1,2-Ethanedithiol - ≥97% , CAS No.540-63-6

CAS: 540-63-6 Cat. No.: E106222 Molecular Weight: 94.19 Beilstein Registry Number: 505946 EC Number: 208-752-3

GRADE & PURITY ≥97%

Synonyms

1,2-Dimercaptoethane | Ethylene mercaptan | Dithioglycol

Storage

Room temperature,Argon charged

Shipped In

Normal

Overview

1,2-Ethanedithiol (EDT) is an organosulfur compound that is used as an organic building block in chemical synthesis. It is also used as a ligand for metal ions to prepare metal complexes. 

Application：
1,2-Ethanedithiol can be used to synthesize:
1,3-Dithiolanes by reacting with aldehydes or ketones.
Dithiazepan-3-yl-alkanoic acids by cyclocondensation reaction with amino acids and formaldehyde.
EDT can also be used as a scavenger in solid phase peptide synthesis for the efficient deprotection of the peptide resin.

Specifications

Synonyms

1, 2-Dimercaptoethane | Ethylene mercaptan | Dithioglycol

Specifications & Purity

≥97%

Biochemical and Physiological Mechanisms

1, 2-Ethanedithiol is a metal complexing agent. It is a reagent for converting carbonyls to thioacetals under mild conditions, as well as reverses the inhibition of alphaketoaldehydes on mitosis in E. coli.

Storage

Room temperature, Argon charged

Shipped In

Normal

Purity

≥97%

Names and Identifiers

• Pubchem Sid: 504752025
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504752025
• Canonical Smiles: C(CS)S
• IUPAC Name: ethane-1,2-dithiol
• InChIKey: VYMPLPIFKRHAAC-UHFFFAOYSA-N
• INCHI: 1S/C2H6S2/c3-1-2-4/h3-4H,1-2H2
• Isomeric SMILES: C(CS)S
• WGK Germany: 3
• RTECS: KI3325000
• UN Number: 3071
• Molecular Weight: 94.19
• Beilstein: 505946
• Reaxy-Rn: 505946
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=505946&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organosulfur compounds
    • Class Thiols
      • Subclass Alkylthiols

• Kingdom: Organic compounds
• Superclass: Organosulfur compounds
• Class: Thiols
• Subclass: Alkylthiols
• Intermediate Tree Nodes: Not available
• Direct Parent: Alkylthiols
• Alternative Parents: Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Alkylthiol - Hydrocarbon derivative - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as alkylthiols. These are organic compounds containing the thiol functional group linked to an alkyl chain.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Soluble in ethanol, acetone, ether, and benzene. Insoluble in water.
• Sensitivity: Air Sensitive
• Refractive Index: 1.559
• Flash Point(°F): 111.2 °F
• Flash Point(°C): 44℃
• Boil Point(°C): 146°C
• Melt Point(°C): -41.2°C
• Molecular Weight: 94.200 g/mol
• XLogP3: 0.800
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 93.9911 Da
• Monoisotopic Mass: 93.9911 Da
• Topological Polar Surface Area: 2.000 Ų
• Heavy Atom Count: 4
• Formal Charge: 0
• Complexity: 6.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

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64. Fengwei Li, Mengmeng Zhang, Chao Liu, Jie Cheng, Yawen Yang, Xiangda Peng, Zhifeng Li, Wenfeng Cai, Haipeng Yu, Junjie Wu, Yuyu Guo, Hongkun Geng, Yun Fa, Youming Zhang, Dalei Wu, Yizhen Yin.  (2025)  De novo discovery of a molecular glue–like macrocyclic peptide that induces MCL1 homodimerization.  PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA,  122  (13): (e2426006122).  [PMID:40131955] [10.1073/pnas.2426006122]

65. Yifan Wang, Rui Chen, Fengyu Wen, Yageng Bai, Yashu He, Lin Cheng, Haoyuan Tan, Jierun Ma, Pengbo Lian, Yuxuan Gu, Jianxin Mu.  (2024)  Developing PEEK composites with exceptional thermal conductivity and electromagnetic shielding properties by constructing a dense dual-continuous filler network.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2024.135021]

66. Yu Huang, Xiaomei Li, Hua Zhang, Zhiguo Wu, Rohan Weerasooriya, Xing Chen, Jiu Zhou, Jiangling Wu, Jianjiang Xue, Junbo Wang, Lei Feng.  (2024)  Development of an optical fiber surface plasmon resonance sensor decorated with MoS2/AuNP plasmonic hybrid structure by using polydopamine-assisted electroless plating.  OPTICS AND LASER TECHNOLOGY,      [PMID:] [10.1016/j.optlastec.2024.112255]

67. Junli Wang, Chen Luo, Wentao Wang, Hui Wang, Jiaxuan Shi, Taihong Yan, Meiwen Cao, Jianwei Li.  (2024)  Efficient capture of palladium from nuclear wastewater by the sulfide and thiol modified covalent organic framework.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2024.134601]

68. Gomaa Mohamed Gomaa Khalaf, Xinzhao Zhao, Mingyu Li, Chunxia Li, Salman Ali, Tianjun Ma, Hsien-Yi Hsu, Jianbin Zhang, Haisheng Song.  (2024)  Efficient PbS quantum dots tandem solar cells through compatible interconnection layer.  Journal of Energy Chemistry,      [PMID:] [10.1016/j.jechem.2024.06.040]

69. Junfei Liu, Yingbo Dong, Yue Zhang, Wei Liu, Jian Xu, Hai Lin.  (2024)  Enhanced synergistic performance of g-C3N4/MoS2 with hollow structure for tetracycline photocatalytic degradation in complex environments: Performance and mechanism.  Journal of Cleaner Production,      [PMID:] [10.1016/j.jclepro.2024.141983]

70. Yuhui Zeng, Yuanbo Zhang, Meng Peng, Junyang Yin, Weijie Liu, Jianqiao Zhao, Shizhou Tan, Junfeng Liu, Maohua Chen, Zhenyu Chen, Feng Wu, Changqing Chen, Liang Gao, Jiangnan Dai.  (2025)  Excellent Mechanical Performance of Cellulose Composite Papers for Flexible Self-Powered Photodetectors Using the ZnO/PbS Heterojunction.  ACS Applied Materials & Interfaces,      [PMID:39772420] [10.1021/acsami.4c18862]

71. Jiahui Zhang, Dongxin Zhao, Kui Lu, Libo Yuan, Heng Du.  (2024)  Gelation Behavior and Drug Sustained-Release Properties of a Helix Peptide Organohydrogel with pH Responsiveness.  LANGMUIR,      [PMID:38591865] [10.1021/acs.langmuir.4c00266]

72. Ke Ma, Meng Yin, Xiao-Xue Wang, Chen-Yu Wang, Ke-Zheng Chen, Sheng-Lin Qiao.  (2024)  Gold Nanocluster-Based Nanozyme for High-Throughput Colorimetric Detection of SARS-CoV-2.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.4c01049]

73. Yu Lu, Zhixu Wu, Pengfei Xiang, Taiming Ji, Rongxin Tang, Yuhao Wang, Yong Xia.  (2025)  High-performance PbS colloidal quantum dot photodiode for short-wave infrared imaging based on energy band alignment engineering.  OPTICAL MATERIALS,      [PMID:] [10.1016/j.optmat.2025.116714]

74. Mengxuan Yu, Binbin Wang, Runze Huang, Hang Xia, Jing Liu, Chengjie Deng, Jianbing Zhang, Liang Gao, Jiang Tang, Xinzheng Lan.  (2024)  Interfacially-Engineered HgTe Colloidal Quantum Dot Photodiodes Using Self-Assembled Monolayer.  ACS Photonics,      [PMID:] [10.1021/acsphotonics.4c00911]

75. Yichen Bu, Yadong Jiang, Zaihua Duan, Wenxin Zeng, Xing Tang, Jingwen Yang, Zhen Yuan, Huiling Tai.  (2025)  Oriented Crystallization of HgTe Quantum Dots with Low Urbach Band-Tail for Broadband Optoelectronic Logic Gates.  Advanced Optical Materials,      [PMID:] [10.1002/adom.202500295]

76. Yang Zhao, Xinyue Zhao, Lewei Duan, Ruxue Hou, Yuxin Gu, Zhen Liu, Jianbin Chen, Feizhen Wu, Limin Yang, X. Chris Le, Qiuquan Wang, Xiaowen Yan.  (2024)  Reinvent Aliphatic Arsenicals as Reversible Covalent Warheads toward Targeted Kinase Inhibition and Non-acute Promyelocytic Leukemia Cancer Treatment.  JOURNAL OF MEDICINAL CHEMISTRY,      [PMID:38556750] [10.1021/acs.jmedchem.3c02076]

77. Saleem Ullah Saleem, Yanhua Liu, Jing Sui, Geoffrey I.N. Waterhouse, Zhiming Zhang, Liangmin Yu.  (2024)  Stable sandwich-type electrochemical lead ions sensor based on bismuth-metal organic framework and Mxene.  Journal of Environmental Chemical Engineering,      [PMID:] [10.1016/j.jece.2024.113603]

78. Xiao Wang, Zhulu Song, Haodong Tang, Yiwen Li, Huaying Zhong, Jiufeng Wu, Weichao Wang, Simin Chen, Wenjie Zhang, Fan Fang, Junjie Hao, Dan Wu, Peter Müller-Buschbaum, Leifeng Cao, Zeguo Tang, Jun Tang, Lei Zhang, Kai Wang, Wei Chen.  (2024)  Synergic Surface Modifications of PbS Quantum Dots by Sodium Acetate in Solid-State Ligand Exchange toward Short-Wave Infrared Photodetectors.  ACS Applied Materials & Interfaces,      [PMID:39087727] [10.1021/acsami.4c05201]

79. Mingyu Li, Jun Yan, Xinzhao Zhao, Tianjun Ma, Afei Zhang, Shiwu Chen, Guohuan Shen, Gomaa Mohamed Gomaa Khalaf, Jianbing Zhang, Chao Chen, Hsien-Yi Hsu, Haisheng Song, Peizhi Yang, Jiang Tang.  (2024)  Synergistic Enhancement of Efficient Perovskite/Quantum Dot Tandem Solar Cells Based on Transparent Electrode and Band Alignment Engineering.  Advanced Energy Materials,      [PMID:] [10.1002/aenm.202400219]

80. Zhongxin Dong, Shengdao Wang, Siyu Zhong, Yanchao Yang, Guibin Wang.  (2025)  The improved interfacial property and solvent resistance of PEEK/GF composites by crystalline PEEK sizing agent.  COMPOSITES SCIENCE AND TECHNOLOGY,      [PMID:] [10.1016/j.compscitech.2025.111348]

81. Xi Ran, Hang Xia, Jing Liu, Mohan Yuan, Xudong Hu, Ya Wang, Xinzheng Lan.  (2025)  Bifunctional ZnTe Enables Top-Illuminated p-on-n PbS Quantum Dot Infrared Photodetectors and Imagers.  ACS Applied Optical Materials,      [PMID:] [10.1021/acsaom.5c00274]

82. Lin Yi, Li Mengyao, Luo Zijin, Meng Yanan, Zong Yan, Ren Hongyu, Yu Xiaolu, Tan Xiaoqiong, Liu Fan, Wei Tuo, Cheng Qiang.  (2025)  Tissue-specific mRNA delivery and prime editing with peptide–ionizable lipid nanoparticles.  NATURE MATERIALS,      [PMID:40890498] [10.1038/s41563-025-02320-9]

83. Weite Meng, Lixiang Xu, Shaoqing Lu, Mingquan Li, Mengyao Li, Yu Zhang, Qingyue Wang, Wen-Jun Wang, Siqi Huo, Miguel A. Bañares, Marisol Martin-Gonzalez, Maria Ibáñez, Andreu Cabot, Min Hong, Yu Liu, Khak Ho Lim.  (2025)  Thiol–Amine Complexes for the Synthesis and Surface Engineering of SnTe Nanomaterials toward High Thermoelectric Performance.  ACS Nano,      [PMID:40974325] [10.1021/acsnano.5c12627]

84. Na Su, Hongxiang Ou, Shucheng Liu, Fang Zhu, Honglai Xue, Xuan Zhang.  (2025)  Covalent organic frameworks-based microspheres with precisely designed recognition sites for selective adsorption of luteolin.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2025.135370]

85. Xing Tang, Yadong Jiang, Zaihua Duan, Yichen Bu, Wenxin Zeng, Jingwen Yang, Zhen Yuan, Huiling Tai.  (2025)  Surface ligand engineering of Ag2Te colloidal quantum dots for selfpowered shortwave infrared photodetector.  Journal of Materials Chemistry C,      [PMID:] [10.1039/D5TC02959G]

86. Zhuoyao Wu, Weiwei Zeng, Weitao Yang, Jinyan Yi, Dinghua Liu, Yan Xu, Chang Liu, Kexin Bian, Hui Wang, Bingbo Zhang.  (2025)  FAP-catalyzed in situ self-assembly of magnetic resonance imaging probe for early and precise staging of liver fibrosis.  Science Advances,  11  (11):   [PMID:40073128] [10.1126/sciadv.adt6082]

87. Yifan Chen, Qi Wei, Shuixian Yang, Tao Zhang, Hongfei Chen, Zhihao Fu, Chao Lu, Zhengyong Liu, Yanxiong Wu, Jingshun Pan, Mingjie Li, Zhaohui Li.  (2025)  Tin-Lead-Selenide Nanocrystals for Sensitive Uncooled Mid-Infrared Focal Plane Array Imager with Monolithic Readout Integration.  ADVANCED MATERIALS,      [PMID:40576523] [10.1002/adma.202504225]

88. Mengxuan Yu, Runze Huang, Xingchen Zhang, Xudong Hu, Xi Ran, Hang Xia, Mohan Yuan, Jianbing Zhang, Liang Gao, Jiang Tang, Xinzheng Lan.  (2025)  Gold Doping of HgTe Colloidal Quantum Dots for High-Performance Infrared Photodetectors.  ADVANCED FUNCTIONAL MATERIALS,      [PMID:] [10.1002/adfm.202423299]

89. Han Zhou, Qin Chen, Yang You, Yunqi Li, Yaozhu Tian, Haibo Xie.  (2025)  Degradable Eugenol-Derived Poly(thioether carbonate)/Bamboo Powder Thermoset Composite Prepared via Thiol–Ene Click Polymerization.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.5c00477]

90. Yaohui Du, Chuanmei Tang, Bowen Li, Lei Yue, Rongxin Su, Wei Qi, Xianbao Cui, Yuefei Wang.  (2025)  Role of Peptide Molecular Conformation in Improving the Gene Delivery Efficiency of Liposomal Formulations.  LANGMUIR,      [PMID:40397808] [10.1021/acs.langmuir.5c00351]

91. Yichuan Wang, Chengjie Deng, Jing Liu, Long Chen, Sen Li, Peiyan Zhang, Tianhao Cui, Yongshun Wang, Boxiang Song, Xing Zhou, Ying Zhou, Jianbing Zhang, Liang Gao, Jiang Tang.  (2025)  Interface Engineering Enables High-performance PbS Colloidal Quantum Dots Imager via Tungsten Oxide Hydrophilic Layer.  Laser & Photonics Reviews,      [PMID:] [10.1002/lpor.202500345]

92. Shengqiang Zhou, Tianliang Lu, Lipeng Zhou, Xiaomei Yang.  (2025)  Confined Gold Nanoparticles in Sn-Beta Zeolite via Molecule Linkage Strategy: An Efficient and Stable Catalyst for Conversion of Glycerol to Methyl Lactate.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.5c01890]

93. Fan Fang, Yihong Tang, Haodong Tang, Yihan Song, Qian Chen, Lei Rao, Shuang Xiao, Wei Chen, Leifeng Cao.  (2025)  Interface-Enhanced PbS Quantum Dot Short-Wave Infrared Photodetector toward Instant Smoke Detection Applications.  ACS Applied Electronic Materials,      [PMID:] [10.1021/acsaelm.5c01168]

94. Yu Wang, Xin Cong, Gang Ma, Chunhui Xiang, Jiannan Ren, Xiao Liu, Guibin Wang, Shuling Zhang, Jiashuang Luan.  (2025)  A PEEK Composite Paper Maintaining High Electromagnetic Shielding Properties Under a Wide Temperature Region and Cyclic Near Infrared High Power Laser Irradiation.  JOURNAL OF APPLIED POLYMER SCIENCE,      [PMID:] [10.1002/app.70143]

95. Zhisheng Li, Chaoqi Hao, Chuantong Cheng, Zhaowei Zhu, Mengjie Zhang, Yuehua Li, Liting Huang, Bao Zhang, Xu Zhang.  (2025)  MPA-Mediated Control of HgTe Quantum Dot Dispersion in an HgI₂-Based System.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2025.185914]

96. Qian Chen, Haibo Zhu, Fan Fang, Haodong Tang, Yihan Song, Youming Chen, Lei Rao, Andong Zhong, Yihong Tang, Yi Li, Peizhao Liu, Jiaji Cheng, Junjie Hao, Yiwen Li, Wei Chen.  (2025)  Trioctylphosphine-Induced Surface Engineering of PbS Quantum Dots for High-Detectivity Short-Wave Infrared Photodiodes.  Advanced Optical Materials,      [PMID:] [10.1002/adom.202502078]

97. Qian Zhang, Libin Tang, Menghan Jia, Liqing Yang, Kar Seng Teng, Yanfei Lü.  (2026)  Ultra-low dark current self-powered 0.36–1.7 μm broadband photodetector with tungsten oxide as interface modification layer.  OPTICAL MATERIALS,      [PMID:] [10.1016/j.optmat.2026.117880]

98. Tianyu Luo, Sisi Liu, Aoshen Wei, Junlin Wang, He Li, Yong Xia, Xiaoyan Wen, Haifei Lu, Ming-Yu Li.  (2026)  Dual ligands-assisted oxidation strategy for suppressing dark current in PbS quantum dot infrared photodetectors.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2026.186232]

99. Yuan Yang, Wang Jingjing, Zhang Kai.  (2026)  Fluorine-Free Waterproof and Breathable Nanofibrous Membranes with Thermal-Insulation and Anti-icing Performances.  FIBERS AND POLYMERS,      [PMID:] [10.1007/s12221-026-01318-7]

100. Yihan Song, Youming Chen, Yiwen Li, Qian Chen, Andong Zhong, Haibo Zhu, Yihong Tang, Fan FANG, Junjie Hao, Haodong Tang, Jiaji Cheng, Yong Xia, Lin Song, Wei Chen.  (2026)  Ligand-Directed Growth Control for High-Performance Short-Wave Infrared Quantum Dot Photodetectors.  Journal of Materials Chemistry C,      [PMID:] [10.1039/D5TC03823E]

101. Jun-Liang Li, Ke-Lei Zu, Chang-Sheng Shi, Bin Xu, Jian Xu, Yin-Fen Ma, Ji-Xiong Zhao, You-Mei Wang, Hai-Liang Long, Qi Zhan, Feng Qiu, Mei Leng, Yong-biao Zhao, Zheng-Hong Lu.  (2026)  Photomultiplication Enables Efficient NIR Quantum Dot Organic Upconversion Devices.  ACS Photonics,      [PMID:] [10.1021/acsphotonics.5c02809]

102. Congkai Guo, Yao Liu, Xiaoyu Yao, Wenjuan Xia, Shaoyang Xu, Lianjun Xiao, Guohua Wu, Yaohong Zhang.  (2026)  Colloidal WOx Quantum Dot Films with Tunable Electrochromic Performance via Surface Ligand Engineering: Implications for Flexible Electrochromic Devices.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.5c05791]

103. Noor Zaman, Yiqun Li, Tongjun Zheng, Jing Zhou, Abdul Basit, Haider Ali Tauqeer, Biniyam Zemene Taye, Muhammad Salman Yousaf, Shizi Luo, Zheng Liang, Xiaoli Chen, Lavrenty G. Gutsev, Ritabrata Sarkar, Andrey S. Vasenko, Gennady L. Gutsev, Xueqing Xu.  (2026)  Solvent-mediated surface modification of electron transport layers for efficient PbS quantum dot solar cells.  Journal of Materials Chemistry A,      [PMID:] [10.1039/D6TA00196C]

104. Huaying Zhong, Fan Fang, Jasper Guido Ebel, Qian Chen, Lixin Li, Kaiyu Luo, Yihan Song, Andong Zhong, Haibo Zhu, Xiao Wang, Kaijie Ling, Yong Xia, Haodong Tang, Wei Chen, Peter Müller-Buschbaum.  (2026)  Decoupling the Impact of Deep-Trap and Band-Tail States on PbS Quantum Dot Photodetectors via Alkylamine Engineering.  Advanced Materials Technologies,      [PMID:] [10.1002/admt.70952]

105. Hang Xia, Luyao Lv, Xi Ran, Mohan Yuan, Xinzheng Lan.  (2026)  Ultralow Dark Current and Broadband PbS Colloidal Quantum Dot Photodetectors.  ACS Photonics,      [PMID:] [10.1021/acsphotonics.6c00366]

106. Aoshen Wei, Sisi Liu, Tianyu Luo, Kangcan Si, He Li, Junlin Wang, Yong Xia, Xiaoyan Wen, Haifei Lu, Ming-Yu Li.  (2026)  High-performance narrowed-bandgap PbS quantum dot infrared solar cell by advanced bilayer hole transport layer.  Materials Today Chemistry,      [PMID:] [10.1016/j.mtchem.2026.103624]

107. Xue Zheng, Yuanzhi Wang, Wenjie Ming, Guohua Zhong, Qianqian Wu, Yan Shao, Chuanlai Ren, Haoran Wang, Jie Zhang, Yang Bai, Wenjun Hou, Ming Chen, Jian-Xin Tang, Chunlei Yang.  (2026)  Operational Stability Enhancement of Pure-Blue Perovskite Light-Emitting Diode With AgCuGaS2 Quantum Dot Solids as Hole Transport Layer.  ADVANCED FUNCTIONAL MATERIALS,      [PMID:] [10.1002/adfm.74757]