2,3,4,6-Tetra-O-(trimethylsilyl)-D-glucono-delta-lactone - ≥95% , CAS No.32384-65-9

CAS: 32384-65-9 Cat. No.: T588728 Molecular Weight: 466.87 EC Number: 608-732-8

GRADE & PURITY ≥95%

Synonyms

2,3,4,6-Tetra-O-(trimethylsilyl)-D-glucono-delta-lactone | methane sulfonic acid sodium salt | DS-7487 | (3R,4S,5R,6R)-3,4,5-tri((trimethylsilyl)oxy)-6-(((trimethylsilyl)oxy)methyl)tetra hydro-2H-pyran-2-one | (3R,4S,5R,6R)-3,4,5-Tris((trimethylsilyl)oxy)

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Specifications

Synonyms

2, 3, 4, 6-Tetra-O-(trimethylsilyl)-D-glucono-delta-lactone | methane sulfonic acid sodium salt | DS-7487 | (3R, 4S, 5R, 6R)-3, 4, 5-tri((trimethylsilyl)oxy)-6-(((trimethylsilyl)oxy)methyl)tetra hydro-2H-pyran-2-one | (3R, 4S, 5R, 6R)-3, 4, 5-Tris((trimethylsilyl)oxy)

Specifications & Purity

≥95%

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥95%

Names and Identifiers

• Pubchem Sid: 504765856
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504765856
• Canonical Smiles: C[Si](C)(C)OCC1C(C(C(C(=O)O1)O[Si](C)(C)C)O[Si](C)(C)C)O[Si](C)(C)C
• IUPAC Name: (3R,4S,5R,6R)-3,4,5-tris(trimethylsilyloxy)-6-(trimethylsilyloxymethyl)oxan-2-one
• InChIKey: VNGTZLYNGGLPIZ-WCXIOVBPSA-N
• INCHI: 1S/C18H42O6Si4/c1-25(2,3)20-13-14-15(22-26(4,5)6)16(23-27(7,8)9)17(18(19)21-14)24-28(10,11)12/h14-17H,13H2,1-12H3/t14-,15-,16+,17-/m1/s1
• Isomeric SMILES: C[Si](C)(C)OC[C@@H]1[C@H]([C@@H]([C@H](C(=O)O1)O[Si](C)(C)C)O[Si](C)(C)C)O[Si](C)(C)C
• Molecular Weight: 466.87

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic oxygen compounds
    • Class Organooxygen compounds
      • Subclass Carbohydrates and carbohydrate conjugates
        • Level5 Monosaccharides
          • Level6 Hexoses
            • Level7 Gluconolactones

• Kingdom: Organic compounds
• Superclass: Organic oxygen compounds
• Class: Organooxygen compounds
• Subclass: Carbohydrates and carbohydrate conjugates
• Intermediate Tree Nodes: Monosaccharides - Hexoses
• Direct Parent: Gluconolactones
• Alternative Parents: Delta valerolactones Oxanes Trialkylheterosilanes Silyl ethers Carboxylic acid esters Oxacyclic compounds Organic metalloid salts Monocarboxylic acids and derivatives Organic oxides Hydrocarbon derivatives Carbonyl compounds
• Molecular Framework: Aliphatic heteromonocyclic compounds
• Substituents: Gluconolactone - Delta valerolactone - Delta_valerolactone - Oxane - Trialkylheterosilane - Silyl ether - Lactone - Carboxylic acid ester - Oxacycle - Organic metalloid salt - Organoheterocyclic compound - Monocarboxylic acid or derivatives - Organoheterosilane - Carboxylic acid derivative - Organosilicon compound - Organic metalloid moeity - Organic oxide - Carbonyl group - Hydrocarbon derivative - Aliphatic heteromonocyclic compound
• Description: This compound belongs to the class of organic compounds known as gluconolactones. These are polyhydroxy acids containing a gluconolactone molecule, which is characterized by a tetrahydropyran substituted by three hydroxyl groups, one ketone group, and one hydroxymethyl group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Moisture sensitive
• Melt Point(°C): 171 °C
• Molecular Weight: 466.900 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 9
• Exact Mass: 466.206 Da
• Monoisotopic Mass: 466.206 Da
• Topological Polar Surface Area: 63.200 Ų
• Heavy Atom Count: 28
• Formal Charge: 0
• Complexity: 530.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 4
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

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