Acetoin - ≥97%, May exist as crystalline dimer , CAS No.513-86-0

CAS: 513-86-0 Cat. No.: A109410 Molecular Weight: 88.11 Beilstein Registry Number: 385636 EC Number: 208-174-1
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GRADE & PURITY ≥97% May exist as crystalline dimer
Synonyms
Acetylmethylcarbinol (May exist as crystalline dimer) | 3-Hydroxy-2-butanone (May exist as crystalline dimer)
Storage
Store at 2-8°C,Argon charged
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Wet ice,FedEx DG Service
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Status
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25g
A109410-25g
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Why this grade

≥97%, May exist as crystalline dimer for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Store at 2-8°C,Argon charged Ships Wet ice,FedEx DG Service Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 58 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Acetoin is a volatile compound widely employed as flavour and fragrance compound in foods, cigarettes, cosmetics, detergents, chemical synthesis, plant growth promoters and biological pest controls.Acetoin is the main extracellular product of Bacilus subtilis grown on glucose and other fermentable carbon sources.It contributes to the aroma and flavor associated with alcoholic beverages. Production of acetoin by wine yeast fermentation has been reported.Acetoin is naturally present in buttery foods such as beer, butter and cheese.Determination of diacetyl and acetoin to evaluate the workplace exposures at a popcorn processing facility has been reported. Acetoin is an acyloin derivative. In the presence of light and moisture it transforms into a white colored solid dimer. It is formed by the reduction of diacetyl.It has been synthesized from acetaldehyde.

Specifications

Synonyms
Acetylmethylcarbinol (May exist as crystalline dimer) | 3-Hydroxy-2-butanone (May exist as crystalline dimer)
Specifications & Purity
≥97%, May exist as crystalline dimer
Storage
Store at 2-8°C, Argon charged
Shipped In
Wet ice, FedEx DG Service
This product requires cold chain shipping. Ground and other economy services are not available.
Purity
≥97%
Names and Identifiers
Canonical SmilesCC(C(=O)C)O
IUPAC Name3-hydroxybutan-2-one
InChIKeyROWKJAVDOGWPAT-UHFFFAOYSA-N
INCHI1S/C4H8O2/c1-3(5)4(2)6/h3,5H,1-2H3
Isomeric SMILES CC(C(=O)C)O
WGK Germany 1
RTECS EL8790000
UN Number 2621(liquid)1325(solid dimer)
Packing Group III
Molecular Weight 88.11
Beilstein 385636
Reaxy-Rn 385636
Reaxys-RN_link_address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=385636&ln=

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

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✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

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📊 Datasheet

Quick-reference summary of product specifications and applications.

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🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

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Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomOrganic compounds
SuperclassOrganic oxygen compounds
ClassOrganooxygen compounds
SubclassCarbonyl compounds
Intermediate Tree Nodes Not available
Direct ParentAcyloins
Alternative Parents Alpha-hydroxy ketones  Secondary alcohols  Organic oxides  Hydrocarbon derivatives  
Molecular FrameworkAliphatic acyclic compounds
Substituents Acyloin - Alpha-hydroxy ketone - Secondary alcohol - Ketone - Organic oxide - Hydrocarbon derivative - Alcohol - Aliphatic acyclic compound
DescriptionThis compound belongs to the class of organic compounds known as acyloins. These are organic compounds containing an alpha hydroxy ketone. Acyloins are formally derived from reductive coupling of carboxylic acyl groups.
External Descriptors acetoin
3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
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23 results found

Lot NumberCertificate TypeDateItem
C2505718Certificate of AnalysisNov 27, 2024 A109410
C2505721Certificate of AnalysisNov 27, 2024 A109410
C2505722Certificate of AnalysisNov 27, 2024 A109410
C2505733Certificate of AnalysisNov 27, 2024 A109410
F2414341Certificate of AnalysisJun 24, 2024 A109410
K2425047Certificate of AnalysisMar 01, 2024 A109410
E2609079Certificate of AnalysisMar 01, 2024 A109410
E2508242Certificate of AnalysisMar 01, 2024 A109410
A2604032Certificate of AnalysisMar 01, 2024 A109410
D2524076Certificate of AnalysisMar 01, 2024 A109410
E2408092Certificate of AnalysisMar 01, 2024 A109410
E2408105Certificate of AnalysisMar 01, 2024 A109410
E2408106Certificate of AnalysisMar 01, 2024 A109410
A2417071Certificate of AnalysisJan 05, 2024 A109410
A2417074Certificate of AnalysisJan 05, 2024 A109410
A2417073Certificate of AnalysisJan 05, 2024 A109410
A2417072Certificate of AnalysisJan 05, 2024 A109410
A2417047Certificate of AnalysisJan 05, 2024 A109410
L2208240Certificate of AnalysisSep 19, 2022 A109410
L2208320Certificate of AnalysisSep 19, 2022 A109410
L2208354Certificate of AnalysisSep 19, 2022 A109410
L2208433Certificate of AnalysisSep 19, 2022 A109410
H2231011Certificate of AnalysisJul 05, 2021 A109410

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Chemical and Physical Properties
SolubilityMiscible with water, propylene glycol and alcohol. Slightly miscible with ether, petroleum ether. Immiscible with fatty oils and vegetable oil.
SensitivityLight & Air Sensitive;Moisture sensitive
Refractive Index1.417
Flash Point(°F)118.4 °F
Flash Point(°C)47°C
Boil Point(°C)148°C
Melt Point(°C)15°C
Molecular Weight88.110 g/mol
XLogP3-0.300
Hydrogen Bond Donor Count1
Hydrogen Bond Acceptor Count2
Rotatable Bond Count1
Exact Mass88.0524 Da
Monoisotopic Mass88.0524 Da
Topological Polar Surface Area37.300 Ų
Heavy Atom Count6
Formal Charge0
Complexity58.600
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count1
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
The total count of all stereochemical bonds0
Covalently-Bonded Unit Count1
Citations of This Product
References
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55. Xiaoqian Liu, Fang Yuan, Bei Zhou, Wen Huang, Zhinan Mei, Salam A. Ibrahim, Ying Liu, Xi Feng.  (2025)  Application of GC-O, aroma recombination and omission tests to identify horse urine-like off-odor in Gastrodia elata Blume.  Food Bioscience,      [PMID:] [10.1016/j.fbio.2025.107905]
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