C-H Activation Catalysts | Aladdin Scientific

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Diethyl dithio carbamic acid silver salt
CAS: 1470-61-7 EC Number: 216-003-7 Formula: C₅H₁₀AgNS₂ Molecular Weight: 256.14

Solid ≥98%

In Stock Item #: D113191

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Technical Identifiers

IUPAC Name

silver;N,N-diethylcarbamodithioate

SMILES

CCN(CC)C(=S)[S-].[Ag+]

InChIKey
NSVHDIYWJVLAGH-UHFFFAOYSA-M

InChI

1S/C5H11NS2.Ag/c1-3-6(4-2)5(7)8;/h3-4H2,1-2H3,(H,7,8);/q;+1/p-1

Synonyms
AgDDTC | EINECS 253-895-7 | Silver, (diethyldithiocarbamato)- | silver;N,N-diethylcarbamodithioate | Silver, (diethyl...
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Bis(triphenylphosphine)palladium(II) diacetate
CAS: 14588-08-0 EC Number: 238-628-4 PubChem CID: 10865532 Formula: C₄₀H₃₆O₄P₂Pd Molecular Weight: 749.08

Solid Pd 14.2%

In Stock Item #: B101047

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Technical Identifiers

IUPAC Name

acetic acid;palladium;triphenylphosphane

SMILES

CC(=O)O.CC(=O)O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Pd]

InChIKey
VKYBQFWSQQZDLX-UHFFFAOYSA-N

InChI

1S/2C18H15P.2C2H4O2.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2(3)4;/h2*1-15H;2*1H3,(H,3,4);

Synonyms
MFCD00010013 | Bis(triphenylphosphine)palladium(II) diacetate, 98% | acetic acid;palladium;triphenylphosphane | Diace...
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Tri(2-furyl)phosphine
CAS: 5518-52-5 EC Number: 628-036-8 PubChem CID: 521585 Formula: C₁₂H₉O₃P Molecular Weight: 232.17

Solid ≥99%

In Stock Item #: T113607

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IUPAC Name

tris(furan-2-yl)phosphane

SMILES

C1=COC(=C1)P(C2=CC=CO2)C3=CC=CO3

InChIKey
DLQYXUGCCKQSRJ-UHFFFAOYSA-N

InChI

1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H

Synonyms
tris(furan-2-yl)phosphane | EN300-207605 | PR-1-0083 | trifuranyl phosphine | J-525041 | (E)-2-(2-(2-(2-(4-TRIFLOUROM...
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Nickel chloride Analytical Titrant
CAS: 7718-54-9 EC Number: 231-743-0 Formula: NiCl₂ Molecular Weight: 129.60

Liquid analysis of titration solution ? 0.5M

In Stock Item #: N128397

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IUPAC Name

dichloronickel

SMILES

Cl[Ni]Cl

InChIKey
QMMRZOWCJAIUJA-UHFFFAOYSA-L

InChI

1S/2ClH.Ni/h2*1H;/q;;+2/p-2

Synonyms
dichloronickel (II) | Nickel(II) chloride, anhydrous | Nickelous chloride | NSC254532 | NSC-254532 | NiCl2 | nickel (...
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8-Dimethylamino-1-octanol
CAS: 29823-87-8 EC Number: 680-019-4 Formula: C₁₀H₂₃NO Molecular Weight: 173.3

≥93%(GC)

Out of Stock Item #: D154362

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IUPAC Name

8-(dimethylamino)octan-1-ol

SMILES

CN(C)CCCCCCCCO

InChIKey
CAKJEDBOIMYCHP-UHFFFAOYSA-N

InChI

1S/C10H23NO/c1-11(2)9-7-5-3-4-6-8-10-12/h12H,3-10H2,1-2H3

Synonyms
CAKJEDBOIMYCHP-UHFFFAOYSA-N | DTXSID40431132 | SCHEMBL756049 | 8-(dimethylamino)octan-1-ol | SB83903 | MFCD03701100 |...
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Nickel(II) Benzenesulfonate Hexahydrate
CAS: 39819-65-3 Formula: C₁₂H₁₀NiO₆S₂·6H₂O Molecular Weight: 481.11

≥98%(T)

In Stock Item #: N159676

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Technical Identifiers

IUPAC Name

benzenesulfonate;nickel(2+)

SMILES

C1=CC=C(C=C1)S(=O)(=O)[O-].C1=CC=C(C=C1)S(=O)(=O)[O-].[Ni+2]

InChIKey
IBVWKDVFDAWRFU-UHFFFAOYSA-L

InChI

1S/2C6H6O3S.Ni/c2*7-10(8,9)6-4-2-1-3-5-6;/h2*1-5H,(H,7,8,9);/q;;+2/p-2

Synonyms
Benzenesulfonic Acid Nickel(II) Salt | benzenesulfonate;nickel(2+) | Nickel(II) Benzenesulfonate | FT-0739671 | Benze...
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[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
CAS: 14647-23-5 Formula: C₂₆H₂₄Cl₂NiP₂ Molecular Weight: 528.02

≥98%

In Stock Item #: D101082

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IUPAC Name

2-diphenylphosphanylethyl(diphenyl)phosphane;nickel(2+);dichloride

SMILES

C1=CC=C(C=C1)P(CCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.[Cl-].[Cl-].[Ni+2]

InChIKey
XXECWTBMGGXMKP-UHFFFAOYSA-L

InChI

1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

Synonyms
AMY19685 | B2225 | [1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride | nickel(2+) ion [2-(diphenylphosphanyl)et...
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Chloro[[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](N,N-dimethylbenzylamine)palladium(II)] (This product is unavailable in the U.S.)
CAS: 930796-10-4 PubChem CID: 76030762 Formula: C₃₆H₄₈ClN₃Pd Molecular Weight: 664.67

≥97%(T)

Out of Stock Item #: C154029

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Technical Identifiers

IUPAC Name

[1,3-bis[2,6-di(propan-2-yl)phenyl]imidazol-2-ylidene]palladium;N,N-dimethyl-1-phenylmethanamine;chloride

SMILES

CC(C)C1=C(C(=CC=C1)C(C)C)N2C=CN(C2=[Pd])C3=C(C=CC=C3C(C)C)C(C)C.CN(C)CC1=CC=CC=[C-]1.[Cl-]

InChIKey
BGNMDPTYDVUDBP-UHFFFAOYSA-M

InChI

1S/C27H36N2.C9H12N.ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-10(2)8-9-6-4-3-5-7-9;;/h9-16,18-21show more

Synonyms
[1,3-bis[2,6-di(propan-2-yl)phenyl]imidazol-2-ylidene]palladium;N,N-dimethyl-1-phenylmethanamine;chloride | DTXSID706...
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Bis(triphenylphosphine)palladium dichloride
CAS: 13965-03-2 EC Number: 237-744-2 PubChem CID: 6102075 Formula: C₃₆H₃₀Cl₂P₂Pd Molecular Weight: 701.9

Pd 15.2%

In Stock Item #: D109544

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Technical Identifiers

IUPAC Name

dichloropalladium;triphenylphosphane

SMILES

C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Pd]Cl

InChIKey
YNHIGQDRGKUECZ-UHFFFAOYSA-L

InChI

1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

Synonyms
Umicore CX73 | Bis(triphenylphosphine)palladium(II) dichloride, ChemDose(TM) tablets, Loading: 1mumol per tablet | PD...
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Chloro[(1,3-dimesitylimidazol-2-ylidene)(N,N-dimethylbenzylamine)palladium(II)]
CAS: 1058661-78-1 PubChem CID: 76030758 Formula: C₃₀H₃₆ClN₃Pd Molecular Weight: 580.51

≥98%(T)

In Stock Item #: C153831

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Technical Identifiers

IUPAC Name

[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]palladium;N,N-dimethyl-1-phenylmethanamine;chloride

SMILES

CC1=CC(=C(C(=C1)C)N2C=CN(C2=[Pd])C3=C(C=C(C=C3C)C)C)C.CN(C)CC1=CC=CC=[C-]1.[Cl-]

InChIKey
DGPOQJVFBKBRDT-UHFFFAOYSA-M

InChI

1S/C21H24N2.C9H12N.ClH.Pd/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-10(2)8-9-6-4-3-5-7-9;;/h7-12H,1-6H3;3-6H,8H2,1-2H3;1show more

Synonyms
1058661-78-1 | DTXSID10693684 | PUBCHEM_53384340 | MFCD11975428 | [1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]p...
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Chlorobis(ethylene)iridium(I) Dimer
CAS: 39722-81-1 PubChem CID: 91972112 Formula: C₈H₁₆Cl₂Ir₂ Molecular Weight: 567.55

≥95%(T)

Out of Stock Item #: C153350

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Technical Identifiers

IUPAC Name

ethene;iridium;dichloride

SMILES

C=C.C=C.C=C.C=C.[Cl-].[Cl-].[Ir].[Ir]

InChIKey
KIGDBTYHWLDKQG-UHFFFAOYSA-L

InChI

1S/4C2H4.2ClH.2Ir/c4*1-2;;;;/h4*1-2H2;2*1H;;/p-2

Synonyms
MFCD28976162 | D89533 | Dichlorotetra(ethylene)diiridium(I) | C3041 | ethene;iridium;dichloride | Chlorobis(ethylene)...
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Tris(2,6-dimethoxyphenyl)phosphine
CAS: 85417-41-0 PubChem CID: 2734597 Formula: C₂₄H₂₇O₆P Molecular Weight: 442.45

≥97%(HPLC)

In Stock Item #: T161546

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Technical Identifiers

IUPAC Name

tris(2,6-dimethoxyphenyl)phosphane

SMILES

COC1=C(C(=CC=C1)OC)P(C2=C(C=CC=C2OC)OC)C3=C(C=CC=C3OC)OC

InChIKey
CMLWFCUAXGSMBB-UHFFFAOYSA-N

InChI

1S/C24H27O6P/c1-25-16-10-7-11-17(26-2)22(16)31(23-18(27-3)12-8-13-19(23)28-4)24-20(29-5)14-9-15-21(24)30-6/h7-15H,1-6H3

Synonyms
CMLWFCUAXGSMBB-UHFFFAOYSA- | AKOS015851709 | A841325 | Phosphine, tris(2,6-dimethoxyphenyl)- | AS-61743 | SCHEMBL1480...

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Frequently Asked Questions

How do I choose the right C-H Activation Catalysts for my reaction?

Match catalyst structure to your substrate scope, desired selectivity, and reaction conditions. C-H Activation Catalysts differ in metal center, ligand framework, and electronic properties. Run small-scale screening with 2-3 candidates before committing to scale-up.

What specifications matter most when comparing C-H Activation Catalysts?

Focus on purity (typically ≥95%), particle size or solubility for heterogeneous systems, moisture and air sensitivity, catalyst loading recommendations, and turnover number from published data. Check storage conditions carefully.

How should C-H Activation Catalysts be handled and stored?

Most c-h activation catalysts require inert atmosphere storage (argon or nitrogen). Some are air- and moisture-sensitive — use a glovebox or Schlenk line for measurement. Refrigerated storage at 2-8°C extends shelf life for many products.

Are pre-formed metal complexes available?

Yes. Many c-h activation catalysts are stocked as pre-formed, ready-to-use complexes that eliminate the need for in-situ ligation. This improves reproducibility and reduces handling of sensitive precursors.

C–H activation catalysts help chemists access direct functionalization strategies that can shorten routes and reduce prefunctionalization steps. Researchers often compare metal system, directing-group requirements, site selectivity, substrate scope, ligand environment, and operational practicality when evaluating catalyst options. This category is useful for route development teams exploring late-stage diversification or streamlined bond construction. It complements broader transition-metal and cross-coupling catalyst pages when multiple activation strategies are under consideration.