Rhodium Chloride Hydrate - Rh 38.5-42.5% , CAS No.20765-98-4

CAS: 20765-98-4 Cat. No.: R109233 Molecular Weight: 209.26(anhydrous basis) EC Number: 606-630-8 PubChem CID: 16211510

GRADE & PURITY Rh 38.5-42.5%

Synonyms

RhCl3 x n H2O

Storage

Room temperature,Argon charged

Shipped In

Normal

Overview

A catalyst for conjugate reduction of cinnamaldehydes followed by cross-coupling with arylboronic acids. Catalyst for the direct conversion of methane to acetic acid.
Catalyst for the isomerization of alkenes, the reduction of aromatic rings, the oxidation ofalkenes, the hydration of acetylene, the hydrosilylation of α,β-unsaturated esters to form dimethylketene trimethylsilyl acetals.

Application：

Catalyst for conjugate reduction of cinnamaldehydes followed by cross-coupling with arylboronic acids. Catalyst for the direct conversion of methane to acetic acid. Catalyst for the isomerization of alkenes, the reduction of aromatic rings, the oxidation ofalkenes, the hydration of acetylene, the hydrosilylation of α,β-unsaturated esters to form dimethylketene trimethylsilyl acetals.

Product class
PGM Solids, Chlorides, Hydrates

Reaction type
Hydroformylation, Isomerization, Oxidation, Reduction

Chemical properties

Chemical formula

Cl3Rh

Empirical formula

RhCl3 x n H2O

Molecular weight

209.26 (anhydrous)

Metal

Rh

Theoretical metal content

38

Physical state

powder

Color

dark red

Specifications

Synonyms

RhCl3 x n H2O

Specifications & Purity

Rh 38.5-42.5%

Storage

Room temperature, Argon charged

Shipped In

Normal

Names and Identifiers

• Canonical Smiles: O.Cl[Rh](Cl)Cl
• InChIKey: HSSMNYDDDSNUKH-UHFFFAOYSA-K
• INCHI: 1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3
• Isomeric SMILES: O.Cl[Rh](Cl)Cl
• WGK Germany: 3
• PubChem CID: 16211510
• UN Number: 3260
• Packing Group: III
• Molecular Weight: 209.26(anhydrous basis)

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Class Transition metal salts
      • Subclass Transition metal chlorides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Class: Transition metal salts
• Subclass: Transition metal chlorides
• Intermediate Tree Nodes: Not available
• Direct Parent: Transition metal chlorides
• Alternative Parents: Inorganic chloride salts
• Molecular Framework: Not available
• Substituents: Transition metal chloride - Inorganic chloride salt - Inorganic salt
• Description: This compound belongs to the class of inorganic compounds known as transition metal chlorides. These are inorganic compounds in which the largest halogen atom is Chlorine, and the heaviest metal atom is a transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Soluble in alcohol and water. Slightly soluble in acetone.
• Sensitivity: Hygroscopic
• Melt Point(°C): 100°C
• Molecular Weight: 227.280 g/mol
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 225.823 Da
• Monoisotopic Mass: 225.823 Da
• Topological Polar Surface Area: 1.000 Ų
• Heavy Atom Count: 5
• Formal Charge: 0
• Complexity: 8.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

References

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