Zirconocene dichloride - ≥98% , CAS No.1291-32-3

CAS: 1291-32-3 Cat. No.: B124559 Molecular Weight: 292.31 EC Number: 215-066-8 PubChem CID: 22833502
AVAILABLE TO ORDER
GRADE & PURITY ≥98%
Synonyms
Bis(cyclopentadienyl)zirconium Dichloride
Storage
Room temperature,Argon charged
Shipped In
Normal
 ·  off list, applied to all prices below.
Size
Status
Price
Qty
1g
B124559-1g
3
$9.90
5g
B124559-5g
4
$14.90
25g
B124559-25g
7
$49.90
100g
B124559-100g
8
$149.90
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Why this grade

≥98% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Room temperature,Argon charged Ships Normal Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 23 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Overview

Useful in the synthesis of a wide range of early-transition-metal complexes and organometallic compounds. Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

Specifications

Synonyms
Bis(cyclopentadienyl)zirconium Dichloride
Specifications & Purity
≥98%
Storage
Room temperature, Argon charged
Shipped In
Normal
Purity
≥98%
Names and Identifiers
Pubchem Sid504769306
Pubchem Sid Urlhttps://pubchem.ncbi.nlm.nih.gov/substance/504769306
Isomeric SMILES C1C=CC=[C-]1.[CH-]1C=CC=C1.Cl[Zr+2]Cl
WGK Germany 3
RTECS ZH7525000
PubChem CID 22833502
UN Number 3261
Packing Group I
Molecular Weight 292.31

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

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✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

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📊 Datasheet

Quick-reference summary of product specifications and applications.

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🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

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Advanced Data

Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

32 results found

Lot NumberCertificate TypeDateItem
F2610306Certificate of AnalysisMay 30, 2026 B124559
F2608202Certificate of AnalysisMay 30, 2026 B124559
F2608201Certificate of AnalysisMay 30, 2026 B124559
F2608200Certificate of AnalysisMay 30, 2026 B124559
H1830140Certificate of AnalysisApr 15, 2026 B124559
F2209284Certificate of AnalysisMar 11, 2026 B124559
A2620274Certificate of AnalysisDec 27, 2025 B124559
A2620275Certificate of AnalysisDec 27, 2025 B124559
A2620273Certificate of AnalysisDec 27, 2025 B124559
H2520262Certificate of AnalysisJun 14, 2025 B124559
H2520226Certificate of AnalysisJun 14, 2025 B124559
H2520225Certificate of AnalysisJun 14, 2025 B124559
H2520220Certificate of AnalysisJun 14, 2025 B124559
F2401081Certificate of AnalysisFeb 29, 2024 B124559
F2401099Certificate of AnalysisFeb 29, 2024 B124559
F2401112Certificate of AnalysisFeb 29, 2024 B124559
D2401016Certificate of AnalysisFeb 29, 2024 B124559
K2322302Certificate of AnalysisNov 03, 2023 B124559
K2322297Certificate of AnalysisNov 03, 2023 B124559
K2322298Certificate of AnalysisNov 03, 2023 B124559
K2322299Certificate of AnalysisNov 03, 2023 B124559
D1918015Certificate of AnalysisFeb 08, 2023 B124559
J2227178Certificate of AnalysisJul 12, 2022 B124559
H2308255Certificate of AnalysisJul 12, 2022 B124559
J2227177Certificate of AnalysisJul 12, 2022 B124559
J2227174Certificate of AnalysisJul 12, 2022 B124559
J2227173Certificate of AnalysisJul 12, 2022 B124559
H1830139Certificate of AnalysisJul 08, 2022 B124559
F2209253Certificate of AnalysisMar 27, 2022 B124559
F2209166Certificate of AnalysisMar 27, 2022 B124559
F2209264Certificate of AnalysisMar 27, 2022 B124559
D1402050Certificate of AnalysisFeb 18, 2022 B124559

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Chemical and Physical Properties
SolubilityIt is soluble in water.
SensitivityMoisture sensitive;Air sensitive
Boil Point(°C)124-125°/15mm
Melt Point(°C)242-245°C
Documents & Articles
Citations of This Product
References
1. Qian Wang, Xu Li, Jinxiang Dong.  (2023)  Synthesis and surface properties of branched-chain tertiary fatty alcohol sulfate surfactants.  TENSIDE SURFACTANTS DETERGENTS,  60  (6): (569-587).  [PMID:] [10.1515/tsd-2023-2534]
2. Juan Zhu, Shuang-Bao Li, Bao-Xu Jiang, Yu-Teng Zhang.  (2023)  Incorporation of Zr-based metal-organic polyhedron into the PDA/PVDF adsorptive membrane for rapid removal of Cr(VI).  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2023.158331]
3. Jing Gao, Jinghua Hao, Yuan Gao, Xiaolin Sun, Yuan Zhang, Depeng Song, Qing Zhao, Fuhua Zhao, Wenyan Si, Kun Wang, Takeo Ohsaka, Futoshi Matsumoto, Jianfei Wu, Haijiao Xie.  (2023)  Scalable wet-slurry fabrication of sheet-type electrodes for sulfide all-solid-state batteries and performance enhancement via optimization of Ni-rich cathode coating layer.  eTransportation,      [PMID:] [10.1016/j.etran.2023.100252]
4. Yang Lyu, Yuan Cheng, Guangdong Zhao, Mengyu Wang, Guiqing Chen, Xinghong Zhang, Wenbo Han.  (2023)  Modification of SiBCN by Zr atom and its effect on ablative resistance of Cf/SiBCN(Zr) composites.  COMPOSITES PART B-ENGINEERING,      [PMID:] [10.1016/j.compositesb.2023.110511]
5. Xu Li, Jiaqi Li, Xiaohong Wang, Lijun Yang, Hong Xu, Jinxiang Dong.  (2022)  Novel branched-chain sulfonate surfactants based on α-olefins from Fischer–Tropsch synthesis via reaction-separation-utilization integrated process.  FUEL,      [PMID:] [10.1016/j.fuel.2022.126961]
6. Yanghuan Huang, Haocheng Zhang, Lou Gao, Tianlan Yan, Yueer Yan, Yahong Zhang, Yi Tang.  (2022)  Direct grafting synthesis of bi-functional Zr–Al-MWW zeolites and their catalytic characteristics in Lewis-Brønsted cascade reaction.  MICROPOROUS AND MESOPOROUS MATERIALS,      [PMID:] [10.1016/j.micromeso.2022.112110]
7. Fuwen Tan, Xu Li, Jinxiang Dong.  (2022)  Synthesis of alkylbenzenes via the alkylation of benzene using α-olefin dimers and the surfactant properties of their sulfonates.  TENSIDE SURFACTANTS DETERGENTS,  59  (1): (39-50).  [PMID:] [10.1515/tsd-2021-2371]
8. He Huang, Zhao-Yang Liu, Shuang-Bao Li, Juan Zhu, Bao-Xu Jiang, Yu-Teng Zhang.  (2021)  Amino-functionalized Zr (IV) metal-organic polyhedron as water-stable catalyst for the photocatalytic degradation of tetracycline.  JOURNAL OF SOLID STATE CHEMISTRY,      [PMID:] [10.1016/j.jssc.2021.122821]
9. Bin-Cheng Wang, Zhi-Ying Feng, Biao-Biao Hao, Chen-Xi Zhang, Qing-Lun Wang.  (2021)  Promotion of Proton Conductivity by Encapsulation of Metal-Organic Polyhedra in Metal-Organic Frameworks.  CHEMISTRY-A EUROPEAN JOURNAL,  27  (47): (12137-12143).  [PMID:34164856] [10.1002/chem.202101213]
10. Yirong Feng, Jie Wang, Haomiao Zhang, Jingdai Wang, Yongrong Yang.  (2021)  A 3D-printed continuous flow platform for the synthesis of methylaluminoxane.  GREEN CHEMISTRY,  23  (11): (4087-4094).  [PMID:] [10.1039/D1GC01015H]
11. Shujie Liang, Xiaohui Zhong, Zuqi Zhong, Bin Han, Weiyi Chen, Kainan Song, Hong Deng, Zhang Lin.  (2021)  Biomimetic inspired porphyrin-based nanoframes for highly efficient photocatalytic CO2 reduction.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2021.128414]
12. Haochuan Lu, Lining Bao, Qingwen Dong, Xu Li, Jinxiang Dong.  (2024)  Coal-Based Branched Vicinal Diol Ethoxylates Versus Guerbet Alcohol Ethoxylates: Role of Tertiary Hydroxyl Groups.  LANGMUIR,      [PMID:38842621] [10.1021/acs.langmuir.4c00965]
13. Shuangbao Li, Shuaibing Ma, Jian Li, Yongbo Yu, Zechao Wu, Yuteng Zhang, Li Jin, Julun Zong, Jianpo Zhang.  (2024)  Diamine-functionalized zirconium metal-organic cage ZrT-1-(NH2)2: A ratiometric fluorescent probe for the rapid and sensitive detection of malachite green.  JOURNAL OF MOLECULAR STRUCTURE,      [PMID:] [10.1016/j.molstruc.2024.140726]
14. Shujie Liang, Yan Zhang, Jingxian Cong, Jiaxin Lv, Hong Deng.  (2024)  Interfacial engineering on hierarchical ZrO2 nanozyme realizes efficient CO2 photoreduction.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:39566412] [10.1016/j.jcis.2024.11.112]
15. Ting-Ting Xu, De-Sheng Wei, Shuang-Bao Li, Yu-Teng Zhang, Nan Lv.  (2024)  One-step synthesis of pure-phase amino-functionalized zirconium-based capsule ZrC-1-NH2 for photocatalytic degradation of tetracycline.  CRYSTENGCOMM,  26  (38): (5431-5439).  [PMID:] [10.1039/D4CE00721B]
16. De-Sheng Wei, Jian Li, Ting-Ting Xu, Wan-Yi Lan, Nan Lv, Yu-Teng Zhang, Shuang-Bao Li.  (2025)  Sonochemical Synthesis of Zr-based metal-organic cages and their adsorption performance towards Tartrazine.  CRYSTENGCOMM,      [PMID:] [10.1039/D4CE01097C]
17. Jian Li, Shuai-Bing Ma, De-Sheng Wei, Wan-Yi Lan, Ting-Ting Xu, Yu-Teng Zhang, Nan Lv, Shuang-Bao Li.  (2024)  Trifluoromethyl-functionalized zirconium-based metal-organic cage (ZrT-(CF3)2): An efficient adsorbent for salicylic acid removal.  JOURNAL OF SOLID STATE CHEMISTRY,      [PMID:] [10.1016/j.jssc.2024.125098]
18. Wan-Yi Lan, De-Sheng Wei, Wang-Xin Duan, Xiao-Hong Li, Zhong Sun, Yu-Teng Zhang, Nan Lv, Hai-Hui Yu, Shuang-Bao Li.  (2025)  Cooperative integration of Keggin-type polyoxometalate and zirconium-based molecular cage into a crystalline porous ionic salt for efficient photoreduction of hexavalent chromium.  JOURNAL OF MOLECULAR STRUCTURE,      [PMID:] [10.1016/j.molstruc.2025.143227]
19. Yu-Teng Zhang, Jing- Yu Sun, Jian Li, De-Sheng Wei, Wan-Yi Lan, Nan Lv, Shuang-Bao Li.  (2025)  In Situ Assembly of Ti-Zr Bimetallic Organic Cages towards High-Performance Photocatalytic Degradation of Tetracycline Hydrochloride.  JOURNAL OF MOLECULAR STRUCTURE,      [PMID:] [10.1016/j.molstruc.2025.144139]
20. Jing-Yu Sun, De-Sheng Wei, Bao-Xu Jiang, Xiaohong Li, Yu-Teng Zhang, Haihui Yu, Shuaibing Ma, Shuangbao Li.  (2025)  Ferrocene-Functionalized Zirconocene-Oxo Assemblies: {Zr3Fc3} and {Zr12Fc4} Clusters with Excellent Photo-Fenton Catalytic Activities.  INORGANIC CHEMISTRY,      [PMID:40952344] [10.1021/acs.inorgchem.5c02848]
21. Xuejiao Song, Zexiang Bi, Zimeng Wei, Xu Li, Jinxiang Dong.  (2025)  Branched-chain anionic surfactants with same hydrophobic tail architecture: effects of hydrophilic headgroups.  TENSIDE SURFACTANTS DETERGENTS,      [PMID:] [10.1515/tsd-2024-2639]
22. Zhongyao Zhang, Hengyu Zhong, Yanjiao Xu, Mengbo Zhang, Haomiao Zhang, Jingdai Wang, Yongrong Yang.  (2025)  Impacts of Heat Treatment and Long-Term Storage on Methylaluminoxane Composition, Catalytic Activity, and Polyethylene Properties.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.5c01770]
23. Shuangbao Li, Shuaibing Ma, Jingyu Sun, Yuteng Zhang, Zi'an Wang, Lingfeng Sheng, Bo Jiang, Qingxin Liu, Li Jin.  (2026)  Zirconium metal-organic cage integrated with fluorescein sodium: A dye-functionalized dual-emission platform for ratiometric sensing of sunset yellow.  DYES AND PIGMENTS,      [PMID:] [10.1016/j.dyepig.2026.113628]
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