Aluminum-nickel alloy - purum, 50% Al basis,50% Ni basis , CAS No.12635-27-7

CAS: 12635-27-7 Cat. No.: A431664 Molecular Weight: 85.675 EC Number: 682-897-4

GRADE & PURITY purum, 50% Al basis,50% Ni basis

Synonyms

aluminum;nickel | Raney(R)-Nickel, W.R. Grace and Co. Raney(R)2400, slurry, in H2O, active catalyst | DTXSID9058315 | Raney(R)-Nickel, W.R. Grace and Co. Raney(R)2800, slurry, in H2O, active catalyst | aluminum-nickel | Aluminium-nickel | nickel-aluminium

Storage

Room temperature

Shipped In

FedEx DG Service

Overview

Application

Aluminum-nickel alloy can be used: For the reduction of nitriles, nitro compounds and oximes to primary amines. For the conversion of carbonyl compounds to hydrocarbons. As a reducing agent to convert Ar-X derivatives to Ar-H compounds. For the synthesis of Raney nickel catalyst to be used as an alkylating agent. To synthesize non-pyrophoric Ni catalyst by alkali leaching. For the synthesis of alloyed skeletal Ni catalysts.

Specifications

Synonyms

aluminum;nickel | Raney(R)-Nickel, W.R. Grace and Co. Raney(R)2400, slurry, in H2O, active catalyst | DTXSID9058315 | Raney(R)-Nickel, W.R. Grace and Co. Raney(R)2800, slurry, in H2O, active catalyst | aluminum-nickel | Aluminium-nickel | nickel-aluminium

Specifications & Purity

purum, 50% Al basis, 50% Ni basis

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

Storage

Room temperature

Shipped In

FedEx DG Service

This product requires cold chain shipping. Ground and other economy services are not available.

Grade

purum

Names and Identifiers

• Canonical Smiles: [Al].[Ni]
• IUPAC Name: aluminum;nickel
• InChIKey: NPXOKRUENSOPAO-UHFFFAOYSA-N
• INCHI: 1S/Al.Ni
• Isomeric SMILES: [Al].[Ni]
• WGK Germany: 3
• Alternate CAS: 12003-78-0
• UN Number: 3089
• Packing Group: II
• Molecular Weight: 85.675
• Reaxy-Rn: 54579804
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=54579804&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Inorganic salts

• Kingdom: Inorganic compounds
• Superclass: Inorganic salts
• Class: Not available
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Inorganic salts
• Alternative Parents: Intermetallic post-transition metal compounds Inorganic nickel compounds
• Molecular Framework: Not available
• Substituents: Intermetallic post-transition metal - Inorganic salt - Inorganic nickel compound
• Description: This compound belongs to the class of inorganic compounds known as inorganic salts. These are inorganic compounds consisting of an assembly of cations and anions.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Molecular Weight: 85.675 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 84.9169 Da
• Monoisotopic Mass: 84.9169 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 2
• Formal Charge: 0
• Complexity: 0.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

References

1. Zhe-Hui Zhang, Ming-Jie Song, Saravanakumar Elangovan, Zhuohua Sun, Tong-Qi Yuan.  (2024)  From lignin-derived monomers to 1,4-cyclohexanediol via a two steps Dakin oxidation and hydrodeoxygenation reaction.  CATALYSIS TODAY,      [PMID:] [10.1016/j.cattod.2024.115079]

2. Zhe-Hui Zhang, Meng-Ying Liu, Zhuohua Sun, Katalin Barta, Tong-Qi Yuan.  (2024)  Simple building blocks from forestry residues via convergent catalytic pathways.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.153942]