Tetrakis(triphenylphosphine)palladium(0) - ≥99.9% metals basis , CAS No.14221-01-3

CAS: 14221-01-3 Cat. No.: T294371 Molecular Weight: 1155.56 Beilstein Registry Number: 6704828 EC Number: 238-086-9 PubChem CID: 11979704

GRADE & PURITY ≥99.9% metals basis

Synonyms

Pd(PPh3)4 | Palladium-tetrakis(triphenylphosphine) | Tetra(triphenylphosphine)palladium | BCP03713 | NFHFRUOZVGFOOS-UHFFFAOYSA-N | tetrakis (triphenylphosphine) palladium(0) | tetrakis (triphenylphosphine)-palladium(0) | Vinorelbin | BP-21267 | EX-A6854 |

Storage

Store at -20°C,Argon charged

Shipped In

Ice chest + Ice pads

Overview

A high-yielding catalyst used in coupling reactions.

Product class

M-P, Homogeneous Catalysts, Monodentate Ligands, Phosphorus Ligands - Achiral

Reaction type

Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Carbonylation, Hiyama Coupling Reaction, Mizoroki Heck Coupling Reaction, Negishi Coupling Reaction, Sonogashira-Hagihara Coupling Reaction, Stille Reaction, Suzuki-Miyaura Coupling Reaction, Cyclization, Isomerization, Oxidation, Reduction

Chemical properties

Chemical formula

C72H60P4Pd

Empirical formula

[Pd(PPh3)4]

Molecular weight

1155.58

Metal

Pd

Theoretical metal content

9

Physical state

crystalline

Color

yellow

Metal purity

99.9%

Applications & references

Suzuki coupling reaction as key synthesis step in the preparation of the chiral, nonracemic 3-aryl piperidine (OSU 6162), a potential central nervous system agent.

Reference: Org. Proc. Res. Dev. 2003, 7, 385. (DOI: 10.1021/op025620u)

Aryl-aryl Negishi coupling reaction in the preparation of 5-[2-Methoxy-5-(4-pyridinyl)phenyl]-2,1,3-benzoxadiazole (PDE472), a selective inhibitor of the phosphodiesterase PDE4D isoenzyme, which is well known as drug target for the treatment of asthma.

Reference: Org. Proc. Res. Dev. 2003, 7, 436. (DOI: 10.1021/op025615q)

Palladium catalyzed synthesis of trans-1,2-diazetidines by cyclization of 2,3-allenyl hydrazines with aryl halides.

Reference: Angew. Chem. Int. Ed. 2008, 47, 4581. (DOI: 10.1021/anie.200800364)

Palladium catalyzed cross coupling reaction of α-diazocarbonyl compounds with arylboronic acids providing access to α-aryl substituted α,β-unsaturated carbonyl compounds.

Reference: J. Am. Chem. Soc. 2008, 130, 1566. (DOI: 10.1021/ja0782293)

Palladium catalyzed intermolecular decarboxylative coupling in the presence of reactive C-H groups.

Reference: J. Org. Chem. 2010, 75, 1550. (DOI: 10.1021/jo9022793)

Specifications

Synonyms

Pd(PPh3)4 | Palladium-tetrakis(triphenylphosphine) | Tetra(triphenylphosphine)palladium | BCP03713 | NFHFRUOZVGFOOS-UHFFFAOYSA-N | tetrakis (triphenylphosphine) palladium(0) | tetrakis (triphenylphosphine)-palladium(0) | Vinorelbin | BP-21267 | EX-A6854 |

Specifications & Purity

≥99.9% metals basis

Storage

Store at -20°C, Argon charged

Shipped In

Ice chest + Ice pads

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥99.9% metals basis

Names and Identifiers

• Pubchem Sid: 488197826
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488197826
• Canonical Smiles: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Pd]
• IUPAC Name: palladium;triphenylphosphane
• InChIKey: NFHFRUOZVGFOOS-UHFFFAOYSA-N
• INCHI: 1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H
• Isomeric SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Pd]
• WGK Germany: 3
• PubChem CID: 11979704
• Molecular Weight: 1155.56
• Beilstein: 6704828
• Reaxy-Rn: 6704828

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Class Benzene and substituted derivatives
      • Subclass Phenylphosphines and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Class: Benzene and substituted derivatives
• Subclass: Phenylphosphines and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Phenylphosphines and derivatives
• Alternative Parents: Organic phosphines and derivatives Organic transition metal salts Hydrocarbon derivatives
• Molecular Framework: Not available
• Substituents: Triphenylphosphine - Phenylphosphine - Phosphine - Organic transition metal salt - Hydrocarbon derivative - Organophosphorus compound - Aromatic homomonocyclic compound
• Description: This compound belongs to the class of organic compounds known as phenylphosphines and derivatives. These are compounds containing a phenylphosphine, which consists of phosphine substituent bound to a phenyl group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Soluble in 1% Toluene.
• Sensitivity: Heat, Light, Air, Moisture Sensitive.
• Melt Point(°C): 103-107°C
• Molecular Weight: 1155.600 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 12
• Exact Mass: 1154.27 Da
• Monoisotopic Mass: 1154.27 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 77
• Formal Charge: 0
• Complexity: 202.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 5

XLogP3

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58. Yuehong Pang, Nianci Yang, Xiaofang Shen, Yi Zhang, Liheng Feng.  (2019)  Conjugated polymer self-assembled with graphene: Synthesis and electrochemical 1-hydroxypyrene sensor.  POLYMER,      [PMID:] [10.1016/j.polymer.2019.122139]

59. Fei Fu, Dan Wang, Minggui Shen, Shibin Shang, Zhanqian Song, Jie Song.  (2019)  Preparation of planar and hydrophobic benzocyclobutene-based dielectric material from biorenewable rosin.  JOURNAL OF APPLIED POLYMER SCIENCE,  137  (26): (48831).  [PMID:] [10.1002/app.48831]

60. Liang Qiu, Haoran Zhang, Bo Wang, Yong Zhan, Chengfen Xing, Cai-Yuan Pan.  (2019)  CO2-Responsive Nano-Objects with Assembly-Related Aggregation-Induced Emission and Tunable Morphologies.  ACS Applied Materials & Interfaces,      [PMID:31815411] [10.1021/acsami.9b18792]

61. Mengru Li, Fangkai Du, Pei Xue, Xuecai Tan, Shaogang Liu, Yan Zhou, Jian Chen, Lijuan Bai.  (2019)  An AIE fluorescent probe with a naphthalimide derivative and its application for detection of hypochlorite and imaging inside living cells.  SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,      [PMID:31707024] [10.1016/j.saa.2019.117760]

62. Yang Yuan, Pei Yin, Tao Wang, Zengming Yang, Weidong Yin, Shaoxiong Zhang, Chunxuan Qi, Ma Hengchang.  (2019)  Synthesis of triphenylamine (TPA) dimers and applications in cell imaging.  DYES AND PIGMENTS,      [PMID:] [10.1016/j.dyepig.2019.108009]

63. Yan Zhang, Hongmei Du, Yiming Yin, Yunyun Dong, Jinsheng Zhao, Zhen Xu.  (2019)  Synthesis and characterization of soluble donor-acceptor type copolymers based on benzotriazole, quinoxaline and benzene units with multicolor electrochromism.  ORGANIC ELECTRONICS,      [PMID:] [10.1016/j.orgel.2019.105514]

64. Fei Fu, Dan Wang, Minggui Shen, Shibin Shang, Zhanqian Song, Jie Song.  (2019)  Biorenewable rosin derived benzocyclobutene resin: a thermosetting material with good hydrophobicity and low dielectric constant.  RSC Advances,  9  (51): (29788-29795).  [PMID:35531539] [10.1039/C9RA04828F]

65. Lamaocao Ma, Hengchang Ma.  (2019)  Synthesis of π-conjugated network polymers based on triphenylamine (TPA) and tetraphenylethylene (TPE) as building blocks via direct Pd-catalyzed reactions and their application in CO2 capture and explosive detection.  RSC Advances,  9  (32): (18098-18105).  [PMID:35515247] [10.1039/C9RA02469G]

66. Da Xu, Yanwei Gao, Yang Sun, Zhaoyang Wang, Zhenhua Jiang, Xiangyu Jiang, Haibo Zhang.  (2019)  A Novel Graphene Nanoplatelets (GNPs) Dispersant: Polyaryletherketones with Pendent Pyrene Groups.  MACROMOLECULAR CHEMISTRY AND PHYSICS,  220  (9): (1800553).  [PMID:] [10.1002/macp.201800553]

67. Limei Han, Wenjia Duan, Xinwei Li, Cong Wang, Ziyi Jin, Yuting Zhai, Chong Cao, Luo Chen, Wenjing Xu, Ying Liu, Yong-Yan Bi, Jianfeng Feng, Ying Mao, Qi Yue, Xiao-Yong Zhang, Cong Li.  (2019)  Surface-Enhanced Resonance Raman Scattering-Guided Brain Tumor Surgery Showing Prognostic Benefit in Rat Models.  ACS Applied Materials & Interfaces,      [PMID:30896915] [10.1021/acsami.9b00227]

68. Linfeng Chen, Xike Tian, Yong Li, Chao Yang, Liqiang Lu, Zhaoxin Zhou, Yulun Nie.  (2019)  An AIE dye based smartphone and LDA integrated portable, intelligent and rapid detection system as trace water indicator and cyanide detector.  DYES AND PIGMENTS,      [PMID:] [10.1016/j.dyepig.2019.03.008]

69. Miao Luo, Sheng Wang, Chengpeng Li, Wangen Miao, Xiang Ma.  (2019)  Aggregation-induced emission organogel formed by both sonication and thermal processing based on tetraphenylethylene and cholesterol derivative.  DYES AND PIGMENTS,      [PMID:] [10.1016/j.dyepig.2019.02.041]

70. Yuan Yang, Tao Wang, Pei Yin, Weidong Yin, Shaoxiong Zhang, Ziqiang Lei, Manyi Yang, Yucheng Ma, Wei Duan, Hengchang Ma.  (2019)  A general concept for white light emission formation from two complementary colored luminescent dyes.  Materials Chemistry Frontiers,  3  (3): (505-512).  [PMID:] [10.1039/C8QM00599K]

71. Tianhao Wang, Meiying Liu, Dazhuang Xu, Junyu Chen, Qing Wan, Yuanqing Wen, Hongye Huang, Fengjie Deng, Xiaoyong Zhang, Yen Wei.  (2018)  Facile fabrication of cross-linked fluorescent organic nanoparticles with aggregation-induced emission characteristic via the thiol-ene click reaction and their potential for biological imaging.  Materials Science & Engineering C-Materials for Biological Applications,      [PMID:30813030] [10.1016/j.msec.2018.12.123]

72. Hengchang Ma, Manyi Yang, Shaoxiong Zhang, Pei Yin, Tao Wang, Yuan Yang, Ziqiang Lei, Yucheng Ma, Yanfang Qin, Zengming Yang.  (2018)  Two aggregation-induced emission (AIE)-active reaction-type probes: for real-time detecting and imaging of superoxide anions.  ANALYST,  144  (2): (536-542).  [PMID:30406221] [10.1039/C8AN01811A]

73. Hengchang Ma, Yucheng Ma, Lei Lei, Weidong Yin, Yuan Yang, Tao Wang, Pei Yin, Ziqiang Lei, Manyi Yang, Yanfang Qin, Shaoxiong Zhang.  (2018)  Light-Enhanced Bacterial Killing and Less Toxic Cell Imaging: Multicationic Aggregation-Induced Emission Matters.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.8b03540]

74. Zhongmin Geng, Qianqian Song, Xiaoming Zhang, Bing Yu, Youqing Shen, Hailin Cong.  (2018)  Mixed matrix membranes composed of WS2 nanosheets and fluorinated poly(2,6-dimethyl-1,4-phenylene oxide) via Suzuki reaction for improved CO2 separation.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2018.08.021]

75. Jianzhong Xu, Qi Ji, Lingqian Kong, Hongmei Du, Xiuping Ju, Jinsheng Zhao.  (2018)  Soluble Electrochromic Polymers Incorporating Benzoselenadiazole and Electron Donor Units (Carbazole or Fluorene): Synthesis and Electronic-Optical Properties.  Polymers,  10  (4): (450).  [PMID:30966485] [10.3390/polym10040450]

76. Rong-Rong Zhang, Qing Yin, Hai-Peng Liang, Qi Chen, Wei-Hua Luo, Bao-Hang Han.  (2018)  Hypercrosslinked porous polycarbazoles from carbazolyl-bearing aldehydes or ketones.  POLYMER,      [PMID:] [10.1016/j.polymer.2018.03.062]

77. Yingfan Zhang, Bo Gui, Rufan Chen, Guiping Hu, Yi Meng, Daqiang Yuan, Matthias Zeller, Cheng Wang.  (2018)  Engineering a Zirconium MOF through Tandem “Click” Reactions: A General Strategy for Quantitative Loading of Bifunctional Groups on the Pore Surface.  INORGANIC CHEMISTRY,      [PMID:29400460] [10.1021/acs.inorgchem.7b03123]

78. Lei Lei, Hengchang Ma, Yanfang Qin, Manyi Yang, Yucheng Ma, Tao Wang, Yuan Yang, Ziqiang Lei, Dedai Lu, Xiaolin Guan.  (2017)  AIE-active florescent polymers: The design, synthesis and the cell imaging application.  POLYMER,      [PMID:] [10.1016/j.polymer.2017.11.030]

79. Hengchang Ma, Manyi Yang, Caili Zhang, Yucheng Ma, Yanfang Qin, Ziqiang Lei, Lu Chang, Lei Lei, Tao Wang, Yuan Yang.  (2017)  Aggregation-induced emission (AIE)-active fluorescent probes with multiple binding sites toward ATP sensing and live cell imaging.  Journal of Materials Chemistry B,  5  (43): (8525-8531).  [PMID:32264520] [10.1039/C7TB02399E]

80. Jiatao Wu, Chunyan Tan, Xinwen Zhou, Ying Tan, Pengyuan Yang, Yuyang Jiang.  (2017)  Molecular weight analysis of water-soluble poly(phenylene ethynylene)s using MALDI-TOF MS.  JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,  55  (15): (2537-2543).  [PMID:] [10.1002/pola.28650]

81. Yongquan Wu, Guanjie Zeng, Nannan Lvyue, Weihua Wu, Tianyu Jiang, Rongle Wu, Wei Guo, Xun Li, Xiaolin Fan.  (2017)  Triethylene glycol-modified iridium(III) complexes for fluorescence imaging of Schistosoma japonicum.  Journal of Materials Chemistry B,  5  (25): (4973-4980).  [PMID:32264013] [10.1039/C7TB00662D]

82. Junjie He, Song Li, Heping Zeng.  (2017)  The Photostability of Two Optical Materials Based on Perylene Diimide Substituted by Different Aromatic Groups at the Bay Area.  JOURNAL OF HETEROCYCLIC CHEMISTRY,  54  (5): (2800-2807).  [PMID:] [10.1002/jhet.2883]

83. Xue Li, Chengpeng Li, Sheng Wang, Huan Dong, Xiang Ma, Derong Cao.  (2017)  Synthesis and properties of photochromic spirooxazine with aggregation-induced emission fluorophores polymeric nanoparticles.  DYES AND PIGMENTS,      [PMID:] [10.1016/j.dyepig.2017.03.068]

84. Qin Jingjing, Chen Lang, Zhao Chenghui, Lin Qixiang, Chen Shaowei.  (2017)  Cellulose nanofiber/cationic conjugated polymer hybrid aerogel sensor for nitroaromatic vapors detection.  JOURNAL OF MATERIALS SCIENCE,  52  (14): (8455-8464).  [PMID:] [10.1007/s10853-017-1065-y]

85. Weiliang Guo, Zhiyuan Cao, Yanhuan Liu, Bin Su.  (2017)  Electrochemiluminescence of a Vinyl-Functionalized Ruthenium Complex and Its Monolayer Formed through the Photoinduced Thiol-Ene Click Reaction.  ChemElectroChem,  4  (7): (1763-1767).  [PMID:] [10.1002/celc.201600905]

86. Tong-Mou Geng, Deng-Kun Li, Zong-Ming Zhu, Ye-Bin Guan, Yu Wang.  (2016)  The synthesis and fluorescence detection properties of benzoquinone-based conjugated microporous/mesoporous polymers.  MICROPOROUS AND MESOPOROUS MATERIALS,      [PMID:] [10.1016/j.micromeso.2016.05.022]

87. Qiulan Lv, Ke Wang, Dazhuang Xu, Meiying Liu, Qing Wan, Hongye Huang, Shangdong Liang, Xiaoyong Zhang, Yen Wei.  (2016)  Facile preparation and biological imaging of luminescent polymeric nanoprobes with aggregation-induced emission characteristics through Michael addition reaction.  COLLOIDS AND SURFACES B-BIOINTERFACES,      [PMID:27311129] [10.1016/j.colsurfb.2016.05.028]

88. Miao Luo, Sheng Wang, Meiling Wang, Shaorong Huang, Chengpeng Li, Lin Chen, Xiang Ma.  (2016)  Novel organogel harnessing Excited-State Intramolecular Proton Transfer process with aggregation induced emission and photochromism.  DYES AND PIGMENTS,      [PMID:] [10.1016/j.dyepig.2016.04.036]

89. Ran Chen, Zhongwei An, Feng Li, Xinbing Chen, Pei Chen.  (2016)  Synthesis and physical properties of tolane liquid crystals containing 2,3-difluorophenylene and terminated by a tetrahydropyran moiety.  LIQUID CRYSTALS,      [PMID:] [10.1080/02678292.2015.1125959]

90. Meiying Liu, Hongye Huang, Ke Wang, Dazhuang Xu, Qing Wan, Jianwen Tian, Qiang Huang, Fengjie Deng, Xiaoyong Zhang, Yen Wei.  (2016)  Fabrication and biological imaging application of AIE-active luminescent starch based nanoprobes.  CARBOHYDRATE POLYMERS,      [PMID:26917371] [10.1016/j.carbpol.2016.01.030]

91. Xiang Han, Lei Zhao, Dong-En Wang, Juan Xu, Longlong Zhang, Mao-Sen Yuan, Qin Tu, Jinyi Wang.  (2015)  A TBET-based ratiometric probe for Au3+ and its application in living cells.  ANALYST,  141  (3): (1098-1104).  [PMID:26662283] [10.1039/C5AN01932J]

92. Kun Hu, Pei Chen, Qiang Weng, Dingqian Shi, Ran Chen, Xinbing Chen, Zhongwei An.  (2015)  Preparation and properties of lateral monofluoro-substituted benzoxazole-based mesogenic compounds.  LIQUID CRYSTALS,      [PMID:] [10.1080/02678292.2015.1069412]

93. Qiulan Lv, Ke Wang, Dazhuang Xu, Meiying Liu, Qing Wan, Hongye Huang, Shangdong Liang, Xiaoyong Zhang, Yen Wei.  (2015)  Synthesis of Amphiphilic Hyperbranched AIE-active Fluorescent Organic Nanoparticles and Their Application in Biological Application.  MACROMOLECULAR BIOSCIENCE,  16  (2): (223-230).  [PMID:26376342] [10.1002/mabi.201500256]

94. Ran Chen, Yi Jiang, Jian Li, Zhongwei An, Xinbing Chen, Pei Chen.  (2015)  Dielectric and optical anisotropy enhanced by 1,3-dioxolane terminal substitution on tolane-liquid crystals.  Journal of Materials Chemistry C,  3  (33): (8706-8711).  [PMID:] [10.1039/C5TC01712B]

95. Xiaoman Bi, Weiwei Zuo, Yingliang Liu, Zhenru Zhang, Cen Zeng, Shengang Xu, Shaokui Cao.  (2015)  Organic solution-processible electroluminescent molecular glasses for non-doped standard red OLEDs with electrically stable chromaticity.  MATERIALS RESEARCH BULLETIN,      [PMID:] [10.1016/j.materresbull.2015.06.026]

96. Lu Tianxing, You Jing, Zhao Dan, Wang Hua, Miao Yanqin, Liu Xicheng, Xiao Yin, Li Xianggao, Wang Shirong.  (2015)  Synthesis of novel s-triazine/carbazole based bipolar molecules and their application in phosphorescent OLEDs.  JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,  26  (9): (6563-6571).  [PMID:] [10.1007/s10854-015-3254-2]

97. Yi Wu, Ying Tan, Jiatao Wu, Shangying Chen, Yu Zong Chen, Xinwen Zhou, Yuyang Jiang, Chunyan Tan.  (2015)  Fluorescence Array-Based Sensing of Metal Ions Using Conjugated Polyelectrolytes.  ACS Applied Materials & Interfaces,      [PMID:25741754] [10.1021/acsami.5b00587]

98. Shengbo Zhu, Zhongwei An, Xinbing Chen, Pei Chen, Qianfeng Liu.  (2015)  Cyclic thiourea functionalized dyes with binary π-linkers: Influence of different π-conjugation segments on the performance of dye-sensitized solar cells.  DYES AND PIGMENTS,      [PMID:] [10.1016/j.dyepig.2015.01.022]

99. Li Wenfeng, Ma Hengchang, Lu con, Ma Yuan, Qi Chunxuan, Zhang Zhonwei, Yang Zengming, Cao Haiying, Lei ziqiang.  (2014)  A self-assembled triphenylamine-based fluorescent chemosensor for selective detection of Fe3+ and Cu2+ ions in aqueous solution.  RSC Advances,  5  (9): (6869-6878).  [PMID:] [10.1039/C4RA12025F]

100. Danling Yang, Rongfeng Zou, Yu Zhu, Ben Liu, Defan Yao, Juanjuan Jiang, Junchen Wu, He Tian.  (2014)  Magainin II modified polydiacetylene micelles for cancer therapy.  Nanoscale,  6  (24): (14772-14783).  [PMID:25355048] [10.1039/C4NR04405C]

101. Bo Gui, Guiping Hu, Tailin Zhou, Cheng Wang.  (2014)  Pore surface engineering in a zirconium metal–organic framework via thiol-ene reaction.  JOURNAL OF SOLID STATE CHEMISTRY,      [PMID:] [10.1016/j.jssc.2014.06.023]

102. Ling Fan, Ruili Cui, Xiuping Guo, Dong Qian, Beibei Qiu, Jun Yuan, Yongfang Li, Wenlong Huang, Junliang Yang, Weifang Liu, Xinjun Xu, Lidong Li, Yingping Zou.  (2014)  A new two-dimensional donor/acceptor copolymer based on 4,8-bis(2′-ethylhexylthiophene)thieno[2,3-f]benzofuran for high-performance polymer solar cells.  Journal of Materials Chemistry C,  2  (28): (5651-5659).  [PMID:] [10.1039/C4TC00738G]

103. Yong Xie, Rui-Xia Yang, Nian-Yu Huang, Hua-Jun Luo, Wei-Qiao Deng.  (2014)  Efficient fixation of CO2 at mild conditions by a Cr-conjugated microporous polymer.  Journal of Energy Chemistry,      [PMID:] [10.1016/S2095-4956(14)60113-3]

104. Xu-Feng Zang, Yang-Fan Xu, Zafar Iqbal, Zu-Sheng Huang, Dai-Bin Kuang, Lingyun Wang, Herbert Meier, Ying Li, Derong Cao.  (2013)  Synthesis and photovoltaic performance of dihydrodibenzoazepine-based sensitizers with additional lateral anchor.  DYES AND PIGMENTS,      [PMID:] [10.1016/j.dyepig.2013.08.023]

105. Jian-Jian Wang, Yin-Ning Zhou, Ping Wang, Zheng-Hong Luo.  (2013)  The synthesis and enhancement of the surface properties of polyfluorene-based photoelectric materials by introducing fluoromonomers.  RSC Advances,  3  (15): (5045-5055).  [PMID:] [10.1039/C3RA22682D]

106. Wanjun Tang, Xuewen Chen, Yingping Zou, Bo Liu, Hong Zhong, Chunyue Pan.  (2012)  5,6-bis(tetradecyloxy)-2,1,3-benzoselenadiazole-based polymers for photovoltaic applications.  JOURNAL OF APPLIED POLYMER SCIENCE,  128  (6): (3678-3686).  [PMID:] [10.1002/app.38586]

107. Wu Zhengjun, Zhao Taotao, Jiang Xingyue, Zhang Dan, Wang Feiyi, Ren Xiaoming, Wang Zhao, Wang Erfei, Ren Jun.  (2024)  A near-infrared fluorescent probe with a large Stokes shift for the detection and imaging of biothiols in vitro and in vivo.  ANALYTICAL AND BIOANALYTICAL CHEMISTRY,      [PMID:39322801] [10.1007/s00216-024-05537-w]

108. Zejian He, Jun Wu, Zhen He, Jia Chen, Weipin Fang, Yifan Zhang, Xinyi Shen, Yangjing Ren, Yulong Chen, Jianguo He, Donghai Yan, Pin Chen, Mi Zhou.  (2025)  A Paper-Based Sensor for the Detection of Gastroesophageal Reflux Disease Utilizing a Cleavable Fluorescent Polymer.  Advanced Healthcare Materials,      [PMID:39823160] [10.1002/adhm.202402919]

109. Ziyi Wang, Yuqin Wei, Zhaoli Xue, Lei Feng, Aijian Wang, Yan Sun, Chunsheng Li, Xinping Qiu, Long Zhao.  (2024)  Asymmetric cobalt porphyrins for pH-universal oxygen reduction reactions: Benzoic acid advances phenyl as substituents.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2024.07.057]

110. Yanjun Chen, Zhaoqi Zhu, Min Li, Jia Zhang, Xiaoyin Cao, Ruijuan Fu, Guoyu Xing, Hanxue Sun, Jiyan Li, An Li.  (2024)  Conjugated Microporous Polymer Aerogels Encapsulated within Hydroxyapatite Nanowires Exhibit Good Thermal Insulation and Flame-Retardant Properties.  LANGMUIR,      [PMID:38920388] [10.1021/acs.langmuir.4c00388]

111. Meijuan Ding, Mei Li, Yijun Wang, Ziyu Li.  (2025)  Construction of graphdiyne-layered bimetallic hydroxide-derived oxide composite photocatalyst for hydrogen evolution.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2025.03.333]

112. Heming Li, Xinming Wang, Ziyang Ding, Weiguo Gao, Yan Liu, Ke Ma, Zhizhi Hu, Yongqi Wang.  (2024)  Crown Ether Copolymerized Polyimide Film: Enhanced Mechanical, Thermal Properties and Low Dielectric Constant under High Frequency.  Polymers,  16  (9): (1188).  [PMID:38732657] [10.3390/polym16091188]

113. Ziyu Li, Mei Li, Rongsheng Xu, Zhiliang Jin.  (2025)  Efficient photocatalytic hydrogen production by employing a graphdiyne/NH2-MIL-88B(Fe) composite.  PHYSICAL CHEMISTRY CHEMICAL PHYSICS,  27  (8): (4278-4289).  [PMID:39918343] [10.1039/D4CP04468A]

114. Zichun Liu, Zhuang Hu, Wei Hu, Tao Ji, Zilin Chen.  (2024)  Etched stainless steel wire modified with conjugated microporous polymers-F6 for jacket-free stir bar sorptive extraction of benzoylureas in juice sample.  ANALYST,  149  (13): (3673-3680).  [PMID:38819227] [10.1039/D4AN00551A]

115. Dandan Wang, Xiaofei Yan, Xinsheng Zhu, Ying Liu, Laihong Zhang, Yaqiu Lu, Jie Li, Dingming Xue.  (2024)  Facilitating Charge Separation of Donor–Acceptor Conjugated Microporous Polymers via Position Isomerism Strategy for Efficient CO2 Photoconversion.  Catalysts,  14  (10): (659).  [PMID:] [10.3390/catal14100659]

116. Xiaojing Lv, Chunyan Liu, Mingfa Shao, Jin Li, Minao Xia, Jiankun Cui, Juncheng Dong, Mi Ouyang, Cheng Zhang.  (2024)  Full color control and patterned display device from cyan/magenta/yellow water-dispersed electrochromic polymer nanoparticles systems.  NANOTECHNOLOGY,  35  (36): (365201).  [PMID:38710176] [10.1088/1361-6528/ad47cd]

117. Heming Li, Panpeng Wei, Yongqi Wang, Qiushi Zhu, Xinming Wang, Weiguo Gao, Lin Tao, Ke Ma, Zhizhi Hu, Wei Chen.  (2024)  High-frequency 5G substrate: Low dielectric biphenyl polyimide with low CTE and high thermal stability.  Materials Today Advances,      [PMID:] [10.1016/j.mtadv.2024.100514]

118. Xiaoli Fan, Xin Song, Jingxue Sun, Yangpeng Zhang, Zhonghua Li.  (2024)  Hydrophilic/hydrophobic heterojunctions for enhanced photocatalytic hydrogen evolution via gas release dynamics.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:39700562] [10.1016/j.jcis.2024.12.095]

119. Rui Ding, Xue-qi Zhang, Jie Liu.  (2024)  Improved solar-driven cathodic protection performance of polymer semiconductor photoelectrodes based on one-dimensional and two-dimensional side chain engineering.  JOURNAL OF MOLECULAR STRUCTURE,      [PMID:] [10.1016/j.molstruc.2024.141205]

120. Zhendong Ma, Jianshuo Zheng, Chenyue Wang, Pengli Lei, Qiu Zhuang, Weijin Li, Aming Xie.  (2024)  Magnetic Resonance Modulation in Ferrocene-alkyne Conjugated Polymer for Electromagnetic Wave Absorption.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.4c00971]

121. Ke Ma, Jianxia Dong, Dingyuan Yan, Deliang Wang, Yuanwei Wang, Jianxing Wang, Dong Wang, Hui Tan, Ben Zhong Tang.  (2024)  Molecular Engineering of AIE-Active Photosensitizers with High Biosafety for Effect Extracellular Antibacteria.  Small,      [PMID:39676412] [10.1002/smll.202403937]

122. Zengfang Huang, Chaoyue Zhou, Xiaotong Zhang, Haoyu Xue, Wenxi Liao, Liucheng Mao, Jinying Yuan, Lei Tao, Yen Wei.  (2024)  Polymerizable aggregation-induced emission enhancement (AEE) dyes with D-A-D’ structure basing on phenothiazine and tetraphenylethylene for fluorescent particles and their application in cell imaging.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2024.113643]

123. Gang Xiang, Wensi Xu, Wenfeng Zhuge, Zhengfa Zhang, Cuizhong Zhang, Jinyun Peng, Fuyan Li.  (2024)  Porphyrin-based conjugated microporous polymer-grafted graphene electrochemical sensor for vanillin detection.  JOURNAL OF THE CHINESE CHEMICAL SOCIETY,      [PMID:] [10.1002/jccs.202400171]

124. Yixuan Xu, Changchang Teng, Yating Wang, Dejia Chen, Dalong Yin, Lifeng Yan.  (2024)  Self-enhanced regulation of stable organic radicals with polypeptide nanoparticles for mild second near-infrared phototheranostics.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:38729006] [10.1016/j.jcis.2024.05.032]

125. Binhua Mei, Ju Bai, Yuhang Zhang, Yang Ma, Yanjun Hou, Shuhong Wang, Cheng Wang.  (2024)  Synthesis of thienopyrazine- and cyclofluorene–thiophene-based donor–acceptor low-band gap polymers and their application in memory devices.  JOURNAL OF APPLIED POLYMER SCIENCE,      [PMID:] [10.1002/app.55998]

126. Zhiyuan Zeng, Tianqun Zhao, Yi Gong, Zhiqiang Yu.  (2024)  Synthesis, curing kinetics and properties of novel aromatic multifunctional epoxy resin.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2024.113375]

127. Ran Chen, Junyu Zou, Zihao Mao, Zhongwei An, Pei Chen, Xinbing Chen.  (2024)  Terminal groups enhance the birefringence and dielectric anisotropy of fluorinated terphenyl liquid crystals for AR displays.  JOURNAL OF MOLECULAR LIQUIDS,      [PMID:] [10.1016/j.molliq.2024.124162]

128. Jianing Li, Dongkui Zhang, Jiangbin Xia.  (2024)  The controllable synthesis of multi-color carbon quantum dots modified by polythiophene and their application in fluorescence detection of Au3+ and Hg2+.  SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,      [PMID:39024785] [10.1016/j.saa.2024.124794]

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130. Meijuan Ding, Mei Li, Jingzhi Wang, Zhiliang Jin.  (2024)  Visible-Light-Induced Photocatalytic Hydrogen Evolution Performance of Graphdiyne-Alkyne Phosphating Mo–Metal-Organic Frameworks Heterojunction.  Solar RRL,      [PMID:] [10.1002/solr.202400041]

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153. Jiawei Lv, Cheng Zeng, Richao Shen, Shuangyu Dong, Yong Li, Sanbao Wang, Hongting Fan, Haowen Huang, Ziqiang Lei, Hengchang Ma, Zhiwang Yang.  (2025)  Compiling Modules of Photosensitizers and Quaternary Phosphonium Blocks into Materials’ Networks by co- Polymerization Strategy: An Effective Way to Fabricate Antimicrobial Agents to Against Drug Resistance.  Journal of Materials Chemistry B,      [PMID:40539568] [10.1039/D5TB00083A]

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156. Huan Huang, Zhiyuan Meng, Yangmei Wu, Lingfeng Sun, Ting Li, Zhonglong Wang, Yiqin Yang.  (2025)  A novel fluorescent sensor with dual response to H2S/biothiols from flavonol derivative-grafted ethyl cellulose and its applications.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:41297811] [10.1016/j.ijbiomac.2025.149254]

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160. Guangsen Tian, Shouzheng Li, Shaojia Song, Hongxi Zhao, Linfeng Zhang, Huadong Wu, Ye Luo, Jianding Li, Jia Guo, Qun Yi.  (2025)  Donor–acceptor engineering in conjugated polymer photocatalysts: thieno[3, 2-b]thiophene-dibenzothiophene sulfone copolymers for noble-metal-free visible-light hydrogen evolution.  Journal of Materials Chemistry A,      [PMID:] [10.1039/D5TA05975E]

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162. Yinuo Dong, Xu Zhang, Haoguo Yue, Libo Wang, Jinsheng Zhao, Fei Zhao, Zhengrong Wei, Junhong Zhang.  (2026)  Triindole-based donor-π-acceptor conjugated polymers for efficient photocatalytic hydrogen evolution: enhancing charge transport and light absorption.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:41548473] [10.1016/j.jcis.2026.139896]

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164. Gao Yuxuan, Kong Qiyu, Wang Jun, Sun Fengwei, Liu Xinyu, Wang Deliang, Li Jiangao, Yang Zhen.  (2026)  Well-tailored Photosensitizers with Boosted Type-I ROS Generation by Fluorination Strategy for Precise Near-infrared Fluorescence-guided Photodynamic Therapy.  CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,      [PMID:] [10.1007/s40242-026-5314-y]

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