Grubbs Catalyst - Ru 12.3% , CAS No.172222-30-9

CAS: 172222-30-9 Cat. No.: G113747 Molecular Weight: 822.96 EC Number: 629-485-2
AVAILABLE TO ORDER
GRADE & PURITY Ru 12.3%
Synonyms
Umicore Grubbs Catalyst M102
Storage
Store at 2-8°C,Argon charged
Shipped In
Wet ice
 ·  off list, applied to all prices below.
Size
Status
Price
Qty
250mg
G113747-250mg
2
$81.90
1g
G113747-1g
2
$234.90
5g
G113747-5g
1
$823.90
25g
G113747-25g
2
$2,883.90
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Why this grade

Ru 12.3% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Store at 2-8°C,Argon charged Ships Wet ice Check lot-specific COA for exact specifications.

📋

Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

📚

Literature proof

Cited in 1 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Ruthenium-Based Metathesis Catalysts,widely used in organic synthesis.


Product class
M-P, Homogeneous Catalysts, M-C, Grubbs Catalyst® 1st Generation, Carbene Ligands, Phosphorus Ligands - Achiral

Reaction type
Alkene Metathesis, Acyclic Diene Metathesis, Cross Metathesis, Ring Arrangement Metathesis , Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self Metathesis

Chemical properties

Chemical formula

C43H72Cl2P2Ru

Empirical formula

Ru(PCy3)2(benzylidene)Cl2

Molecular weight

822.96

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

purple


Applications & references

Formal Synthesis of (-)-Haliclonin A: Stereoselective Construction of an Azabicyclo[3.3.1]nonane Ring System by a Tandem Radical Reaction.


Reference: Org. Lett. 2020, 22, 13, 5046–5050

Formylation of a metathesis-derived ansa[4]-ferrocene: a simple route to anticancer organometallics.


Reference: Dalton Trans. 2020, (doi.org/10.1039/D0DT01975E)

Aerogels for the separation of asphalt-containing oil–water mixtures and the effect of asphalt stabilizer.


Reference: RSC Adv. 2020,10, 24840-24846

Asymmetric total synthesis of the naturally occurring antibiotic Anthracimycin


Reference: Org. Lett. 2020, 22, 14, 5550–5554

Sequential two-fold Claisen Rearrangement, One-pot Ring Closing Metathesis and Cross-metathesis as a Route to Substituted Benzo[b]azepine-2-one, Benzo[b]azepine and Benzo[b]oxepine Derivatives.


Reference: Helv Chem Acta 2020 ASAP (doi.org/10.1002/hlca.202000216)

Specifications

Synonyms
Umicore Grubbs Catalyst M102
Specifications & Purity
Ru 12.3%
Storage
Store at 2-8°C, Argon charged
Shipped In
Wet ice
This product requires cold chain shipping. Ground and other economy services are not available.
Names and Identifiers
Canonical SmilesC[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru
WGK Germany 3
UN Number 1325
Molecular Weight 822.96

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

8 results found

Lot NumberCertificate TypeDateItem
B2428084Certificate of AnalysisDec 22, 2025 G113747
B2428085Certificate of AnalysisDec 22, 2025 G113747
B2428086Certificate of AnalysisDec 22, 2025 G113747
E2207109Certificate of AnalysisDec 12, 2025 G113747
E2207110Certificate of AnalysisDec 12, 2025 G113747
E2207115Certificate of AnalysisDec 12, 2025 G113747
K2507016Certificate of AnalysisNov 26, 2025 G113747
L2417108Certificate of AnalysisFeb 22, 2024 G113747
Chemical and Physical Properties
SensitivityAir and Light sensitive.
Melt Point(°C)153°C
Documents & Articles
Citations of This Product
References
1. Hongmei Qin, Man Liu, Shiyu Qin, Shixian Zhang, Xingnan Zhou, Chenjian Li, Yuhao Wei, Dan Chen, Rong Fan, Shan Wang, Quanling Yang, Chuanxi Xiong, Qing Wang.  (2024)  Stereoisomerically enhanced polynorbornene-imide dielectric energy storage performance.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.149244]
Solution Calculators
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