RuCl[(R,R)-Fsdpen](p-cymene) - ≥90% , CAS No.1026995-71-0

CAS: 1026995-71-0 Cat. No.: C137946 Molecular Weight: 712.14 EC Number: 806-978-2 PubChem CID: 71463829

GRADE & PURITY ≥90%

Synonyms

Chloro(p-cymene)[(R,R)-N-(pentafluorobenzenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II) | R0123 | 1026995-71-0 | Ruthenium, [N-[(1R,2R)-2-(amino-kappaN)-1,2-diphenylethyl]-2,3,4,5,6-pentafluorobenzenesulfonamidato-kappaN]chloro[(1,2,3,4,5,6-eta)-1

Storage

Room temperature

Shipped In

Normal

Overview

Ligands and Complexes for Asymmetric Reactions

Specifications

Synonyms

Chloro(p-cymene)[(R, R)-N-(pentafluorobenzenesulfonyl)-1, 2-diphenylethylenediamine]ruthenium(II) | R0123 | 1026995-71-0 | Ruthenium, [N-[(1R, 2R)-2-(amino-kappaN)-1, 2-diphenylethyl]-2, 3, 4, 5, 6-pentafluorobenzenesulfonamidato-kappaN]chloro[(1, 2, 3, 4, 5, 6-eta)-1

Specifications & Purity

≥90%

Storage

Room temperature

Shipped In

Normal

Purity

≥90%

Names and Identifiers

• Pubchem Sid: 488202248
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488202248
• Canonical Smiles: CC1=CC=C(C=C1)C(C)C.C1=CC=C(C=C1)C(C(C2=CC=CC=C2)[N-]S(=O)(=O)C3=C(C(=C(C(=C3F)F)F)F)F)N.[Cl-].[Ru+2]
• IUPAC Name: [(1R,2R)-2-amino-1,2-diphenylethyl]-(2,3,4,5,6-pentafluorophenyl)sulfonylazanide;1-methyl-4-propan-2-ylbenzene;ruthenium(2+);chloride
• InChIKey: UWFMZLATRGEOIW-ZJPTYAPPSA-M
• INCHI: 1S/C20H14F5N2O2S.C10H14.ClH.Ru/c21-13-14(22)16(24)20(17(25)15(13)23)30(28,29)27-19(12-9-5-2-6-10-12)18(26)11-7-3-1-4-8-11;1-8(2)10-6-4-9(3)5-7-10;;/h1-10,18-19H,26H2;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t18-,19-;;;/m1.../s1
• Isomeric SMILES: CC1=CC=C(C=C1)C(C)C.C1=CC=C(C=C1)[C@H]([C@@H](C2=CC=CC=C2)[N-]S(=O)(=O)C3=C(C(=C(C(=C3F)F)F)F)F)N.[Cl-].[Ru+2]
• WGK Germany: 2
• PubChem CID: 71463829
• Molecular Weight: 712.14

Chemical and Physical Properties

• Sensitivity: air sensitive
• Specific Rotation[α]: [α]25/D ?16°, c = 0.1 in chloroform
• Flash Point(°F): >212 °F
• Flash Point(°C): >100 °C
• Melt Point(°C): 238-244°C

References

1. Jin-Bo Li, Cheng-Ye Zhu, Bian-Bian Guo, Chang Liu, Jia-Hui Xin, Chao Zhang, Jian Wu, Lin Zhang, Hao-Cheng Yang, Zhi-Kang Xu.  (2023)  Ultrahigh-permeance polyamide thin-film composite membranes enabled by interfacial polymerization on a macro-porous substrate toward organic solvent nanofiltration.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2023.122342]