Methyltrioxorhenium(VII)（MTO） - ≥98% , CAS No.70197-13-6

CAS: 70197-13-6 Cat. No.: M100685 Molecular Weight: 249.24 Beilstein Registry Number: 3927932 EC Number: 677-701-9 PubChem CID: 2734010

GRADE & PURITY ≥98%

Synonyms

MTO | AKOS015902546 | methyl trioxorhenium | Rhenium, methyltrioxo-, (T-4)- | SC11060 | Methyltrioxorhenium [MI] | methyl(trioxo)rhenium | PQTLALPZRPFYIT-UHFFFAOYSA-N | methlytrioxorhenium | Rhenium, methyltrioxo-,(T-4)- (9CI) | methyl rhenium trioxide |

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice

Overview

Methyltrioxorhenium(VII) is a potent catalytic oxidant for converting alkenes to epoxides in a variety of solvents as well as an effective antioxidant under various conditions.
A catalytic oxidant and antioxidant.

Product class
M-C, Homogeneous Catalysts, Alkyl Ligands, Precursors for Heterogeneous Catalysts

Reaction type
Oxidation, Metathesis

Chemical properties

Chemical formula

CH3ORe

Empirical formula

CH3ReO3

Molecular weight

249.24

Metal

Re

Theoretical metal content

75

Physical state

crystalline

Color

pale gray

Specifications

Synonyms

MTO | AKOS015902546 | methyl trioxorhenium | Rhenium, methyltrioxo-, (T-4)- | SC11060 | Methyltrioxorhenium [MI] | methyl(trioxo)rhenium | PQTLALPZRPFYIT-UHFFFAOYSA-N | methlytrioxorhenium | Rhenium, methyltrioxo-, (T-4)- (9CI) | methyl rhenium trioxide |

Specifications & Purity

≥98%

Storage

Store at 2-8°C, Protected from light, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥98%

Names and Identifiers

• Canonical Smiles: [CH3-].O=[Re](=O)=O
• IUPAC Name: carbanide;trioxorhenium
• InChIKey: VZSXFJPZOCRDPW-UHFFFAOYSA-N
• INCHI: 1S/CH3.3O.Re/h1H3;;;;/q-1
• Isomeric SMILES: [CH3-].O=[Re](=O)=O
• WGK Germany: 3
• PubChem CID: 2734010
• Molecular Weight: 249.24
• Beilstein: 3927932
• Reaxy-Rn: 3927932

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Class Transition metal organides
      • Subclass Transition metal oxides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Class: Transition metal organides
• Subclass: Transition metal oxides
• Intermediate Tree Nodes: Not available
• Direct Parent: Transition metal oxides
• Alternative Parents: Inorganic salts Inorganic oxides Carbides
• Molecular Framework: Not available
• Substituents: Transition metal oxide - Carbide - Inorganic oxide - Inorganic salt
• Description: This compound belongs to the class of inorganic compounds known as transition metal oxides. These are inorganic compounds containing an oxygen atom of an oxidation state of -2, in which the heaviest atom bonded to the oxygen is a transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Solubility in water: very soluble in H2O
• Sensitivity: light sensitive ;air sensitive
• Melt Point(°C): 111°C
• Molecular Weight: 249.240 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 249.964 Da
• Monoisotopic Mass: 249.964 Da
• Topological Polar Surface Area: 51.200 Ų
• Heavy Atom Count: 5
• Formal Charge: -1
• Complexity: 65.500
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

References

1. Xueni Zhong, Qianqian Lv, Qiyun Yong, Wenping Hu, Dan Li, Shuhui Ji, Liuyue Zhan, Wenbin Chen, Min Li, Jinsheng Lin, Cuirong Sun.  (2022)  Forced degradation studies of elagolix sodium with the implementation of high resolution LC-UV-PDA-MSn (n = 1,2,3…) and NMR structural elucidation.  JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS,      [PMID:36495708] [10.1016/j.jpba.2022.115198]