1,1,1-Tris(hydroxymethyl)propane - ≥98% , CAS No.77-99-6

CAS: 77-99-6 Cat. No.: T110597 Molecular Weight: 134.17 Beilstein Registry Number: 1698309 EC Number: 201-074-9 PubChem CID: 6510
AVAILABLE TO ORDER
GRADE & PURITY ≥98%
Synonyms
Trimethylol propane | Etriol | Ettriol | 2,2-Bis(hydroxymethyl)-1-butanol | TMP (alcohol) | Ethriol | 2-Ethyl-2-(hydroxymethyl)-1,3-propanediol | Trimethylolpropane | Hexaglycerol
Storage
Argon charged,Room temperature
Shipped In
Normal
 ·  off list, applied to all prices below.
Size
Status
Price
Qty
25g
T110597-25g
3
$9.90
100g
T110597-100g
3

$11.90

$15.90
Save $4.00 (25.16%)
500g
T110597-500g
3
$22.90
Enter a quantity for the sizes you want to add.
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Why this grade

≥98% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Argon charged,Room temperature Ships Normal Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 141 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Specifications

Synonyms
Trimethylol propane | Etriol | Ettriol | 2, 2-Bis(hydroxymethyl)-1-butanol | TMP (alcohol) | Ethriol | 2-Ethyl-2-(hydroxymethyl)-1, 3-propanediol | Trimethylolpropane | Hexaglycerol
Specifications & Purity
≥98%
Storage
Argon charged, Room temperature
Shipped In
Normal
Purity
≥98%
Names and Identifiers
Pubchem Sid504751107
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/504751107
Canonical SmilesCCC(CO)(CO)CO
IUPAC Name2-ethyl-2-(hydroxymethyl)propane-1,3-diol
InChIKeyZJCCRDAZUWHFQH-UHFFFAOYSA-N
INCHI1S/C6H14O3/c1-2-6(3-7,4-8)5-9/h7-9H,2-5H2,1H3
Isomeric SMILES CCC(CO)(CO)CO
WGK Germany 1
RTECS TY6470000
PubChem CID 6510
Molecular Weight 134.17
Beilstein 1698309
Reaxy-Rn 1698309

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomOrganic compounds
SuperclassOrganic oxygen compounds
ClassOrganooxygen compounds
SubclassAlcohols and polyols
Intermediate Tree Nodes Not available
Direct ParentPrimary alcohols
Alternative Parents Hydrocarbon derivatives  
Molecular FrameworkAliphatic acyclic compounds
Substituents Hydrocarbon derivative - Primary alcohol - Aliphatic acyclic compound
DescriptionThis compound belongs to the class of organic compounds known as primary alcohols. These are compounds comprising the primary alcohol functional group, with the general structure RCOH (R=alkyl, aryl).
External Descriptors Not available
3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

28 results found

Lot NumberCertificate TypeDateItem
G2205438Certificate of AnalysisApr 03, 2026 T110597
G2504535Certificate of AnalysisJun 05, 2025 T110597
L2526254Certificate of AnalysisJun 05, 2025 T110597
L2526253Certificate of AnalysisJun 05, 2025 T110597
L2526252Certificate of AnalysisJun 05, 2025 T110597
H2522713Certificate of AnalysisJun 05, 2025 T110597
H2522712Certificate of AnalysisJun 05, 2025 T110597
H2522711Certificate of AnalysisJun 05, 2025 T110597
H2522538Certificate of AnalysisJun 05, 2025 T110597
G2504534Certificate of AnalysisJun 05, 2025 T110597
G2504327Certificate of AnalysisJun 05, 2025 T110597
D2509514Certificate of AnalysisMar 28, 2025 T110597
D2509598Certificate of AnalysisMar 28, 2025 T110597
D2509597Certificate of AnalysisMar 28, 2025 T110597
D2509515Certificate of AnalysisMar 28, 2025 T110597
D2509596Certificate of AnalysisMar 28, 2025 T110597
F2412402Certificate of AnalysisMay 27, 2024 T110597
F2412388Certificate of AnalysisMay 27, 2024 T110597
F2412384Certificate of AnalysisMay 27, 2024 T110597
A2408026Certificate of AnalysisNov 08, 2022 T110597
K2218779Certificate of AnalysisNov 08, 2022 T110597
K2218780Certificate of AnalysisNov 08, 2022 T110597
K2218781Certificate of AnalysisNov 08, 2022 T110597
K2218782Certificate of AnalysisNov 08, 2022 T110597
K2218787Certificate of AnalysisNov 08, 2022 T110597
I1817137Certificate of AnalysisJul 20, 2022 T110597
G2205437Certificate of AnalysisJun 15, 2022 T110597
G2205436Certificate of AnalysisJun 15, 2022 T110597

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Chemical and Physical Properties
SolubilitySoluble in water.
SensitivityHygroscopic.
Flash Point(°F)356 °F
Flash Point(°C)172 °C
Boil Point(°C)149°C/2mmHg
Melt Point(°C)58°C
Molecular Weight134.170 g/mol
XLogP3-0.800
Hydrogen Bond Donor Count3
Hydrogen Bond Acceptor Count3
Rotatable Bond Count4
Exact Mass134.094 Da
Monoisotopic Mass134.094 Da
Topological Polar Surface Area60.700 Ų
Heavy Atom Count9
Formal Charge0
Complexity60.400
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
The total count of all stereochemical bonds0
Covalently-Bonded Unit Count1
Documents & Articles
Adding a Temperature-Triggered Switch to NCO: How Blocked Isocyanates Affect the Storage, Curing, and Film Performance of 1K Baking Coatings
Alkyd Resins: From Oil/Fatty-Acid-Modified Polyesters to Autoxidative Drying — Understanding Their Structure and Film-Formation Mechanism
How Do Isocyanates and Polyols Affect the Performance of Polyurethane Coating Films: Structure, Raw Material Selection, and Performance Design Essentials
Comprehensive Performance Analysis of Polyurethane Coating Films: Soft/Hard Segment Structure, Microphase Separation, Crosslinking and Curing, and Selection of Representative Chemicals
When Should You Choose Silicone Resin? Selection Comparison with Epoxy, Acrylic, Polyurethane, Fluororesin, and Other Coating Resins
Understanding Polyester Resins for Coatings: Structure Design, Key Indicators, and Coating Film Performance
Polyurethane Coating Resins: Not a Single Resin, but a Designable High-Performance System
Phenolic-Modified Alkyd Resin: Performance Enhancement and Applications in Fast-Drying Industrial Coatings
Applications of Rosin and Modified Rosin Resins in Coatings and Inks: Structure–Property Relationships, Modification Pathways, and Usage Guidelines
Cashew Nut Shell Liquid (CNSL): From Cashew Processing By-Product to Reactive Bio-Based Raw Material for Coating Resins
Waterborne Resin Technology Explained: Waterborne Forms, Performance Balance, and a Technology Map
Guide to Common Waterborne Resin Types and Application-Based Selection: How to Choose Acrylics, PUD, Waterborne Epoxy, Waterborne Alkyd, VAE, and Related Chemicals
Resin Polarity in Coating Formulations: From Molecular Structure to Dissolution, Compatibility, Interfacial Interactions, and Formulation Design
Citations of This Product
References
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