(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-t-butylphosphine - ≥97% , CAS No.155830-69-6

CAS: 155830-69-6 Cat. No.: R396593 Molecular Weight: 542.45 EC Number: 639-808-9 PubChem CID: 250184787
AVAILABLE TO ORDER
GRADE & PURITY ≥97%
Synonyms
(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine | (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS) | Josiphos SL-J002-1
Storage
Room temperature,Argon charged
Shipped In
Normal
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R396593-100mg
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R396593-500mg
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1g
R396593-1g
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2g
R396593-2g
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R396593-5g
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10g
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Why this grade

≥97% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Room temperature,Argon charged Ships Normal Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

📚

Literature proof

Cited in 0 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

application:

It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester.


product description:

(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-tBu) is a chiral ferrocenyl diphosphine ligand.


Specifications

Synonyms
(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine | (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS) | Josiphos SL-J002-1
Specifications & Purity
≥97%
Legal Information
Sold in collaboration with Solvias for research purposes only. Solvias Josiphos Ligand Kit component.
Storage
Room temperature, Argon charged
Shipped In
Normal
Purity
≥97%
Names and Identifiers
Pubchem Sid504773766
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/504773766
Canonical Smiles[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)P(C(C)(C)C)C(C)(C)C
InChIKeySTAGMXYQPGLLTD-GHVWMZMZSA-N
INCHI1S/C27H35P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-21H,1-7H3;1-5H;/t21-;;/m1../s1
WGK Germany 3
PubChem CID 250184787
Molecular Weight 542.45

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

10 results found

Lot NumberCertificate TypeDateItem
C2624149Certificate of AnalysisApr 06, 2026 R396593
C2619161Certificate of AnalysisMar 24, 2026 R396593
B2207359Certificate of AnalysisAug 20, 2025 R396593
B2207364Certificate of AnalysisAug 20, 2025 R396593
B2207365Certificate of AnalysisAug 20, 2025 R396593
B2207366Certificate of AnalysisAug 20, 2025 R396593
B2207375Certificate of AnalysisAug 20, 2025 R396593
B2207377Certificate of AnalysisAug 20, 2025 R396593
B2207378Certificate of AnalysisAug 20, 2025 R396593
B2207387Certificate of AnalysisAug 20, 2025 R396593
Chemical and Physical Properties
SensitivityAir sensitive
Specific Rotation[α]-412° ±15° (c 0.5, CHCl3)
Solution Calculators
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