[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride - ≥98% , CAS No.191654-69-0

CAS: 191654-69-0 Cat. No.: R486824 Molecular Weight: 856.1 EC Number: 695-404-2 PubChem CID: 11814861

GRADE & PURITY ≥98%

Synonyms

[(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride | [(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II)chloride | Palladium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-bis(4-methylphenyl)phosphine-kappaP]

Storage

Argon charged,Room temperature

Shipped In

Normal

Overview

Description

Catalyst for:Enantioselective preparation of hydroxydicarbonyls via aldol addition of pyruvates and diketones with ketene thioacetalStereoselective aldol condensation using trimethyl[[(phenyl)ethenyl]oxy]silane and benzaldehyde as reactantsStereoselective preparation of naphthalenols via alkylative ring opening of oxabenzonorbornadienes with dialkylzincReactant for:Preparation of palladium bis(diphenylphosphino)binaphthyl aqua mononuclear and hydroxo-bridged dinuclear complexes

Specifications

Synonyms

[(R)-(+)-2, 2'-Bis(di-p-tolylphosphino)-1, 1'-binaphthyl]palladium(II) chloride | [(R)-(+)-2, 2'-Bis(di-p-tolylphosphino)-1, 1'-binaphthyl]palladium(II)chloride | Palladium, [1, 1'-(1R)-[1, 1'-binaphthalene]-2, 2'-diylbis[1, 1-bis(4-methylphenyl)phosphine-kappaP]

Specifications & Purity

≥98%

Storage

Argon charged, Room temperature

Shipped In

Normal

Purity

≥98%

Names and Identifiers

• Canonical Smiles: CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.Cl[Pd]Cl
• IUPAC Name: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;dichloropalladium
• InChIKey: ADMKISPNGKUJAU-UHFFFAOYSA-L
• INCHI: 1S/C48H40P2.2ClH.Pd/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;;;/h5-32H,1-4H3;2*1H;/q;;;+2/p-2
• Isomeric SMILES: CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.Cl[Pd]Cl
• WGK Germany: 3
• PubChem CID: 11814861
• Molecular Weight: 856.1

Chemical and Physical Properties

• Sensitivity: air sensitive