Methylenebis(phosphonic dichloride) - ≥97% , CAS No.1499-29-2

CAS: 1499-29-2 Cat. No.: M332858 Molecular Weight: 249.78 EC Number: 627-821-2
AVAILABLE TO ORDER
GRADE & PURITY ≥97%
Synonyms
Methylenebis(phosphonic dichloride), 97% | 4-Methoxy-2-Phenylacetophenone | Bis(dichlorophosphonyl)methane | AKOS016012993 | Phosphonic dichloride, methylenebis- | Bis(dichlorophosphoryl)methane | SCHEMBL668667 | DTXSID10407940 | EN300-134475 | [(dichloro
Storage
Room temperature
Shipped In
Normal
 ·  off list, applied to all prices below.
Size
Status
Price
Qty
250mg
M332858-250mg
4
$38.90
1g
M332858-1g
2
$104.90
5g
M332858-5g
5
$359.90
Enter a quantity for the sizes you want to add.
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Why this grade

≥97% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Room temperature Ships Normal Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

📚

Literature proof

Cited in 0 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Product description:

Methylenebis(phosphonic dichloride) is an organophosphorus compound that is commonly used in phosphonylation reactions. It is more reactive and the rate of reaction is faster compared to POCl3. This is because the phosphorus center is more electrophilic due to the lack of electron back-donation from the CH2 group.

Specifications

Synonyms
Methylenebis(phosphonic dichloride), 97% | 4-Methoxy-2-Phenylacetophenone | Bis(dichlorophosphonyl)methane | AKOS016012993 | Phosphonic dichloride, methylenebis- | Bis(dichlorophosphoryl)methane | SCHEMBL668667 | DTXSID10407940 | EN300-134475 | [(dichloro
Specifications & Purity
≥97%
Storage
Room temperature
Shipped In
Normal
Purity
≥97%
Names and Identifiers
Pubchem Sid488195071
Canonical SmilesC(P(=O)(Cl)Cl)P(=O)(Cl)Cl
IUPAC Namebis(dichlorophosphoryl)methane
InChIKeyVRXYCDTWIOCJBH-UHFFFAOYSA-N
INCHI1S/CH2Cl4O2P2/c2-8(3,6)1-9(4,5)7/h1H2
Isomeric SMILES C(P(=O)(Cl)Cl)P(=O)(Cl)Cl
UN Number 3261
Packing Group I
Molecular Weight 249.78
Reaxy-Rn 1072979
Reaxys-RN_link_address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1072979&ln=

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

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🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomOrganic compounds
SuperclassOrganic acids and derivatives
ClassOrganic phosphonic acids and derivatives
SubclassNot available
Intermediate Tree Nodes Not available
Direct ParentOrganic phosphonic acids and derivatives
Alternative Parents Organophosphorus compounds  Organic oxides  Hydrocarbon derivatives  
Molecular FrameworkAliphatic acyclic compounds
Substituents Organophosphonic acid derivative - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organophosphorus compound - Aliphatic acyclic compound
DescriptionThis compound belongs to the class of organic compounds known as organic phosphonic acids and derivatives. These are organic compounds containing phosphonic acid or a derivative thereof.
External Descriptors Not available
3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

7 results found

Lot NumberCertificate TypeDateItem
C2324188Certificate of AnalysisJan 26, 2026 M332858
C2324183Certificate of AnalysisJan 26, 2026 M332858
C2324181Certificate of AnalysisJan 26, 2026 M332858
C2324180Certificate of AnalysisJan 26, 2026 M332858
C2324179Certificate of AnalysisJan 26, 2026 M332858
C2324189Certificate of AnalysisJan 03, 2023 M332858
C2505165Certificate of AnalysisJan 03, 2023 M332858
Chemical and Physical Properties
SensitivityMoisture sensitive
Melt Point(°C)102-104° C (lit.)
Molecular Weight249.800 g/mol
XLogP31.800
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count2
Rotatable Bond Count2
Exact Mass249.825 Da
Monoisotopic Mass247.828 Da
Topological Polar Surface Area34.100 Ų
Heavy Atom Count9
Formal Charge0
Complexity157.000
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
The total count of all stereochemical bonds0
Covalently-Bonded Unit Count1
Solution Calculators
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