2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution - 1.0M in THF , CAS No.898838-07-8

CAS: 898838-07-8 Cat. No.: T466154 Molecular Weight: 242.40

GRADE & PURITY 1.0M in THF

Synonyms

DTXSID30635642 | 2,2,6,6-tetramethylpiperidinylmagnesium chloride lithium chloride | lithium magnesium 2,2,6,6-tetramethylpiperidin-1-ide dichloride | JHBZAAACZVPPRQ-UHFFFAOYSA-L | TMPMgCl·LiCl

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice

Overview

Description

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.Selective Deprotonations using Knochel-Hauser-Base

Specifications

Synonyms

DTXSID30635642 | 2, 2, 6, 6-tetramethylpiperidinylmagnesium chloride lithium chloride | lithium magnesium 2, 2, 6, 6-tetramethylpiperidin-1-ide dichloride | JHBZAAACZVPPRQ-UHFFFAOYSA-L | TMPMgCl·LiCl

Specifications & Purity

1.0M in THF

Storage

Store at 2-8°C, Protected from light, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Names and Identifiers

• Canonical Smiles: [Li+].CC1(CCCC([N-]1)(C)C)C.[Mg+2].[Cl-].[Cl-]
• IUPAC Name: lithium;magnesium;2,2,6,6-tetramethylpiperidin-1-ide;dichloride
• InChIKey: JHBZAAACZVPPRQ-UHFFFAOYSA-L
• INCHI: 1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
• Isomeric SMILES: [Li+].CC1(CCCC([N-]1)(C)C)C.[Mg+2].[Cl-].[Cl-]
• UN Number: UN 2924
• Packing Group: II
• Molecular Weight: 242.40

Chemical and Physical Properties

• Sensitivity: moisture＆light＆air sensitive