Methoxydiphenylphosphine - ≥98%(GC) , CAS No.4020-99-9

CAS: 4020-99-9 Cat. No.: M158552 Molecular Weight: 216.22 Beilstein Registry Number: 16(3)845 EC Number: 223-683-9

GRADE & PURITY ≥98%(GC)

Synonyms

AMY19756 | SY048353 | F10242 | Methyl diphenylphosphinite, 97% | EINECS 223-683-9 | Phosphinous acid, diphenyl-, methyl ester | A824980 | FT-0625275 | MFCD00048025 | methyldiphenyl phosphinite | SCHEMBL187947 | methoxy(diphenyl)phosphane | Methyl diphenyl

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

Ased as: · Catalyst for hydroformylative desymmetrization of bisalkenyl carbinols and bishomoallylic carbinols · Ligand in rhodium-catalyzed hydroformylation of bishomoallylic alcohols · Calatyst in preparation of γ-lactones via branched-regioselective hydroformylation reactions · Ligand for nickel-catalyzed hydrocyanation reactions · Catalyst in annulation reactions

Specifications

Synonyms

AMY19756 | SY048353 | F10242 | Methyl diphenylphosphinite, 97% | EINECS 223-683-9 | Phosphinous acid, diphenyl-, methyl ester | A824980 | FT-0625275 | MFCD00048025 | methyldiphenyl phosphinite | SCHEMBL187947 | methoxy(diphenyl)phosphane | Methyl diphenyl

Specifications & Purity

≥98%(GC)

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥98%(GC)

Names and Identifiers

• Pubchem Sid: 488185434
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488185434
• Canonical Smiles: COP(C1=CC=CC=C1)C2=CC=CC=C2
• IUPAC Name: methoxy(diphenyl)phosphane
• InChIKey: OAADXJFIBNEPLY-UHFFFAOYSA-N
• INCHI: 1S/C13H13OP/c1-14-15(12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3
• Isomeric SMILES: COP(C1=CC=CC=C1)C2=CC=CC=C2
• WGK Germany: 3
• Molecular Weight: 216.22
• Beilstein: 16(3)845
• Reaxy-Rn: 1640480
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1640480&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Class Benzene and substituted derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Class: Benzene and substituted derivatives
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Benzene and substituted derivatives
• Alternative Parents: Organopnictogen compounds Organophosphorus compounds Organooxygen compounds Hydrocarbon derivatives
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: Monocyclic benzene moiety - Organic oxygen compound - Organopnictogen compound - Hydrocarbon derivative - Organophosphorus compound - Organooxygen compound - Aromatic homomonocyclic compound
• Description: This compound belongs to the class of organic compounds known as benzene and substituted derivatives. These are aromatic compounds containing one monocyclic ring system consisting of benzene.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Air sensitive; Moisture sensitive
• Refractive Index: 1.604
• Flash Point(°F): 230°F
• Flash Point(°C): >110 °C
• Boil Point(°C): 149 °C/6 mmHg
• Molecular Weight: 216.210 g/mol
• XLogP3: 3.100
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 216.07 Da
• Monoisotopic Mass: 216.07 Da
• Topological Polar Surface Area: 9.200 Ų
• Heavy Atom Count: 15
• Formal Charge: 0
• Complexity: 153.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1