4-(Methylamino)pyridine - ≥99% , CAS No.1121-58-0

CAS: 1121-58-0 Cat. No.: M119978 Molecular Weight: 108.14 EC Number: 628-413-7
AVAILABLE TO ORDER
GRADE & PURITY ≥99%
Synonyms
4-Methylaminopyridine | N-Methyl-4-pyridinamine | N-methylpyridin-4-amine
Storage
Argon charged,Room temperature
Shipped In
Normal
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Size
Status
Price
Qty
1g
M119978-1g
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$9.90

$14.90
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5g
M119978-5g
10

$18.90

$28.90
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25g
M119978-25g
1

$81.90

$122.90
Save $41.00 (33.36%)
100g
M119978-100g
1

$260.90

$391.90
Save $131.00 (33.43%)
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Why this grade

≥99% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Argon charged,Room temperature Ships Normal Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 6 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Application:

4-(Methylamino)pyridine can be used:
To functionalize hypercrosslinked emulsion-templated porous polymers (polyHIPE) to form a highly efficient heterogeneous nucleophilic catalyst for the acylation of a tertiary alcohol.
As a reactant to synthesize 4-(N-allyl-N-methylamino)pyridine, which is employed as an intermediate to prepare DMAP/SBA-15 supported catalyst for the synthesis of propylene carbonate.
To prepare 5-azaoxindoles via homolytic aromatic substitution;
4-(Methylamino)pyridine was employed as efficient nucleophilic catalyst during the preparation of ultra-high surface area emulsion templated porous polymers

Specifications

Synonyms
4-Methylaminopyridine | N-Methyl-4-pyridinamine | N-methylpyridin-4-amine
Specifications & Purity
≥99%
Storage
Argon charged, Room temperature
Shipped In
Normal
Purity
≥99%
Names and Identifiers
Pubchem Sid488187713
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/488187713
Canonical SmilesCNC1=CC=NC=C1
IUPAC NameN-methylpyridin-4-amine
InChIKeyLSCYTCMNCWMCQE-UHFFFAOYSA-N
INCHI1S/C6H8N2/c1-7-6-2-4-8-5-3-6/h2-5H,1H3,(H,7,8)
Isomeric SMILES CNC1=CC=NC=C1
WGK Germany 3
Molecular Weight 108.14
Reaxy-Rn 108213
Reaxys-RN_link_address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=108213&ln=

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomOrganic compounds
SuperclassOrganoheterocyclic compounds
ClassPyridines and derivatives
SubclassAminopyridines and derivatives
Intermediate Tree Nodes Not available
Direct ParentAminopyridines and derivatives
Alternative Parents Secondary alkylarylamines  Heteroaromatic compounds  Azacyclic compounds  Organopnictogen compounds  Hydrocarbon derivatives  
Molecular FrameworkAromatic heteromonocyclic compounds
Substituents Secondary aliphatic/aromatic amine - Aminopyridine - Heteroaromatic compound - Azacycle - Secondary amine - Organic nitrogen compound - Organopnictogen compound - Hydrocarbon derivative - Organonitrogen compound - Amine - Aromatic heteromonocyclic compound
DescriptionThis compound belongs to the class of organic compounds known as aminopyridines and derivatives. These are organic heterocyclic compounds containing an amino group attached to a pyridine ring.
External Descriptors Not available
3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

10 results found

Lot NumberCertificate TypeDateItem
G2108234Certificate of AnalysisApr 03, 2025 M119978
A2630064Certificate of AnalysisApr 01, 2024 M119978
D2415090Certificate of AnalysisApr 01, 2024 M119978
D2415091Certificate of AnalysisApr 01, 2024 M119978
D2415092Certificate of AnalysisApr 01, 2024 M119978
D2415093Certificate of AnalysisApr 01, 2024 M119978
K1530078Certificate of AnalysisJul 07, 2023 M119978
E1924106Certificate of AnalysisMar 13, 2023 M119978
B2302460Certificate of AnalysisFeb 07, 2023 M119978
D2319539Certificate of AnalysisJul 14, 2021 M119978
Chemical and Physical Properties
SolubilitySoluble in Methanol
Sensitivityair sensitive
Boil Point(°C)100°C/0.1mmHg
Melt Point(°C)127°C
Molecular Weight108.140 g/mol
XLogP30.800
Hydrogen Bond Donor Count1
Hydrogen Bond Acceptor Count2
Rotatable Bond Count1
Exact Mass108.069 Da
Monoisotopic Mass108.069 Da
Topological Polar Surface Area24.900 Ų
Heavy Atom Count8
Formal Charge0
Complexity57.500
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
The total count of all stereochemical bonds0
Covalently-Bonded Unit Count1
Citations of This Product
References
1. Xiankun Wu, Chang-an Xu, Mangeng Lu, Kunxin Wang, Zhao Li, Hui Yang.  (2022)  Preparation and characterization of high temperature resistant thermosetting polyphenylene ether resin.  JOURNAL OF APPLIED POLYMER SCIENCE,  139  (39): (e52858).  [PMID:] [10.1002/app.52858]
2. Xiaojie Li, Hui Shi, Yan Cui, Kai Pan, Wei Wei, Xiaoya Liu.  (2020)  Dextran-caffeic acid/tetraaniline composite coatings for simultaneous improvement of cytocompatibility and corrosion resistance of magnesium alloy.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2020.105928]
3. Pengju Zhang, You Li, Yaohui Tang, Hui Shen, Jiankai Li, Zhengfang Yi, Qinfei Ke, He Xu.  (2020)  Copper-Based Metal–Organic Framework as a Controllable Nitric Oxide-Releasing Vehicle for Enhanced Diabetic Wound Healing.  ACS Applied Materials & Interfaces,      [PMID:32216291] [10.1021/acsami.0c01792]
4. Dan Chen, Binglin Li, Bin Li, Xiaoli Zhang, Longhui Wei, Wenwen Zheng.  (2019)  Synthesis of vitamin E succinate catalyzed by nano-SiO2 immobilized DMAP derivative in mixed solvent system.  Green Processing and Synthesis,  (1): (667-676).  [PMID:] [10.1515/gps-2019-0037]
5. Li Bin, Chen Dan, Zhang Xiaoli, Dong Wenbo, Zhao Binxia.  (2018)  A convenient method to immobilize 4-dimethylaminopyridine on silica gel as a heterogeneous nucleophilic catalyst for acylation.  CHEMICAL PAPERS,  72  (6): (1339-1345).  [PMID:] [10.1007/s11696-018-0381-2]
6. Yaya Wang, Qi Zhang, Yingying Man, Xiaobin Wu, Yingchun Yin, Xiufang Liu, Hongbing Song, Xin Jin.  (2024)  Functionally enhanced polyether-bridged amidopyridinium dicationic ionic liquids for highly efficient and sustainable fixation of CO2 to cyclic carbonates.  FUEL,      [PMID:] [10.1016/j.fuel.2024.132301]
Solution Calculators
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