Rhodium chloride - ≥98% , CAS No.10049-07-7

CAS: 10049-07-7 Cat. No.: R132432 Molecular Weight: 209.26 EC Number: 233-165-4 PubChem CID: 386392195

GRADE & PURITY ≥98%

Synonyms

Rhodium trichloride | Rhodium(3+) trichloride | Trichlororhodium

Storage

Room temperature,Argon charged

Shipped In

Normal

Specifications

Synonyms

Rhodium trichloride | Rhodium(3+) trichloride | Trichlororhodium

Specifications & Purity

≥98%

Storage

Room temperature, Argon charged

Shipped In

Normal

Purity

≥98%

Names and Identifiers

• WGK Germany: 3
• RTECS: VI9275000
• PubChem CID: 386392195
• Molecular Weight: 209.26

Chemical and Physical Properties

• Solubility: Insoluble in water. Soluble in hydroxide and cyanide solutions.
• Sensitivity: Hygroscopic

References

1. Jiaxin Zhu, Zekun Liu, Yihua Chen, Zhiqiang Chen, Hang Ma, Jian Sun, Liao Meng, Tongzhou Liu.  (2023)  A detailed investigation of electrochemical hydrodefluorination of 4-fluorophenol: Rh-doped cathode preparation, reaction conditions optimizations, reactive species identification, and in situ characterization.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2023.144009]

2. Xiao-Jian Zhang, Bao-Juan Dou, Yu-Qi Wang, Fei Yang, Xue Cai, Mian Li, Zhi-Qiang Liu, Yu-Guo Zheng.  (2023)  Efficient synthesis of sugar alcohols using a composite trimetallic Pt–Ni–Sn/MWCNTs catalyst based on metal element coordination and valence regulation.  Food Bioscience,      [PMID:] [10.1016/j.fbio.2023.102708]

3. Ying Li, Jian Xue, Rongjun Yu, Siling Chen, Xiangyu Deng, Anyi Chen, Jingfu Qiu.  (2023)  PdPtRu trimetallic nanozymes and application to electrochemical immunosensor for sensitive SARS-COV-2 antigen detection.  TALANTA,      [PMID:37141825] [10.1016/j.talanta.2023.124604]

4. Huizhen Dai, Te Zhang, Kaiyu Dong, Houkang Pu, Yingying Wang, Yujia Deng.  (2023)  Electrochemical Synthesis of Rh Nanorods with High-Index Facets for the Oxidation of Formic Acid.  ENERGY & FUELS,      [PMID:] [10.1021/acs.energyfuels.3c00364]

5. Yanjia Ma, Ming Hou, Li Yang, Jiyun Gao, Guozhu Zhang, Ronghui Guo, Shenghui Guo.  (2023)  Combinatorial Material Strategy: Parallel Synthesis and High-Throughput Screening of WO3 Nanoplates Decorated with Noble Metals for VOCs Sensor.  Chemosensors,  11  (4): (239).  [PMID:] [10.3390/chemosensors11040239]

6. Qingqin Tan, Zhenxing Chen, Lei Liu, Xi Huang.  (2023)  Functionalized Rhodium Nanoparticles as Antimicrobial Agents for Treatment of Drug-Resistant Skin and Soft Tissue Infections.  Advanced Healthcare Materials,  12  (19): (2203200).  [PMID:36944074] [10.1002/adhm.202203200]

7. Wang Yi, Yang Rong, Ding Yajun, Zhang Bo, Li Hao, Bai Bing, Li Mingrun, Cui Yi, Xiao Jianping, Wu Zhong-Shuai.  (2023)  Unraveling oxygen vacancy site mechanism of Rh-doped RuO2 catalyst for long-lasting acidic water oxidation.  Nature Communications,  14  (1): (1-10).  [PMID:36918568] [10.1038/s41467-023-37008-8]

8. Dongxue Tao, Haitao Zhou, Kaihui Cui, Linchen Xie, Kun Huang.  (2023)  Preferential recovery and separation of rhodium in the concentrated hydrochloric acid using thin-layer oil membrane extraction based on laminar flow.  CHEMICAL ENGINEERING RESEARCH & DESIGN,      [PMID:] [10.1016/j.cherd.2023.02.012]

9. Qi Xue, Zixin Ge, Zihan Yuan, Jiangtao Huang, Bin He, Yu Chen.  (2023)  Au core@AuPtRh alloy shell nanowires for ethanol oxidation.  Materials Today Physics,      [PMID:] [10.1016/j.mtphys.2023.100980]

10. Fan Zhenglong, Liao Fan, Ji Yujin, Liu Yang, Huang Hui, Wang Dan, Yin Kui, Yang Haiwei, Ma Mengjie, Zhu Wenxiang, Wang Meng, Kang Zhenhui, Li Youyong, Shao Mingwang, Hu Zhiwei, Shao Qi.  (2022)  Coupling of nanocrystal hexagonal array and two-dimensional metastable substrate boosts H2-production.  Nature Communications,  13  (1): (1-10).  [PMID:36192414] [10.1038/s41467-022-33512-5]

11. Qiqi Mao, Kai Deng, Hongjie Yu, You Xu, Ziqiang Wang, Xiaonian Li, Liang Wang, Hongjing Wang.  (2022)  In Situ Reconstruction of Partially Hydroxylated Porous Rh Metallene for Ethylene Glycol-Assisted Seawater Splitting.  ADVANCED FUNCTIONAL MATERIALS,  32  (31): (2201081).  [PMID:] [10.1002/adfm.202201081]

12. Yunxia Yang, Dan Yu, Xiaoyue Xu, Yisong Zhao, Yuping Mi, Faming Gao.  (2022)  One-dimensional bimetallic PdRh alloy mesoporous nanotubes constructed for ultra-sensitive detection of carbamate pesticide.  ANALYTICAL BIOCHEMISTRY,      [PMID:35588856] [10.1016/j.ab.2022.114726]

13. Junlu Bi, Xuejun Zhai, Guishan Liu, Jing-Qi Chi, Xuanyi Wang, Shaojin Chen, Zhenyu Xiao, Lei Wang.  (2021)  Low loading of P modified Rh nanoparticles encapsulated in N, P-doped carbon for boosted and pH-universal hydrogen evolution reaction.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2021.11.036]

14. Xiaodong Huang, YanEn Wang, Qinshu Zhu, Kejie Zhou, Huizhen Zhi, Jinfei Yang.  (2021)  High quality synthesis of Rh nanocubes and their application in hydrazine hydrate oxidation assisted water splitting.  INORGANIC CHEMISTRY COMMUNICATIONS,      [PMID:] [10.1016/j.inoche.2021.109023]

15. Liang Li, Yongwei Lu, Xiaowei Liu, Xinran Wang, Siyue Zhou.  (2021)  Layered double hydroxide drived ultra-evenly Rh-doped Co2Fe-P composite for high-efficient overall water splitting.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2021.162549]

16. Shufang Chang, Jinxing Yu, Ran Wang, Qingyang Fu, Xiaoxiang Xu.  (2021)  LaTaON2 Mesoporous Single Crystals for Efficient Photocatalytic Water Oxidation and Z-Scheme Overall Water Splitting.  ACS Nano,      [PMID:34677058] [10.1021/acsnano.1c06871]

17. Guoliang Gao, Huangze Yu, Xue Lu Wang, Ye-Feng Yao.  (2021)  Enhanced hydrogen evolution reaction activity of FeM (M = Pt, Pd, Ru, Rh) nanoparticles with N-doped carbon coatings over a wide-pH environment.  Molecular Catalysis,      [PMID:] [10.1016/j.mcat.2021.111830]

18. Zhang Jiapeng, Li Yilin, Yang Lijing, Zhang Fengming, Li Ran, Dong Hua.  (2021)  Ruthenium Nanosheets Decorated Cobalt Foam for Controllable Hydrogen Production from Sodium Borohydride Hydrolysis.  CATALYSIS LETTERS,  152  (5): (1386-1391).  [PMID:] [10.1007/s10562-021-03730-5]

19. Lihua Zhu, Huaze Zhu, Mohsen Shakouri, Linghai Zeng, Zhiqing Yang, Yongfeng Hu, Hengqiang Ye, Hui Wang, Bing Hui Chen, Rafael Luque.  (2021)  Mechanistic insights into interfacial nano-synergistic effects in trimetallic Rh-on-NiCo on-CNTs for room temperature solvent-free hydrogenations.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2021.120404]

20. Xue Jiang, Zemeng Dong, Jing Wang, Ning Zhang, Guang-Rui Xu, Wen Zhang, Jianping Lai, Zhenjiang Li, Lei Wang.  (2021)  Self-assembly of functionalized Echinops-like Rh porous nanostructure electrocatalysts for highly efficient seawater splitting.  Journal of Materials Chemistry C,  9  (26): (8314-8322).  [PMID:] [10.1039/D1TC01722E]

21. Nan Wang, Jianguo Liu, Long Tang, Xiuzhi Wei, Chenguang Wang, Xinjun Li, Longlong Ma.  (2021)  Facile Synthesis of Rh Anchored Uniform Spherical COF for One-Pot Tandem Reductive Amination of Aldehydes to Secondary Imines.  ACS Applied Materials & Interfaces,      [PMID:34008944] [10.1021/acsami.1c05732]

22. Gao Ying, Zhang Jinniu, Leng Deying, Li Gang, Zhang Yuanyi, Wang Wei, Liang Qingfei, Chen Xiaorui, Lu Hongbing, Gao Jianzhi.  (2021)  Electrospun NiO nanofibers with Rh decoration for enhanced acetone sensing performances.  JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,  32  (10): (14102-14112).  [PMID:] [10.1007/s10854-021-05990-8]

23. Xiuju Wu, Rongfei Wang, Wei Li, Bomin Feng, Weihua Hu.  (2021)  Rh2P Nanoparticles Partially Embedded in N/P-Doped Carbon Scaffold at Ultralow Metal Loading for High Current Density Water Electrolysis.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.0c03126]

24. Bin Qiao, Ting Yang, Shufeng Shi, Nan Jia, Yu Chen, Xinbing Chen, Zhongwei An, Pei Chen.  (2021)  Highly Active Hollow RhCu Nanoboxes toward Ethylene Glycol Electrooxidation.  Small,  17  (10): (2006534).  [PMID:33590702] [10.1002/smll.202006534]

25. Xiao-Jian Zhang, Hai-Wei Li, Wang Bin, Bao-Juan Dou, De-Shui Chen, Xin-Ping Cheng, Mian Li, Hong-Yan Wang, Kai-Qian Chen, Li-Qun Jin, Zhi-Qiang Liu, Yu-Guo Zheng.  (2020)  Efficient Synthesis of Sugar Alcohols under Mild Conditions Using a Novel Sugar-Selective Hydrogenation Catalyst Based on Ruthenium Valence Regulation.  JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY,      [PMID:33095018] [10.1021/acs.jafc.0c03873]

26. Jialu Shen, Weifeng Chen, Guo Lv, Zihan Yang, Jiaying Yan, Xiang Liu, Zhongxu Dai.  (2020)  Hydrolysis of NH3BH3 and NaBH4 by graphene quantum dots-transition metal nanoparticles for highly effective hydrogen evolution.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2020.09.153]

27. Zhenbing Xie, Bingfeng Chen, Fangfang Peng, Mingyang Liu, Huizhen Liu, Guanying Yang, Buxing Han.  (2020)  Highly Efficient Synthesis of Amino Acids by Amination of Bio-Derived Hydroxy Acids with Ammonia over Ru Supported on N-Doped Carbon Nanotubes.  ChemSusChem,  13  (21): (5683-5689).  [PMID:32893503] [10.1002/cssc.202001561]

28. Fang Luo, Long Guo, Yuhua Xie, Jingxiang Xu, Weiwei Cai, Konggang Qu, Zehui Yang.  (2020)  Robust hydrogen evolution reaction activity catalyzed by ultrasmall Rh–Rh2P nanoparticles.  Journal of Materials Chemistry A,  8  (25): (12378-12384).  [PMID:] [10.1039/D0TA04773B]

29. Wendan Nie, Yixing Luo, Qifeng Yang, Gang Feng, Qilu Yao, Zhang-Hui Lu.  (2019)  An amine-functionalized mesoporous silica-supported PdIr catalyst: boosting room-temperature hydrogen generation from formic acid.  Inorganic Chemistry Frontiers,  7  (3): (709-717).  [PMID:] [10.1039/C9QI01375J]

30. Yin Hu, Chen Wei, Ba Mingwei, Xie Xin, Song Weiguo.  (2019)  Solvent-Free Hydrogenation of α-Pinene to cis-Pinane by Using Ru/TiO2 Nanocomposite with Strong Acid Sites.  Russian Journal of Physical Chemistry A,  93  (9): (1754-1761).  [PMID:] [10.1134/S0036024419090322]

31. Chunjie Li, You Xu, Songliang Liu, Shuli Yin, Hongjie Yu, Ziqiang Wang, Xiaonian Li, Liang Wang, Hongjing Wang.  (2019)  Facile Construction of IrRh Nanosheet Assemblies As Efficient and Robust Bifunctional Electrocatalysts for Overall Water Splitting.  ACS Sustainable Chemistry & Engineering,      [PMID:] [10.1021/acssuschemeng.9b03967]

32. Xie Congxia, Qu Li, Yu Hailong, Yu Fengli, Yuan Bing, Yu Shitao, Nie Shuangxi.  (2019)  Synthesis of Ru nanoparticles with hydroxyethyl cellulose as stabilizer for high-efficiency reduction of α-pinene.  CELLULOSE,  26  (13): (8059-8071).  [PMID:] [10.1007/s10570-019-02656-x]

33. Yijin Shu, Ting Chen, Hang Cheong Chan, Lifang Xie, Qingsheng Gao.  (2018)  Chemoselective Hydrogenation of Cinnamaldehyde on Iron-Oxide Modified Pt/MoO3−y Catalysts.  Chemistry-An Asian Journal,  13  (23): (3737-3744).  [PMID:30232843] [10.1002/asia.201801281]

34. Yinghua Xu, Tingjie Ge, Hongxing Ma, Xufen Ding, Xiaoyong Zhang, Qi Liu.  (2018)  Rh-Pd-alloy catalyzed electrochemical hydrodefluorination of 4-fluorophenol in aqueous solutions.  ELECTROCHIMICA ACTA,      [PMID:] [10.1016/j.electacta.2018.03.018]

35. Jing Yang, Shaotong Liu, Chunze Liu, Yuanyuan Wang, Liyi Dai.  (2018)  Correlation between Liquid Product Distribution and H2 Selectivity in Lignin Depolymerization.  CHEMICAL ENGINEERING & TECHNOLOGY,  41  (4): (867-874).  [PMID:] [10.1002/ceat.201700017]

36. Hui Lv, Yueyun Li, Xiaobo Zhang, Zengqiang Gao, Jinhui Feng, Ping Wang, Yunhui Dong.  (2017)  The label-free immunosensor based on rhodium@palladium nanodendrites/sulfo group functionalized multi-walled carbon nanotubes for the sensitive analysis of carcino embryonic antigen.  ANALYTICA CHIMICA ACTA,      [PMID:29405989] [10.1016/j.aca.2017.12.030]

37. Liang Huang, Chengpeng Jiao, Liqiong Wang, Zili Huang, Feng Liang, Simin Liu, Yuhua Wang, Haijun Zhang, Shaowei Zhang.  (2017)  Preparation of Rh/Ag bimetallic nanoparticles as effective catalyst for hydrogen generation from hydrolysis of KBH4.  NANOTECHNOLOGY,  29  (4): (044002).  [PMID:29144281] [10.1088/1361-6528/aa9b19]

38. Liqiong Wang, Liang Huang, Chengpeng Jiao, Zili Huang, Feng Liang, Simin Liu, Yuhua Wang, Haijun Zhang.  (2017)  Preparation of Rh/Ni Bimetallic Nanoparticles and Their Catalytic Activities for Hydrogen Generation from Hydrolysis of KBH4.  Catalysts,  7  (4): (125).  [PMID:] [10.3390/catal7040125]

39. Meiling Zou, Mingliang Du, Ming Zhang, Tingting Yang, Han Zhu, Pan Wang, Shiyong Bao.  (2014)  Synthesis and deposition of ultrafine noble metallic nanoparticles on amino-functionalized halloysite nanotubes and their catalytic application.  MATERIALS RESEARCH BULLETIN,      [PMID:] [10.1016/j.materresbull.2014.10.053]

40. Ruiqi Guo, Zhenglong Fan, Qiwei Zhou, Mengjie Ma, Wenxiang Zhu, Fan Liao, Hao Yang, Jiajie Wang, Zhenhui Kang, Minqi Sheng.  (2024)  Activating the passivated Ir sites in 3R-IrO2 by intercalating Pt atoms for enhanced oxygen reduction reaction activity.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.149671]

41. Xuyuan Nie, Guang Li, Linzhe Lü, Lifei Ji, Jian Yang, Yan-Xia Jiang, Binwei Zhang, Zidong Wei, Shi-Gang Sun.  (2024)  In Situ Fourier Transform Infrared Spectroscopy CO-Probe Method for Evaluating the Surface Electronic Structure of Metal Catalysts.  Journal of Physical Chemistry C,      [PMID:] [10.1021/acs.jpcc.4c05670]

42. Yang Yang, Liqiang Zhang, Jiaben Wang, Hao Song, Xiao Zhang, Xiang Gao.  (2024)  Metal-doped black In2O3 for atmospheric-pressure photothermal CO2 reduction with high efficiency and selectivity.  Catalysis Science & Technology,  14  (14): (4019-4028).  [PMID:] [10.1039/D4CY00382A]

43. Jun Zhang, Yimeng Cao, Fang Chen, Mengdie Cai, Jia-qi Bai, Jiawei Xue, Jingshuai Chen, Chang-Jie Mao, Song Sun.  (2024)  Modulating the electron interaction of Cu-Ni hybrid sites for boosting photocatalytic hydrogen evolution over Al-doped SrTiO3.  Surfaces and Interfaces,      [PMID:] [10.1016/j.surfin.2024.104156]

44. Yong Zhu, Ziqu Fang, Jie Bai, Longhui Wang, Jiaqing Chen, Zehua Zhang, Qiang Wang, Weiwei Sheng, Xueyin Pan, Zhenyuan Gao, Dengqiu Xu, Pengkai Wu, Beicheng Sun.  (2025)  Orally Administered Functional Polyphenol-Nanozyme-Armored Probiotics for Enhanced Amelioration of Intestinal Inflammation and Microbiota Dysbiosis.  Advanced Science,      [PMID:40067175] [10.1002/advs.202411939]

45. Jinxing Yu, Li Shi, Ronghua Li, Jie Huang, Ran Wang, Zhuo Li, Cai Shen, Gang Liu, Yanbo Li, Xiaoxiang Xu.  (2023)  Single-Crystalline LaTiO2N Nanosheets with Regulated Defects for Photocatalytic Overall Water Splitting under Visible Light up to 600 nm.  ACS Catalysis,      [PMID:] [10.1021/acscatal.3c04743]

46. Mao Qiqi, Mu Xu, Wang Wenxin, Deng Kai, Yu Hongjie, Wang Ziqiang, Xu You, Wang Liang, Wang Hongjing.  (2023)  Atomically dispersed Cu coordinated Rh metallene arrays for simultaneously electrochemical aniline synthesis and biomass upgrading.  Nature Communications,  14  (1): (1-12).  [PMID:37709775] [10.1038/s41467-023-41423-2]

47. Yaming Liu, Xinyu Li, Yutian Zhao, Zhenle Hu, Xinrui Zhu, Kemeng Chen, Yuxuan Lu, Guoqiang Liu, Chao Zhi, Yongzhen Wang, Jiaguang Meng, Xiang Li.  (2025)  Revealing the influence of surface structure on the fabrication of Pt-based alloy nanowires induced by H2 and their electrocatalytic upcycling of polyethylene terephthalate.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2025.125353]

48. Zhen Wang, Lei Ying, Weibin Xu, Beien Zhu, Chuande Huang, Pengfei Wu, Qingqing Gu, Bing Yang, Jian Lin, Yi Gao, Xiaodong Wang, Tao Zhang.  (2025)  Aunano-Fe1 tandem catalysis for promoted methane conversion to acetic acid by O2 oxidation.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2025.125632]

49. Xiao Yan, Yafei Luo, Wei Liu, Li Liang, Ya Gan, Zhongzhu Chen, Zhigang Xu, Hua Wan, Dianyong Tang, Hubing Shi, Jianping Hu.  (2020)  Strategy used to synthesize high activity and low Pd catalyst for Suzuki coupling reaction: an experimental and theoretical investigation.  PHYSICAL CHEMISTRY CHEMICAL PHYSICS,  22  (11): (6222-6230).  [PMID:32129367] [10.1039/C9CP06802C]

50. Kefeng Liu, Xuelian Sun, Puxin Cheng, Zhiteng Li, Penghui Li, Donghan Jia, Shijing Zhao, Xin Yang, Xinyu Wang, Liangting Ye, Shengqing Xia, Shuo Zhang, Yu Chen, Tao Gan, Jiong Li, Xiao Zhang, Jialiang Xu, Anmin Nie, Bing Huang, Huiyang Gou.  (2025)  Optimized Synthesis and Characterization of Janus RhSeCl with Uniform Anionic Valences, Nonlinear Optical and Optoelectronic Properties.  Advanced Science,  12  (34): (e05279).  [PMID:40539714] [10.1002/advs.202505279]

51. Zhizhuo Yang, Haitao Zhou, Xueqin Wu, Kun Huang.  (2025)  Confined molecular recognition in microchannels: Specific recognition of hydrated anions at interface.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2025.139335]

52. Boyang Zhang, Jiaming Zhang, Kaiwei Liu, Haifeng Wang, Yao Xu, Ke Shi, Zihao Zhang, Jifang Zhang, Guijun Ma.  (2026)  A Rhodium-Doped PbTiO3 Photocathode Applicable to Photoelectrochemical Water Splitting.  ACS Catalysis,      [PMID:] [10.1021/acscatal.5c07730]

53. Qi Wang, Muxi Chen, Jilin Yang, Zhengyi Liu, Jiazheng Lin, Xuewen Zhao, Rui Zhai, Hong Zheng, Shaobin Wang, Jinying Zhang.  (2026)  Low reduction barrier and exothermic ammonia desorption of violet phosphorene nanosheets for nitrogen photoreduction with high reduction rate and long durability.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2026.126512]

54. Jiankang Zhang, Yongsheng Wei, Hongxia Zhang, Zhiwei Zhu, Jinghui Yang, Liancheng Bing, Changqing Chu, Xiaofeng Gao, Dan Feng, Qiming Sun, Yong Qin.  (2026)  Chemical and Spatial Dual-Confinement Engineering for Antisintering Bimetal Cluster Catalyst: Framework Zinc-Stabilized Pt–(O–Zn)x Sites for Propane Dehydrogenation.  ACS Catalysis,      [PMID:] [10.1021/acscatal.6c00202]