Silver Bis(trifluoromethanesulfonyl)imide - ≥98% , CAS No.189114-61-2

CAS: 189114-61-2 Cat. No.: S124682 Molecular Weight: 388.01 EC Number: 689-634-2 PubChem CID: 15975413

GRADE & PURITY ≥98%

Synonyms

MFCD28054494 | SCHEMBL4197236 | Silver(I) Bis(trifluoromethylsulfonyl)amide | silver,bis(trifluoromethylsulfonyl)azanide | S0898 | FT-0696270 | silver;bis(trifluoromethylsulfonyl)azanide | Silver triflimide | Silver bis(trifluoromethanesulfonyl)imide | SY

Storage

Protected from light,Store at -20°C,Argon charged

Shipped In

Ice chest + Ice pads

Overview

Silver bis(trifluoromethanesulfonyl)imide is a silver-based salt that is widely used as a catalyst in organic synthesis. It is used in the C3 regioselective alkylation of indole derivatives via conjugated addition type reactions with α, β-enones. It is also used as a p-type dopant for efficient and stable solid-state dye-sensitized and perovskite solar cells.

Specifications

Synonyms

MFCD28054494 | SCHEMBL4197236 | Silver(I) Bis(trifluoromethylsulfonyl)amide | silver, bis(trifluoromethylsulfonyl)azanide | S0898 | FT-0696270 | silver;bis(trifluoromethylsulfonyl)azanide | Silver triflimide | Silver bis(trifluoromethanesulfonyl)imide | SY

Specifications & Purity

≥98%

Storage

Protected from light, Store at -20°C, Argon charged

Shipped In

Ice chest + Ice pads

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥98%

Names and Identifiers

• Canonical Smiles: C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.[Ag+]
• IUPAC Name: silver;bis(trifluoromethylsulfonyl)azanide
• InChIKey: HSYLTRBDKXZSGS-UHFFFAOYSA-N
• INCHI: 1S/C2F6NO4S2.Ag/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1
• Isomeric SMILES: C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.[Ag+]
• WGK Germany: 3
• PubChem CID: 15975413
• Molecular Weight: 388.01
• Reaxy-Rn: 8734918

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic acids and derivatives
    • Class Organic sulfonic acids and derivatives
      • Subclass Organosulfonic acids and derivatives

• Kingdom: Organic compounds
• Superclass: Organic acids and derivatives
• Class: Organic sulfonic acids and derivatives
• Subclass: Organosulfonic acids and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Organosulfonic acids and derivatives
• Alternative Parents: Sulfonyls Trihalomethanes Organic metal halides Organofluorides Organic silver salts Organic oxides Organic nitrogen compounds Hydrocarbon derivatives Alkyl fluorides Organic cations
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Organosulfonic acid or derivatives - Sulfonyl - Trihalomethane - Organic metal halide - Organic transition metal salt - Alkyl fluoride - Alkyl halide - Halomethane - Hydrocarbon derivative - Organic silver salt - Organic oxide - Organic salt - Organic oxygen compound - Organic nitrogen compound - Organosulfur compound - Organofluoride - Organohalogen compound - Organic cation - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as organosulfonic acids and derivatives. These are compounds containing a sulfonic acid or derivative, with the general structure RS(=O)2X (R=alkyl, aryl; X=any heteroatom).
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Soluble in water
• Sensitivity: Moisture & Light & Heat Sensitive
• Melt Point(°C): 249°C
• Molecular Weight: 388.020 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 2
• Exact Mass: 386.822 Da
• Monoisotopic Mass: 386.822 Da
• Topological Polar Surface Area: 86.000 Ų
• Heavy Atom Count: 16
• Formal Charge: 0
• Complexity: 374.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

References

1. Bobo Cao, Weilu Ding, Linmeng Huo, Yumiao Lu, Yanlei Wang, Hongyan He.  (2025)  Robust Conductive Adhesives: A Strategy Using Metal-Doped Poly(ionic liquid)s.  ACS Applied Materials & Interfaces,      [PMID:40745697] [10.1021/acsami.5c11335]

2. Lixi Wang, Haitao Liu, Fan Fang, Jiangyong Pan, Zhenghao Gao, Xingyu Liu, Yuyang Wei, Yujie Qin, Xiuwei Huo, Jia Lu, Chengjun Liu, Lei Mao, Jianhua Chang, Jing Chen, Yuning Zhang, Baoping Wang, Dewei Zhao.  (2025)  High-Efficiency Cadmium-Free Blue Quantum Dot Light-Emitting Diodes Enabled by Engineering of a Hole Transporting Interface with a Multifunctional Molecule.  ACS Photonics,      [PMID:] [10.1021/acsphotonics.4c02140]