(Acetylacetonato)dicarbonylrhodium(I) - ≥99% , CAS No.14874-82-9

CAS: 14874-82-9 Cat. No.: A118542 Molecular Weight: 258.03 EC Number: 238-947-9
AVAILABLE TO ORDER
GRADE & PURITY ≥99%
Synonyms
CARAC | Rh(CO)2acac
Storage
Room temperature,Argon charged
Shipped In
Normal
 ·  off list, applied to all prices below.
Size
Status
Price
Qty
25mg
A118542-25mg
8-12 wks(?) Production requires sourcing of materials. We appreciate your patience and understanding.
$130.90
100mg
A118542-100mg
1

$400.90

$467.90
Save $67.00 (14.32%)
250mg
A118542-250mg
8-12 wks(?) Production requires sourcing of materials. We appreciate your patience and understanding.

$893.90

$926.90
Save $33.00 (3.56%)
500mg
A118542-500mg
2

$926.90

$1,476.90
Save $550.00 (37.24%)
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Why this grade

≥99% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Room temperature,Argon charged Ships Normal Check lot-specific COA for exact specifications.

📋

Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

📚

Literature proof

Cited in 1 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a fluorous-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds.
A catalyst for various carbonylation reactions


Product class
M-O, Homogeneous Catalysts, Acetylacetonate Ligands

Reaction type
Carbonylation, Hydroformylation, Reduction

Chemical properties

Chemical formula

C7H7O4Rh

Empirical formula

Rh(CO)2(acac)

Molecular weight

258.04

Metal

Rh

Theoretical metal content

40

Physical state

crystalline

Color

green

Specifications

Synonyms
CARAC | Rh(CO)2acac
Specifications & Purity
≥99%
Storage
Room temperature, Argon charged
Shipped In
Normal
Purity
≥99%
Names and Identifiers
Canonical Smiles[C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Rh]
InChIKeyBZCAWKOPWNIDOC-FGSKAQBVSA-M
INCHI1S/C5H8O2.2CO.Rh/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
Isomeric SMILES CC(=[OH+])CC(=[OH+])C.[C-]#[O+].[C-]#[O+].[Rh]
WGK Germany 3
UN Number 3467
Packing Group II
Molecular Weight 258.03
Reaxy-Rn 20671103
Reaxys-RN_link_address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=20671103&ln=

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

8 results found

Lot NumberCertificate TypeDateItem
J1810100Certificate of AnalysisMay 20, 2026 A118542
G2220243Certificate of AnalysisMay 08, 2026 A118542
H2113147Certificate of AnalysisMay 12, 2025 A118542
H2113148Certificate of AnalysisMay 12, 2025 A118542
A1911136Certificate of AnalysisNov 11, 2022 A118542
F2424490Certificate of AnalysisJun 08, 2022 A118542
I2528044Certificate of AnalysisJun 08, 2022 A118542
K2310045Certificate of AnalysisMay 10, 2021 A118542
Chemical and Physical Properties
SolubilitySolubility in water: insoluble in water;Soluble in acetone
SensitivityAir Sensitive
Melt Point(°C)154-156°C
Documents & Articles
Citations of This Product
References
1. Jian Ruan, Youkai Jiang, Yaheng Zhang, Luhaibo Zhao, Jie Zhang, Zhiyong Tang.  (2022)  Towards more efficient hydroformylation of long-chain alkenes in aqueous biphasic system using microbubbles.  Asia-Pacific Journal of Chemical Engineering,  18  (1): (e2842).  [PMID:] [10.1002/apj.2842]
Solution Calculators
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