RockPhos Pd G3 - ≥98% , CAS No.2009020-38-4

CAS: 2009020-38-4 Cat. No.: M282867 Molecular Weight: 838.43 EC Number: 102-545-0 PubChem CID: 117065433

GRADE & PURITY ≥98%

Synonyms

Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

The 3rd generation Buchwald palladium catalyst contains blocky RockPhos ligands. The system has been shown to be effective in cross coupling reaction reactions like arylated fatty alcohols.

Specifications

Synonyms

Methanesulfonato(2-(di-t-butylphosphino)-3-methoxy-6-methyl-2', 4', 6'-tri-i-propyl-1, 1'-biphenyl)(2'-amino-1, 1'-biphenyl-2-yl)palladium(II)

Specifications & Purity

≥98%

Legal Information

Patents: PCT/US2013/030779, US Serial No. 13/799620. Buchwald Palladacycle Precatalyst Kit 2 component

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥98%

Names and Identifiers

• Canonical Smiles: CC1=C(C(=C(C=C1)OC)P(C(C)(C)C)C(C)(C)C)C2=C(C=C(C=C2C(C)C)C(C)C)C(C)C.CS(=O)(=O)O.C1=CC=C([C-]=C1)C2=CC=CC=C2N.[Pd]
• IUPAC Name: ditert-butyl-[6-methoxy-3-methyl-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;methanesulfonic acid;palladium;2-phenylaniline
• InChIKey: QAHMIRGGAFFMDS-UHFFFAOYSA-N
• INCHI: 1S/C31H49OP.C12H10N.CH4O3S.Pd/c1-19(2)23-17-24(20(3)4)28(25(18-23)21(5)6)27-22(7)15-16-26(32-14)29(27)33(30(8,9)10)31(11,12)13;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15-21H,1-14H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1
• Isomeric SMILES: CC1=C(C(=C(C=C1)OC)P(C(C)(C)C)C(C)(C)C)C2=C(C=C(C=C2C(C)C)C(C)C)C(C)C.CS(=O)(=O)O.C1=CC=C([C-]=C1)C2=CC=CC=C2N.[Pd]
• PubChem CID: 117065433
• Molecular Weight: 838.43

Chemical and Physical Properties

• Sensitivity: Air sensitive
• Melt Point(°C): 220-250 °C