GRADE & PURITY ≥99.9% metals basis

Synonyms

lithium tbutoxide | lithium t-butoxide | lithium(1+) ion 2-methylpropan-2-olate | LiOtBu | 2-Methyl-2-propanol lithium salt | lithium tertbutoxide | Lithium tert-butoxide | Tussol: | L0253 | Lithium t-butoxide, 1M in THF | Lithium tert -butanolate | lithi

Storage

Room temperature,Argon charged

Shipped In

Normal

Specifications

Synonyms

lithium tbutoxide | lithium t-butoxide | lithium(1+) ion 2-methylpropan-2-olate | LiOtBu | 2-Methyl-2-propanol lithium salt | lithium tertbutoxide | Lithium tert-butoxide | Tussol: | L0253 | Lithium t-butoxide, 1M in THF | Lithium tert -butanolate | lithi

Specifications & Purity

≥99.9% metals basis

Storage

Room temperature, Argon charged

Shipped In

Normal

Purity

≥99.9% metals basis

Names and Identifiers

• Pubchem Sid: 504769494
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504769494
• Canonical Smiles: [Li+].CC(C)(C)[O-]
• IUPAC Name: lithium;2-methylpropan-2-olate
• InChIKey: LZWQNOHZMQIFBX-UHFFFAOYSA-N
• INCHI: 1S/C4H9O.Li/c1-4(2,3)5;/h1-3H3;/q-1;+1
• Isomeric SMILES: [Li+].CC(C)(C)[O-]
• WGK Germany: 3
• UN Number: 3206
• Packing Group: II
• Molecular Weight: 80.05
• Beilstein: 3620018
• Reaxy-Rn: 8541101
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=8541101&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic salts
    • Class Organic metal salts
      • Subclass Organic alkali metal salts

• Kingdom: Organic compounds
• Superclass: Organic salts
• Class: Organic metal salts
• Subclass: Organic alkali metal salts
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic lithium salts
• Alternative Parents: Organic zwitterions Organic oxides Hydrocarbon derivatives Alkoxides
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Organic lithium salt - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organic zwitterion - Alkoxide - Organooxygen compound - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as organic lithium salts. These are organic compounds containing a lithium ion.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Hygroscopic；Moisture sensitive
• Flash Point(°F): -18.4 °F
• Flash Point(°C): -28 °C
• Boil Point(°C): 110 °C/at 0.1333 hPa
• Molecular Weight: 80.100 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 80.0813 Da
• Monoisotopic Mass: 80.0813 Da
• Topological Polar Surface Area: 23.100 Ų
• Heavy Atom Count: 6
• Formal Charge: 0
• Complexity: 29.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

References

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2. Muhammad Irfan, Yuli Zang, Zeheng Yang, Weixin Zhang.  (2023)  Hydrophobicity of 2-((8-hydroxyoctyl)oxy)ethyl-sulfanetrione in conducting solid polymer electrolyte boosting the electrochemical performance of lithium metal batteries.  JOURNAL OF POWER SOURCES,      [PMID:] [10.1016/j.jpowsour.2023.233206]

3. Yunlong Zhang, Muhammad Irfan, Zeheng Yang, Kun Liu, Jianhui Su, Weixin Zhang.  (2022)  Lithium hydroxyphenyl propanesulfonate imparts composite solid polymer electrolytes with ultrahigh ionic conductivity for dendrite free lithium batteries.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2022.134775]

4. Zifeng Yang, Lei Liu, Hongzhe An, Chenhao Li, Zhencai Zhang, Wenjuan Fang, Fei Xu, Suojiang Zhang.  (2020)  Cost-Effective Synthesis of High Molecular Weight Biobased Polycarbonate via Melt Polymerization of Isosorbide and Dimethyl Carbonate.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.0c00430]

5. Ru-Jun Chen, Yi-Bo Zhang, Ting Liu, Bing-Qing Xu, Yang Shen, Yuan-Hua Lin, Ce-Wen Nan.  (2017)  Improvement of the conductivity of sol-gel derived Li-La-Zr-O thin films by the addition of surfactant.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2017.05.201]

6. Ru-Jun Chen, Mian Huang, Wen-Ze Huang, Yang Shen, Yuan-Hua Lin, Ce-Wen Nan.  (2014)  Sol–gel derived Li–La–Zr–O thin films as solid electrolytes for lithium-ion batteries.  Journal of Materials Chemistry A,  2  (33): (13277-13282).  [PMID:] [10.1039/C4TA02289K]

7. Ping Sun, Li Huang, Zimu Li, Yao Yang, Shiman Lu, Nansha Gao, Hongzhong Chen, Xiaowei Zeng, Zhongjian Xie.  (2024)  Charge-reversal biodegradable nanoplatform with ferroptosis and ICD induction for tumor synergistic treatment.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.149234]

8. Jiabin Fang, Kang Wu, Lijun Qin, Jianguo Li, Wangle Zhang, Ting Gong, Hao Feng.  (2025)  Atomic Layer Deposited Silicon Anode with Nanoporous Fluorinated Surface Modulation Enabling Invertible Electrochemical Lithium Storage.  Small,      [PMID:40630042] [10.1002/smll.202504940]