Triisopropoxyvanadium(V) Oxide（VTIP） - ≥97%(T) , CAS No.5588-84-1

CAS: 5588-84-1 Cat. No.: T162313 Molecular Weight: 244.2 Beilstein Registry Number: 1(1)184 EC Number: 226-997-4 PubChem CID: 79702

GRADE & PURITY ≥97%(T)

Synonyms

Oxotris(propan-2-olato)vanadium | SCHEMBL820046 | DTXSID60904393 | VTIP | oxovanadium;propan-2-ol | DSGGJXAUQHKOGQ-UHFFFAOYSA-N | MFCD00015017 | Vanadic acid (H3VO4) tris(1-methylethyl) ester | D92612 | Vanadium(V) oxytriisopropoxide | Oxotri(isopropoxo)v

Storage

Protected from light,Room temperature,Argon charged

Shipped In

Normal

Specifications

Synonyms

Oxotris(propan-2-olato)vanadium | SCHEMBL820046 | DTXSID60904393 | VTIP | oxovanadium;propan-2-ol | DSGGJXAUQHKOGQ-UHFFFAOYSA-N | MFCD00015017 | Vanadic acid (H3VO4) tris(1-methylethyl) ester | D92612 | Vanadium(V) oxytriisopropoxide | Oxotri(isopropoxo)v

Specifications & Purity

≥97%(T)

Storage

Protected from light, Room temperature, Argon charged

Shipped In

Normal

Purity

≥97%(T)

Names and Identifiers

• Pubchem Sid: 504755406
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504755406
• Canonical Smiles: CC(C)O.CC(C)O.CC(C)O.O=[V]
• IUPAC Name: oxovanadium;propan-2-ol
• InChIKey: JOUSPCDMLWUHSO-UHFFFAOYSA-N
• INCHI: 1S/3C3H8O.O.V/c3*1-3(2)4;;/h3*3-4H,1-2H3
• Isomeric SMILES: CC(C)O.CC(C)O.CC(C)O.O=[V]
• PubChem CID: 79702
• Molecular Weight: 244.2
• Beilstein: 1(1)184
• Reaxy-Rn: 3662904

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic oxygen compounds
    • Class Organooxygen compounds
      • Subclass Alcohols and polyols

• Kingdom: Organic compounds
• Superclass: Organic oxygen compounds
• Class: Organooxygen compounds
• Subclass: Alcohols and polyols
• Intermediate Tree Nodes: Not available
• Direct Parent: Secondary alcohols
• Alternative Parents: Organic transition metal salts Organic oxides Hydrocarbon derivatives
• Molecular Framework: Not available
• Substituents: Secondary alcohol - Organic transition metal salt - Organic oxide - Hydrocarbon derivative - Organic salt - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as secondary alcohols. These are compounds containing a secondary alcohol functional group, with the general structure HOC(R)(R') (R,R'=alkyl, aryl).
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Miscible with toluene, hexane and isopropanol.
• Sensitivity: Moisture sensitive. light sensitive
• Refractive Index: 1.479
• Flash Point(°F): 113°F
• Flash Point(°C): 45℃
• Boil Point(°C): 80-82 °C/2 mmHg
• Melt Point(°C): -12°C
• Molecular Weight: 247.230 g/mol
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 247.111 Da
• Monoisotopic Mass: 247.111 Da
• Topological Polar Surface Area: 77.800 Ų
• Heavy Atom Count: 14
• Formal Charge: 0
• Complexity: 62.900
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 4

XLogP3

References

1. Xuguang Han, Yan Zhang, Mengmeng Liu, Yifei Sun, Wenshan Gou, Zhao Xu, Chang Ming Li.  (2023)  In situ growth of amorphous vanadium oxide nanospheres on carbon cloth as free-standing cathodes used in high performance aqueous zinc-ion batteries.  Inorganic Chemistry Frontiers,  10  (7): (2125-2135).  [PMID:] [10.1039/D2QI02756A]

2. Weixing He, Tengteng Gu, Xijun Xu, Shiyong Zuo, Jiadong Shen, Jun Liu, Min Zhu.  (2022)  Uniform In Situ Grown ZIF-L Layer for Suppressing Hydrogen Evolution and Homogenizing Zn Deposition in Aqueous Zn-Ion Batteries.  ACS Applied Materials & Interfaces,      [PMID:36031804] [10.1021/acsami.2c11313]

3. Xianqing Lv, Chengke Zhao, Xiwei Zhang, Zhuotong Wu, Li Shuai.  (2024)  Preparation of aldehyde-functionalized cellulose nanocrystals via aerobic oxidation of cellulose in a recyclable triisopropoxy vanadium oxidation system.  GREEN CHEMISTRY,  26  (4): (1876-1882).  [PMID:] [10.1039/D3GC04583H]