Trimethylsulfonium hydroxide solution - 0.2mol/L in methanol , CAS No.17287-03-5

CAS: 17287-03-5 Cat. No.: T113600 Molecular Weight: 94.18 Beilstein Registry Number: 3910286 EC Number: 628-493-3 PubChem CID: 11105313

GRADE & PURITY 0.2mol/L in methanol

Synonyms

DTXSID70938225 | Trimethylsulfoniumhydroxyd | UNII-835839L58Y | IODO-GLUTIONAL [WHO-DD] | Trimethylsulfanium Hydroxide | T1576 | trimethylsulfanium;hydroxide | 835839L58Y | MFCD00216756 | MDTPTXSNPBAUHX-UHFFFAOYSA-M | Sulfonium, trimethyl-, hydroxide | AI

Storage

Store at -20°C

Shipped In

Ice chest + Ice pads

Overview

Trimethylsulfonium hydroxide (TMSH) is a methylating reagent. It can be prepared by dissolving trimethylsulfonium iodide in methanol and water solvent further treating with silver oxide.

Specifications

Synonyms

DTXSID70938225 | Trimethylsulfoniumhydroxyd | UNII-835839L58Y | IODO-GLUTIONAL [WHO-DD] | Trimethylsulfanium Hydroxide | T1576 | trimethylsulfanium;hydroxide | 835839L58Y | MFCD00216756 | MDTPTXSNPBAUHX-UHFFFAOYSA-M | Sulfonium, trimethyl-, hydroxide | AI

Specifications & Purity

0.2mol/L in methanol

Storage

Store at -20°C

Shipped In

Ice chest + Ice pads

This product requires cold chain shipping. Ground and other economy services are not available.

Names and Identifiers

• Pubchem Sid: 504766009
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504766009
• Canonical Smiles: C[S+](C)C.[OH-]
• IUPAC Name: trimethylsulfanium;hydroxide
• InChIKey: MDTPTXSNPBAUHX-UHFFFAOYSA-M
• INCHI: 1S/C3H9S.H2O/c1-4(2)3;/h1-3H3;1H2/q+1;/p-1
• Isomeric SMILES: C[S+](C)C.[OH-]
• WGK Germany: 2
• PubChem CID: 11105313
• UN Number: 3286
• Molecular Weight: 94.18
• Beilstein: 3910286
• Reaxy-Rn: 3910286

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic oxygen compounds
    • Class Organic oxoanionic compounds

• Kingdom: Organic compounds
• Superclass: Organic oxygen compounds
• Class: Organic oxoanionic compounds
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic oxoanionic compounds
• Alternative Parents: Organosulfur compounds Organic salts Organic oxides Hydrocarbon derivatives Organic cations
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Organic oxide - Hydrocarbon derivative - Organic salt - Organosulfur compound - Organic hydroxide - Organic cation - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as organic oxoanionic compounds. These are organic compounds containing an oxoanion.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: heat sensitive
• Flash Point(°F): 11℃
• Flash Point(°C): 11℃
• Molecular Weight: 94.180 g/mol
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 94.0452 Da
• Monoisotopic Mass: 94.0452 Da
• Topological Polar Surface Area: 2.000 Ų
• Heavy Atom Count: 5
• Formal Charge: 0
• Complexity: 8.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

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