Glycerol propoxylate - Mn~266 , CAS No.25791-96-2

CAS: 25791-96-2 Cat. No.: G477943 EC Number: 500-044-5

GRADE & PURITY Mn~266

Synonyms

Glycerol propoxylate (1PO/OH)

Storage

Room temperature

Overview

Glycerin propoxic acid is a zig-zag (zig-zag) triol material consisting of a polypropylene glycol unit with three terminal hydroxyl groups. Due to the presence of multiple active sites in the branched chain, this hydrophobic macromolecular monomer is widely used in the preparation of crosslinked polymers. It can also be used as a plasticizer to give the material good elasticity 

Application：

Glycerin propoxic acid can be used as macromolecular monomer to prepare reusable oil-absorbing gel materials for cleaning oil spills

Specifications

Synonyms

Glycerol propoxylate (1PO/OH)

Specifications & Purity

Mn~266

Storage

Room temperature

Names and Identifiers

• Pubchem Sid: 504759314
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504759314
• Isomeric SMILES: COC1=C(C(=CC(=C1)C=O)Br)OCC2=CC=CC=C2F

Chemical and Physical Properties

• Solubility: H2O: soluble 1.000g/L
• Refractive Index: n20/D 1.46
• Flash Point(°F): ＞230℉
• Melt Point(°C): -40 °C
• Molecular Weight: 339.160 g/mol
• XLogP3: 3.600
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 337.995 Da
• Monoisotopic Mass: 337.995 Da
• Topological Polar Surface Area: 35.500 Ų
• Heavy Atom Count: 20
• Formal Charge: 0
• Complexity: 315.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

References

1. Jiexiang Tong, Subin Xie, Jia-Tao Miao, Jing Luo, Ren Liu.  (2023)  A novel method to synthesize polyurethane-urea acrylate with high strength and toughness.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2023.108006]

2. Zhijun Liu, Guoming Yuan, Wenjie Diao, Yaodong Zhang, Enxiang Jiao, Jun Shi, Kun Wu.  (2023)  UV-curing polyurethane pressure-sensitive adhesive with high shear strength and good adhesion properties inspired by spider silk.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2023.107963]

3. Jiexiang Tong, Subin Xie, Jia-Tao Miao, Jing Luo, Ren Liu.  (2023)  Preparation of UV-cured polyurethane-urea acrylate coatings with high hardness and toughness.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2023.107969]

4. Xinyu Wang, Zefei Yuan, Xueyi Pan, Jianbo Li, Qinggang Tan, Jie Ren.  (2023)  Eco-Friendly Polyurethane Reactive Hot-Melt Adhesive Derived from Poly(ε-caprolactone-co-lactic acid) Diols.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.3c01245]

5. Kunlin Chen, Bingqian Zhao, Sheng Dai, Gang Wang, Jiangzhou Cui, Dali Zhao, Kejing Yu, Hua Qiu.  (2023)  Facile fabrication of transparent slippery coatings with dual self-healing ability.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2023.158207]

6. Xiaolong Sun, Qingqing He, Yue Hou, Xuan Zheng, Peng Bi, Yufeng Xu, Xingzhong Zhang, Yong Liu, Rui Xiong, Yang Yang, Ziyu Wang.  (2023)  Self-Healing Flexible Pressure Sensor for Human Motion Detection Based on Silver-Nanoparticle-Modified Polyimide Membranes.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.3c00498]

7. Jie Zhou, Tao Zhang, Yusong Xu, Xianming Zhang.  (2023)  A phosphorus- and nitrogen-containing aromatic Schiff base derivative in waterborne polyurethane backbone for excellent flame retardant, UV-shielding and mechanical properties.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2023.107631]

8. Hao Wu, Mi Wang, Wanbao Wu, De Bai, Yihong Liang, Shunyou Hu, Wen Yu, Peng He, Jiaheng Zhang.  (2023)  Ionic liquid–polymer thermochromic electrolytes with a wide and tunable LCST for application in multi-stimuli-responsive optical modulation.  Journal of Materials Chemistry A,  11  (17): (9626-9634).  [PMID:] [10.1039/D2TA08226H]

9. Jinsong Wang, Farzad Seidi, Yang Huang, Huining Xiao.  (2022)  Smart lignin-based polyurethane conjugated with corrosion inhibitor as bio-based anticorrosive sublayer coating.  INDUSTRIAL CROPS AND PRODUCTS,      [PMID:] [10.1016/j.indcrop.2022.115719]

10. Haibo Wang, Junhuai Xu, Kaijun Li, Yi Dong, Zongliang Du, Shuang Wang.  (2022)  Highly stretchable, self-healable, and self-adhesive ionogels with efficient antibacterial performances for a highly sensitive wearable strain sensor.  Journal of Materials Chemistry B,  10  (8): (1301-1307).  [PMID:35141732] [10.1039/D2TB00041E]

11. Wenbo Xie, Hao Li, Yao Sun, Wen Li, Fengmei Yi, Lu Xia, Fuhou Lei.  (2022)  Separating and purifying of Panax notoginseng saponins using a rosin-based polymer-bonded with silica as a high-performance liquid chromatography stationary phase.  MICROCHEMICAL JOURNAL,      [PMID:] [10.1016/j.microc.2022.107234]

12. Jiarui Yu, Nan Gao, Xiaowen Xie, Xing Xin, Zhanqi Li, Shuai Chen, Jingkun Xu.  (2021)  Thermally driven self-healing PEDOT conductive films relying on reversible and multiple Diels–Alder interaction.  JOURNAL OF POLYMER SCIENCE,  60  (5): (794-802).  [PMID:] [10.1002/pol.20210750]

13. Yuhuan Yuan, Cong Peng, Duo Chen, Zhanjun Wu, Shichao Li, Tao Sun, Xin liu.  (2021)  Synthesis of a coupling agent containing polyurethane chain and its influence on improving the dispersion of SiO2 nanoparticles in epoxy/amine thermoset.  COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING,      [PMID:] [10.1016/j.compositesa.2021.106573]

14. Xing-Ya Liu, Rui-Yang Xie, Tao Chen, Lei He, Ting Wang, Wang Liao, Zhi-Guo Liu, Ming-Jun Chen.  (2021)  Improvement of polyurethane film strength by H-bonding crosslinking with hydroxylated melamine.  JOURNAL OF APPLIED POLYMER SCIENCE,  138  (47): (51411).  [PMID:] [10.1002/app.51411]

15. Zhang Weihong, Wang Dan, Wang Jie-Xin, Pu Yuan, Chen Jian-Feng.  (2020)  High-gravity-assisted emulsification for continuous preparation of waterborne polyurethane nanodispersion with high solids content.  Frontiers of Chemical Science and Engineering,  14  (6): (1087-1099).  [PMID:] [10.1007/s11705-019-1895-z]

16. Shuqiang Peng, Yuewei Li, Lixin Wu, Jie Zhong, Zixiang Weng, Longhui Zheng, Zhi Yang, Jia-Tao Miao.  (2020)  3D Printing Mechanically Robust and Transparent Polyurethane Elastomers for Stretchable Electronic Sensors.  ACS Applied Materials & Interfaces,      [PMID:31927985] [10.1021/acsami.9b20631]

17. Weijing Yao, Xiao Chen, Qingyong Tian, Chengsheng Luo, Xiaomei Zhang, Haiyan Peng, Wei Wu.  (2019)  Directly printing of upconversion fluorescence-responsive elastomers for self-healable optical application.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2019.123375]

18. Lei Jinfeng, Deng Lei, Li Xinying, Xu Yongbin, Li Defu, Mu Changdao.  (2018)  Comparative study of the physicochemical and photocatalytic properties of water-soluble polymer-capped TiO2 nanoparticles.  ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,  25  (26): (26259-26266).  [PMID:29978313] [10.1007/s11356-018-2679-6]

19. Xie Li, Wei Li, Xiaolin Wang, Heling Guo, Rongjie Wang, Xuhong Guo, Cuihua Li, Xin Jia.  (2018)  Enhanced adhesion force based on microphase separation induced by complexation of ferric ions and polyurethane matrix.  JOURNAL OF APPLIED POLYMER SCIENCE,  135  (17): (46069).  [PMID:] [10.1002/app.46069]

20. Wenyuan Fang, Libin Liu, Gailan Guo.  (2017)  Tunable Wettability of Electrospun Polyurethane/Silica Composite Membranes for Effective Separation of Water-in-Oil and Oil-in-Water Emulsions.  CHEMISTRY-A EUROPEAN JOURNAL,  23  (47): (11253-11260).  [PMID:28543628] [10.1002/chem.201701409]

21. Jun Liu, Hai-Feng Liu, Li Deng, Bing Liao, Qing-Xiang Guo.  (2013)  Improving aging resistance and mechanical properties of waterborne polyurethanes modified by lignin amines.  JOURNAL OF APPLIED POLYMER SCIENCE,  130  (3): (1736-1742).  [PMID:] [10.1002/app.39267]

22. Xiaofeng Wang, Weiyi Xing, Bibo Wang, Panyue Wen, Lei Song, Yuan Hu, Ping Zhang.  (2013)  Comparative Study on the Effect of Beta-Cyclodextrin and Polypseudorotaxane As Carbon Sources on the Thermal Stability and Flame Retardance of Polylactic Acid.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/ie303002b]

23. Xianqiang Zeng, Liguo Wang, Yan Cao, Chen Liu, Peng He, Huiquan Li.  (2024)  Beta Zeolite-Supported Double-Metal Cyanide Catalysts with Enhanced Lewis Acidity for the Synthesis of High-Performance Poly(1,2-butylene oxide) Lubricating Oils.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.3c03429]

24. Zuo Han, Zhang Luzhi, Xuan Huixia, Gu Shijia, Xu Xinxin, Neisiany Rasoul Esmaeely, Wu Qilin, You Zhengwei.  (2024)  Cement-inspired readily fabricated water-strengthened polymeric materials.  Science China-Chemistry,  67  (10): (3458-3467).  [PMID:] [10.1007/s11426-024-2165-x]

25. Yao An, Junshi Wu, Beihang Xu, Jinghao Zhu, Antong Ma, Wenjin Wang, Yongjia Yang, Xiaodong Lian, Zhaoxiang Yang, Yapei Wang, Yonglin He.  (2024)  Direct Ionic Ink Writing on and Penetrating into Elastomer for Patternable, Waterproof, and Wear-Resistant Ionic Circuits.  ADVANCED FUNCTIONAL MATERIALS,      [PMID:] [10.1002/adfm.202413434]

26. Ke Yang, Shanda Wang, Yanru Chen, Hanhai Dong, Quanguo Wang, Qingli Cheng.  (2025)  Dynamic Mechanical Properties and Energy Absorption Capabilities of Polyureas Through Experiments and Molecular Dynamic Simulation.  Polymers,  17  (1): (107).  [PMID:39795510] [10.3390/polym17010107]

27. Jiayi Gan, Jie Zhou, Yusong Xu, Tao Zhang, Xianming Zhang.  (2024)  Flame-Retardant and Antibacterial Waterborne Polyurethane Composites Based on a Cu(II)–Phytate–Aromatic Schiff Base Complex.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.4c01865]

28. Qiushuang Zhang, Jinkang Dou, Minghui Xu, Bojun Tan, Hongchang Mo, Xianming Lu, Jianquan Wang, Ning Liu.  (2024)  Highly Flexible Polyether for Solid Propellants: Synthesis, Room Temperature Curing, Thermal Analysis, and Mechanical Properties.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.4c01709]

29. Jialiang Li, Yinghu Song, Guojun Song, Zhaoji Li, Xirui Yang, Xiaoran Wang, Hongjia Liu, Xiaoru Li, Xin Luo, Haoyu Yin, Zhongxun Li.  (2025)  Mechanically Robust, Super Tough and Ultrastretchable Self-Healing Polyurethane Constructed from Multiple Asymmetric Hydrogen Bonds.  POLYMER,      [PMID:] [10.1016/j.polymer.2025.128022]

30. Jun Liu, Yuguo Zhuo, Dawei Yan, Zhu Zhang, Hongfei Jin, Boxuan Xie.  (2024)  Preparation and characterization of modified CNC/waterborne polyurethane composite film.  FERROELECTRICS,      [PMID:] [10.1080/00150193.2024.2325894]

31. Guang Wang, Hongzhao Fan, Zhongwei Chen, Yufei Gao, Zuankai Wang, Zhigang Li, Haipeng Lu, Yanguang Zhou.  (2024)  Tuning Thermal Conductivity of Hybrid Perovskites through Halide Alloying.  Advanced Science,  11  (25): (2401194).  [PMID:38647250] [10.1002/advs.202401194]

32. Xiaoyun Xu, Songmei Li, Zicheng Luo, Chuangchuang Zhang, Dashan Zhang, Jia Hui, Shubin Yang, Bin Li.  (2024)  Ultra-wide temperature range aqueous electrolyte through local aggregation anchoring active water towards practical aqueous zinc metal battery.  Energy Storage Materials,      [PMID:] [10.1016/j.ensm.2024.103567]

33. Jingjing Bai, Yan Zhai, Xin Li, Mingzheng Hao, Weijie Ren, Maoyong He, Zhenzhong Li.  (2025)  Refractive index dependent photoelectric properties of carbon dots based luminescent solar concentrators.  OPTICAL MATERIALS,      [PMID:] [10.1016/j.optmat.2025.117301]

34. Wen Zhou, Xi Yu, Leitao Cao, Ming Yang, Yang Li, Yang Si, Jianyong Yu, Bin Ding.  (2020)  Green and Ethanol-Resistant Polyurethane Nanofibrous Membranes Based on an Ethanol Solvent for Waterproof and Breathable Textiles.  Advanced Sustainable Systems,  4  (9): (2000105).  [PMID:] [10.1002/adsu.202000105]

35. Yanyan Yu, Jinlong Fan, Guopeng Xu, Jie Zhang.  (2024)  Blends of polydimethylsiloxane-based polyurethane and poly (propylene glycol)-based polyurethane with co-continuous structures: Morphology evolution, synergistic effects and application in strain sensors.  POLYMER,      [PMID:] [10.1016/j.polymer.2024.127615]

36. Zhenfang Zeng, Wei Wei, Hao Li, Wen Li, Lijuan Bai, Mengling Wei, Jiabao Liu, Danmei Chen, Fuhou Lei.  (2025)  Purification of PNS From Sanqi Extract Using a Rosin-Based Polymer Composite: Adsorption and Mechanism.  JOURNAL OF APPLIED POLYMER SCIENCE,      [PMID:] [10.1002/app.57621]

37. Sun Xiaolong, Hou Yue, Zhu Zheng, Zhu Bo, Ding Qianfeng, Zhou Wenjie, Yan Sijia, Xia Zhanglong, Liu Yong, Hou Youmin, Yu Yuan, Wang Ziyu.  (2025)  Modular assembly of self-healing flexible thermoelectric devices with integrated cooling and heating capabilities.  Nature Communications,  16  (1): (1-9).  [PMID:40328774] [10.1038/s41467-025-59602-8]

38. Jian He, Zihao Qian, Zhijun Hu, Mingyu Guo.  (2025)  Transparent and Extremely Stretchable Piezoelectric Device for Sensors and Energy Harvesters.  ACS Applied Materials & Interfaces,      [PMID:40375384] [10.1021/acsami.5c05660]

39. Pei Huan Wu, Chun Hui Xie, Yun Qi Li, Cai Juan Huang, Hai Bo Xie, Yang You.  (2025)  Fatigue-resistant, self-healable and thermally conductive polyurethane composites based on the intrinsic π-π stacking interactions between boron nitrides and hard segments.  Materials Today Communications,      [PMID:] [10.1016/j.mtcomm.2025.112228]

40. Jingya Dai, Yusong Xu, Tao Zhang, Xianming Zhang.  (2025)  Epoxidized Soybean Oil-Based Phosphorus-Containing Waterborne Polyurethane Coating for PET Rope With Enhanced Flame Retardancy and Mechanical Properties.  JOURNAL OF APPLIED POLYMER SCIENCE,      [PMID:] [10.1002/app.58171]

41. Ruwei Guo, Mingyu Guo.  (2025)  Direct Wrinkling of Silver Nanowire Networks on Electrospun Polyurethane–Urea Mats for Stretchable Electronics.  JOURNAL OF APPLIED POLYMER SCIENCE,      [PMID:] [10.1002/app.70021]

42. Yue Wang, Ximing Liao, Lei Zhou, Songchao Fu, Qing He, Xinqi Chen, Linxi Xia, Cihui Liu, Feng Liu, Lei Yang.  (2025)  Innovative Y-Shaped Hydrogel Mitral Clip with Magnetic Actuation and Hydrophilic Janus Surface for Enhanced Valve Leaflet Repair.  Materials Today Bio,      [PMID:41560826] [10.1016/j.mtbio.2025.102750]

43. Zhao Huang, Xiaomeng Li, Haotian Yang, Zhaoxuan Yan, Bo Chen.  (2026)  Effect of TiC layer thickness on the thermal conductivity and mechanical properties of Diamond/TiC/SiC composites.  JOURNAL OF THE CERAMIC SOCIETY OF JAPAN,  134  (1): (10-17).  [PMID:28588173] [10.2109/jcersj2.25112]

44. Hao Chen, Xiao-Long Zhang, Jianyu Liu, Jie Liu, Xiaoli Liu, Zhirong Xin, Chunyang Bao.  (2026)  Fully Recyclable Aramid Fiber-Reinforced Composites with Superior Tearing Resistance Enabled by Reversibly Cross-Linked Poly(boron-urethane) Elastomer.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.5c04410]