Bis(triphenylphosphine)rhodium(I) carbonyl chloride - Rh ≥14.90% , CAS No.13938-94-8

CAS: 13938-94-8 Cat. No.: B113668 Molecular Weight: 690.94 Beilstein Registry Number: 4618896 EC Number: 237-712-8 PubChem CID: 53486327
AVAILABLE TO ORDER
GRADE & PURITY Rh ≥14.90%
Synonyms
RhCl(CO)(PPh3)2 | Carbonylbis(triphenylphosphine)rhodium(I) Chloride | formaldehyde;rhodium;triphenylphosphane;chloride | MFCD00044273 | AC-4991 | AKOS025402107
Storage
Argon charged,Room temperature
Shipped In
Normal
 ·  off list, applied to all prices below.
Size
Status
Price
Qty
100mg
B113668-100mg
3
$34.90
250mg
B113668-250mg
3
$68.90
1g
B113668-1g
3
$207.90
5g
B113668-5g
2
$931.90
Enter a quantity for the sizes you want to add.
🧪

Why this grade

Rh ≥14.90% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Argon charged,Room temperature Ships Normal Check lot-specific COA for exact specifications.

📋

Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

📚

Literature proof

Cited in 1 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Used for cyclometallation.

Specifications

Synonyms
RhCl(CO)(PPh3)2 | Carbonylbis(triphenylphosphine)rhodium(I) Chloride | formaldehyde;rhodium;triphenylphosphane;chloride | MFCD00044273 | AC-4991 | AKOS025402107
Specifications & Purity
Rh ≥14.90%
Storage
Argon charged, Room temperature
Shipped In
Normal
Names and Identifiers
Canonical SmilesC=O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
IUPAC Nameformaldehyde;rhodium;triphenylphosphane;chloride
InChIKeyHPWKFRMRYWEJBC-UHFFFAOYSA-M
INCHI1S/2C18H15P.CH2O.ClH.Rh/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h2*1-15H;1H2;1H;/p-1
Isomeric SMILES C=O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
WGK Germany 3
PubChem CID 53486327
UN Number 2811
Molecular Weight 690.94
Beilstein 4618896
Reaxy-Rn 4618896

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

7 results found

Lot NumberCertificate TypeDateItem
F2615030Certificate of AnalysisJun 29, 2026 B113668
L2327078Certificate of AnalysisOct 17, 2025 B113668
K2323037Certificate of AnalysisAug 11, 2025 B113668
K21251045Certificate of AnalysisJun 10, 2025 B113668
K21251114Certificate of AnalysisJun 10, 2025 B113668
D1613065Certificate of AnalysisAug 01, 2023 B113668
L1523044Certificate of AnalysisMay 10, 2023 B113668
Chemical and Physical Properties
SolubilitySoluble in acetone, chloroform, ethanol
SensitivityMoisture sensitive
Melt Point(°C)224-227°C
Documents & Articles
Citations of This Product
References
1. Zeyu Liu, Xiaohan Shan, Qiang Xue, Yao Liu, Lin He, Haijiao Xie.  (2023)  Efficient detection of nitrite in water based on an Au/NiO/Rh trimetallic composite modified laser-induced graphene electrode prepared by one-step electrodeposition.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2023.145486]
Solution Calculators
Reviews

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