Palladium acetate - AR, Pd 46.0 - 48.0 % , CAS No.3375-31-3

CAS: 3375-31-3 Cat. No.: P100486 Summenformel: C₄H₆O₄Pd Molekulargewicht: 224.51 Beilstein Registry Number: 6086766 EG-Nummer: 222-164-4

GRADE & PURITY AR, Pd 46.0 - 48.0 %

Synonyms

Palladium (II) acetate | SR-01000389719 | EU-0040175 | BCP05504 | Palladium(II) acetate | palladium-(II) acetate | UNII-0LTG3460Y5 | Bis(acetato)palladium | Acetic Acid Palladium(II) Salt | AMY1789 | AC-677 | Diacetatopalladium | Acetic acid palladium sal

Storage

Room temperature,Desiccated

Shipped In

Normal

Übersicht

Product class
M-O, Homogeneous Catalysts, Acetate Ligands

Reaction type
Cross Coupling Reactions with Arenes, CH-Activation, Carbonylation, Mizoroki Heck Coupling Reaction, Sonogashira-Hagihara Coupling Reaction, Suzuki-Miyaura Coupling Reaction, Oxidation

Chemical properties

Chemical formula

C12H18O12Pd3

Empirical formula

[Pd(OAc)2]3

Molecular weight

673.53

Metal

Pd

Theoretical metal content

47

Physical state

powder

Color

red brown

Applications & references

Synthesis of 2-(4-{2-[(2R)-2-Cyclopentyl-5-(5,7-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-2-ylmethyl)-4-hydroxy-6-oxo-3,6-dihydro-2H-pyran-2-yl]-ethyl}-2-fluoro-phenyl)-2-methyl-propionitrile on multikilogram scale using a merging Heck coupling reaction. Compound is an inhibitor of the hepatitis C viral polymerase (HCVP) enzyme.

Reference: Org. Proc. Res. Dev. 2006, 10, 814. (DOI: 10.1021/op0600761)

Reductive carbonylation of aryl halides as an alternative and mild route for the introduction of aldehyde functionality, which is mostly desired for fine chemical and pharmaceutical intermediates to open up the wide range of further possible transformations.

Reference: Org. Proc. Res. Dev. 2007, 11, 39. (DOI: 10.1021/op060193w)

Synthesis of the pyrazolopyridinone-based p38 mitogen-activated protein kinase inhibitor including a Suzuki coupling reaction. p38 MAP kinases are intercellular serine/threonine kinases which certainly regulate the production and action of several pro-inflammatory mediators. They are also involved in disease states such as rheumatoid arthritis, Crohn’s diseases and psoriasis.

Reference: Org. Proc. Res. Dev. 2011, 15, 31. (DOI: 10.1021/op100205s)

Efficient hydroformylation of aryl triflates.

Reference: Synthesis 1996, 470 (DOI: 10.1055/s-1996-4246)

Deacetylation-Diazotation-Heck-Sequence: Carbon-Carbon bond formation with acetanilides as formal leaving groups

Reference: Adv. Synth. Catal. 2013, 355, 463 (DOI: 10.1002/adsc.201200929)

Deacetylation-Diazotation-Suzuki-Sequence: Carbon-Carbon bond formation with acetanilides as formal leaving groups.

Reference: Adv. Synth. Catal. 2013, 355, 463 (DOI: 10.1002/adsc.201200929)

Deacetylation-Diazotation-[2+2+1]-Cycloaddition:

Reference: Adv. Synth. Catal. 2013, 355, 463 (DOI: 10.1002/adsc.201200929)

Specifications

Synonyme

Palladium (II) acetate | SR-01000389719 | EU-0040175 | BCP05504 | Palladium(II) acetate | palladium-(II) acetate | UNII-0LTG3460Y5 | Bis(acetato)palladium | Acetic Acid Palladium(II) Salt | AMY1789 | AC-677 | Diacetatopalladium | Acetic acid palladium sal

Spezifikationen & Reinheit

AR, Pd 46.0 - 48.0 %

Rechtliche Informationen

Product of Umicore

Storage

Room temperature,Desiccated

Verschickt in

Normal

Note

AR

Namen und Kennungen

Pubchem Sid

508816758

Pubchem Sid Url

https://pubchem.ncbi.nlm.nih.gov/substance/508816758

Kanonisches Lächeln

CC(=O)[O-].CC(=O)[O-].[Pd+2]

IUPAC Name

palladium(2+);diacetate

InChIKey

YJVFFLUZDVXJQI-UHFFFAOYSA-L

INCHI

1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

Isomere SMILES

CC(=O)[O-].CC(=O)[O-].[Pd+2]

WGK Deutschland

3

RTECS

AJ1900000

UN-Nummer

3077

Verpackungsgruppe

III

Molekulargewicht

224.51

Beilstein

6086766

Reaxy-Rn

3602276

Reaxys-RN_link_address

https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=3602276&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic acids and derivatives
    • Klasse Carboxylic acids and derivatives
      • Subclass Carboxylic acids

• Kingdom: Organic compounds
• Superclass: Organic acids and derivatives
• Klasse: Carboxylic acids and derivatives
• Subclass: Carboxylic acids
• Intermediate Tree Nodes: Not available
• Direct Parent: Carboxylic acids
• Alternative Parents: Monocarboxylic acids and derivatives Organic salts Organic oxides Hydrocarbon derivatives Carbonyl compounds
• Molecular Framework: Not available
• Substituents: Monocarboxylic acid or derivatives - Carboxylic acid - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organic salt - Organooxygen compound - Carbonyl group - Aliphatic acyclic compound
• Beschreibung: This compound belongs to the class of organic compounds known as carboxylic acids. These are compounds containing a carboxylic acid group with the formula -C(=O)OH.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemische und physikalische Eigenschaften

• Löslichkeit: Soluble in Acetone
• Schmelzpunkt (°C): 216.3-223.7°C
• Molekulargewicht: 224.510 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 223.93 Da
• Monoisotopic Mass: 223.93 Da
• Topological Polar Surface Area: 80.300 Ų
• Heavy Atom Count: 9
• Formal Charge: 0
• Complexity: 25.500
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 3

XLogP3