian, Xiaohui Tang, Jiangnan Wen, Yun Wang, Xiaofei Wang, Songbai Han, Jinlong Zhu, Haibin Lin, Yusheng Zhao.  (2024)  Modulating the Coordination Chemistry of Cobalt Catalytic Sites by Ruthenium Species to Accelerate the Polysulfide Conversion Kinetics in Lithium-Sulfur Batteries.  CHEMISTRY-A EUROPEAN JOURNAL,  30  (37): (e202400945).  [PMID:38690799] [10.1002/chem.202400945]
19. Yaqi Qu, Hualiang An, Xinqiang Zhao, Yanji Wang.  (2024)  Noble Metal-Coated Cu Nanoparticle Catalysts for Selective Hydrogenation of Nitrobenzene: Modifying Properties of Noble Metal.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.4c03340]
20. Xuanbei Peng, Yongjin Luo, Tianhua Zhang, Jinxiu Deng, Yanliang Zhou, Jiaxin Li, Jun Ni, Bingyu Lin, Jianxin Lin, Dongshuang Wu, Lirong Zheng, Xiuyun Wang, Lilong Jiang.  (2024)  Potassium promoter regulates electronic structure and hydrogen spillover of ultrasmall Ru nanoclusters catalyst for ammonia synthesis.  CHEMICAL ENGINEERING SCIENCE,      [PMID:] [10.1016/j.ces.2024.120021]
21. Mingzhen Li, Yongsheng Li, Zekun Jing, Deshun Huang, Guozong Yue, Yakun Guo, Maobing Shuai.  (2025)  Selective hydrogenation of nitroaromatics catalyzed by surface Pt-rich high-entropy alloy catalysts at room temperature.  Catalysis Science & Technology,      [PMID:] [10.1039/D4CY01542H]
22. Xiaobo Wang, Anru Yan, Ling Zhu, Yanping Yuan, Tian Lan, Xuesheng Liu, Zhiyong Wang.  (2025)  Revealing electric field on low temperature ammonia decomposition activity over ceria-supported catalyst.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:40706363] [10.1016/j.jcis.2025.138480]
23. Shuanglong Zhou, Liang Zhao, Yuanduo Li, Hangkai Shi, Weizhou Wang, Yu Dai, Jianping Lai, Lei Wang.  (2025)  Ruthenium–molybdenum nanoparticles with multi-valence ruthenium species to drive redox electrocatalysis at high current densities.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:41005140] [10.1016/j.jcis.2025.139076]
24. Ziqi Fu, Pengfei Huang, Xiaoyang Wang, Wei-Di Liu, Lingchang Kong, Kang Chen, Jinyang Li, Yanan Chen.  (2025)  Artificial Intelligence-Assisted Ultrafast High-Throughput Screening of High-Entropy Hydrogen Evolution Reaction Catalysts.  Advanced Energy Materials,      [PMID:] [10.1002/aenm.202500744]
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