Isopropenyloxytrimethylsilane [Trimethylsilylating Agent] - ≥90%(GC) , CAS No.1833-53-0

CAS: 1833-53-0 Cat. No.: I157569 Molecular Weight: 130.26 Beilstein Registry Number: 1849020 EC Number: 217-393-1

GRADE & PURITY ≥90%(GC)

Synonyms

Isopropenoxytrimethylsilane | 2-trimethylsiloxypropene | Silane, trimethyl((1-methylethenyl)oxy)- | (Isopropenyloxy)trimethylsilane | trimethyl(prop-1-en-2-yloxy)silane | Isopropenyloxytrimethylsilane | Silane, trimethyl[(1-methylethenyl)oxy]- | 2-(trimet

Storage

Store at -20°C,Argon charged

Shipped In

Ice chest + Ice pads

Overview

(Isopropenyloxy)trimethylsilane is an enol silyl ether.It participates as nucleophile in Lewis acid-promoted C3-nucleophile substitution of tetracyclic bromide.It is reported to participate in the total synthesis of (±)-powelline.It is reported to participate in dityltin bis(triflate) catalyzed Michael addition reaction of enol silyl ethers.

Specifications

Synonyms

Isopropenoxytrimethylsilane | 2-trimethylsiloxypropene | Silane, trimethyl((1-methylethenyl)oxy)- | (Isopropenyloxy)trimethylsilane | trimethyl(prop-1-en-2-yloxy)silane | Isopropenyloxytrimethylsilane | Silane, trimethyl[(1-methylethenyl)oxy]- | 2-(trimet

Specifications & Purity

≥90%(GC)

Storage

Store at -20°C, Argon charged

Shipped In

Ice chest + Ice pads

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥90%(GC)

Names and Identifiers

• Canonical Smiles: CC(=C)O[Si](C)(C)C
• IUPAC Name: trimethyl(prop-1-en-2-yloxy)silane
• InChIKey: UAIFZYSPVVBOPN-UHFFFAOYSA-N
• INCHI: 1S/C6H14OSi/c1-6(2)7-8(3,4)5/h1H2,2-5H3
• Isomeric SMILES: CC(=C)O[Si](C)(C)C
• WGK Germany: 3
• UN Number: 1993
• Packing Group: II
• Molecular Weight: 130.26
• Beilstein: 1849020
• Reaxy-Rn: 1849023
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1849023&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Class Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Organoheterosilanes
          • Level6 Trialkylheterosilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Class: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Organoheterosilanes
• Direct Parent: Trialkylheterosilanes
• Alternative Parents: Silyl enol ethers Organic metalloid salts Organooxygen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkylheterosilane - Organic metalloid salt - Silyl enol ether - Organic oxygen compound - Hydrocarbon derivative - Organic salt - Organooxygen compound - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as trialkylheterosilanes. These are organoheterosilanes, bearing a silicon atom linked to three alkyl groups and one heteroatom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Heat & Moisture Sensitive
• Refractive Index: 1.4
• Flash Point(°F): 19.4 °F
• Flash Point(°C): -7°C(lit.)
• Boil Point(°C): 94°C(lit.)
• Molecular Weight: 130.259 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 130.081 Da
• Monoisotopic Mass: 130.081 Da
• Topological Polar Surface Area: 9.200 Ų
• Heavy Atom Count: 8
• Formal Charge: 0
• Complexity: 91.200
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

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