49
In
Indium
Atomic Mass114.818
Electron Configuration[Kr]5s24d105p1
Oxidation States+3
Year Discovered1863

Identifiers

Element NameIndium
Element SymbolIn
InChIInChI=1S/In
InChIKeyAPFVFJFRJDLVQX-UHFFFAOYSA-N

Properties

Atomic Weight

114.818(1)

114.818

114.8

114.818(1)

Electron Configuration

[Kr]5s24d105p1

Atomic Radius

Van der Waals Atomic Radius :193 pm (Van der Waals)

Empirical Atomic Radius :155pm (Empirical)

Covalent Atomic Radius :142(5) pm (Covalent)

Oxidation States

+3

3, 2, 1, -1, -2, -5 ​(an amphoteric oxide)

Ground Level

21/2

Ionization Energy

5.786 eV

5.7863558 ± 0.0000005 eV

Electronegativity

Pauling Scale Electronegativity :1.78(Pauling Scale)

Allen Scale Electronegativity :1.656(Allen Scale)

Electron Affinity

0.3eV

0.2eV

Atomic Spectra

Lines Holdings

Levels Holdings

Physical Description

Solid

Element Classification

Metal

Element Period Number

5

Element Group Number

13

Density

7.31 grams per cubic centimeter

Melting Point

429.75 K (156.60°C or 313.88°F)

156.6°C

Boiling Point

2345 K (2072°C or 3762°F)

2072°C

Estimated Crustal Abundance

2.5×10-1 milligrams per kilogram

Estimated Oceanic Abundance

2×10-2 milligrams per liter

History

The name derives from the term "indigo" for the indigo-blue line in the element's spark spectrum. It was discovered in 1863 by the German physicist Ferdinand Reich and the German metallurgist Hieronymus Theodor Richter, while examining zinc blende. They isolated indium in 1867.

Indium was discovered by the German chemists Ferdinand Reich and Hieronymus Theodor Richter in 1863. Reich and Richter had been looking for traces of the element thallium in samples of zinc ores. A brilliant indigo line in the sample's spectrum revealed the existence of indium. Indium is about as abundant as silver but is much easier to recover since it typically occurs along with zinc, iron, lead and copper ores.

From the brilliant indigo line in its spectrum. Discovered by Reich and Richter, who later isolated the metal. Until 1924, a gram or so constituted the world's supply of this element in isolated form. It is probably about as abundant as silver. About 4 million troy ounces of indium are now produced annually in the Free World. Canada is presently producing more than 1,000,000 troy ounces annually.

Historical Atomic Weights

Year Atomic Weight (uncertainty) [u] Reference
2011 114.818(1) https://doi.org/10.1351/PAC-REP-13-03-02
1991 114.818(3) https://doi.org/10.1351/pac199264101519
1969 114.82(1) https://doi.org/10.1351/pac197021010091
1955 114.82 https://doi.org/10.1021/ja01595a001
1934 114.76 https://doi.org/10.1039/JR9340000499
1909 114.8 https://doi.org/10.1021/ja01931a001
1905 115 https://doi.org/10.1021/ja01979a001
1902 114 https://doi.org/10.1007/BF01370337

Historical Isotopic Abundances

Year Isotope Abundance (uncertainty) Reference
2013 113In 0.042 81(52) https://doi.org/10.1515/pac-2015-0503
2013 115In 0.957 19(52) https://doi.org/10.1515/pac-2015-0503
1997 113In 0.0429(5) https://doi.org/10.1351/pac199870010217
1997 115In 0.9571(5) https://doi.org/10.1351/pac199870010217
1979 113In 0.043(2) https://doi.org/10.1351/pac198052102349
1979 115In 0.957(2) https://doi.org/10.1351/pac198052102349
1975 113In 0.043 https://doi.org/10.1351/pac197647010075
1975 115In 0.957 https://doi.org/10.1351/pac197647010075

Description

Indium is available in ultra pure form. Indium is a very soft, silvery-white metal with a brilliant luster. The pure metal gives a high-pitched "cry" when bent. It wets glass, as does gallium.

Users

Indium is used to coat the bearings of high speed motors since it allows for the even distribution of lubricating oil. Indium is used to dope germanium to make transistors. It is also used to make other electrical components such as rectifiers, thermistors and photoconductors. Indium can be used to make mirrors that are as reflective as silver mirrors but do not tarnish as quickly. Indium is also used to make low melting alloys. An alloy of 24% indium and 76% gallium is a liquid at room temperature.

It has found application in making low-melting allows; an allow of 24% indium - 76% gallium is liquid at room temperature. It is used in making bearing alloys, germanium transistors, rectifiers, thermistors, and photoconductors. It can be plated onto metal and evaporated onto glass, forming a mirror as good as that made with silver but with more resistance to atmospheric corrosion.

Sources

Indium is most frequently associated with zinc materials, and it is from these that most commercial indium is now obtained; however, it is also found in iron, lead, and copper ores.

Compounds

See more information at the Indium compound page.

Element Forms

CID Name Formula SMILES Molecular Weight
5359967 indium In [In] 114.818
105148 indium(3+) In+3 [In+3] 114.818
6335518 indium-113 In [113In] 112.904060
5462099 indium-111 In [111In] 110.90511
6336608 indium-114 In [114In] 113.904916
6336613 indium-115 In [115In] 114.9038788
6337038 indium-116 In [116In] 115.905260
6337559 indium-109 In [109In] 108.90715
6337711 indium-119 In [119In] 118.90585
6337544 indium-112 In [112In] 111.90554
6337562 indium-117 In [117In] 116.90452
6337618 indium-110 In [110In] 109.9072
9793721 indium-111(3+) In+3 [111In+3] 110.90511
15682806 indium(1+) In+ [In+] 114.818
71510782 indium-113(3+) In+3 [113In+3] 112.904060

Handling And Storage

There is evidence that indium has a low order of toxicity; however, care should be taken until further information is available.

Isotopes

Stable Isotope Count1

Isotopes in Medicine

111In (with a half-life of 2.8 days) is used in indium leukocyte imaging (Fig. IUPAC.49.1), in which white blood cells that are abundant at sites of infection are labeled with 111In to help locate the source of the infection [361], [362], [363].

Fig. IUPAC.49.1: Radionuclide imaging of infection. Leukocytes are white blood cells in the body that protect the body from infection and can be dyed with ¹¹¹In to locate the site of an infection in the body. (Image Source: Love, Charito MD and Palestro, Christopher J. MD., 2004) [363].

[361] M. T. Syrjälä, V. Valtonen, K. Liewendahl, G. Myllylä. J. Nucl. Med.28, 155 (1987).
[362] M. D. Cerqueira, A. F. Jacobson. J. Nucl. Med.30, 703 (1989).
[363] C. Love, C. J. Palestro. J. Nucl. Med.Technol.32, 47 (2004).

Isotopes Used as a Source of Radioactive Isotope(s)

113In is used to produce 113Sn (with a half-life of 115 days) via the reaction 113In (p, n) 113Sn, and 113In is used to produce the radioisotope 110In (with a half-life of 1.15 h) [364], [365].

[364] F. E. Fakhari. Separation and Purification of 111In from Irradiated Cadmium Targets by Solid Phase Extraction (SPE) Method for Medical Applications, Deutsche National Bibliothek (2014), Feb. 26; http://archiv.ub.uni-marburg.de/diss/z2006/0132/view.html.
[365] M. Mostafa, A. A. El Sadek, H. El Said, M. A. El Amir. J. Nucl. Radiochem. Sci.10, 1 (2009).

Isotope Mass and Abundance

Isotope Atomic Mass (uncertainty) [u] Abundance (uncertainty)
113In 112.904 060(2) 0.042 81(52)
115In 114.903 878 77(8) 0.957 19(52)
Isotope Atomic Mass (uncertainty) [u] Abundance (uncertainty)
113In 112.90406184(91) 0.0429(5)
115In 114.903878776(12) 0.9571(5)

Atomic Mass, Half Life, and Decay

Nuclide Atomic Mass and Uncertainty [u] Half Life and Uncertainty Discovery Year Decay Modes, Intensities and Uncertainties [%]
96In 95.959109 ± 0.000537 [Estimated] 1 ms >400ns [Estimated] 2016 β+ ?; p ?
97In 96.949125 ± 0.00043 [Estimated] 36 ms ± 6 2011 β+=100%; β+p=2.3±1.3%; p ?
97Inm 96.949125 ± 0.00043 [Estimated] 0.12 ms ± 0.07 2018 p ?
98In 97.942129 ± 0.000327 [Estimated] 30 ms ± 1 1994 β+=100%; β+p<0.13%
98Inm 97.942129 ± 0.000327 [Estimated] 890 ms ± 20 2001 β+=100%; β+p=44±0.2%
99In 98.934110 ± 0.00032 [Estimated] 3.11 s ± 0.06 1994 β+=100%; β+p=0.29±0.3%
99Inm 98.934110 ± 0.00032 [Estimated] 1 s [Estimated] β+ ?; β+p ?; IT ?
100In 99.931101929 ± 0.0000024 5.62 s ± 0.06 1982 β+=100%; β+p=1.66±0.3%
101In 100.926414025 ± 0.000012519 15.1 s ± 1.1 1988 β+=100%; β+p<1.7%
101Inm 100.926414025 ± 0.000012519 10 s [Estimated] 2019 β+ ?; IT ?
102In 101.924105911 ± 0.000004909 23.3 s ± 0.1 1981 β+=100%; β+p=0.0093±1.3%
103In 102.919878830 ± 0.00000964 60 s ± 1 1978 β+=100%
103Inm 102.919878830 ± 0.00000964 34 s ± 2 1988 β+=67%; IT=33%
104In 103.918214538 ± 0.0000062 1.80 m ± 0.03 1977 β+=100%
104Inm 103.918214538 ± 0.0000062 15.7 s ± 0.5 1988 IT=80±0.5%; β+=20±0.5%
105In 104.914502322 ± 0.000011 5.07 m ± 0.07 1975 β+=100%
105Inm 104.914502322 ± 0.000011 48 s ± 6 1975 IT≈100%; β+ ?
106In 105.913463596 ± 0.000013125 6.2 m ± 0.1 1962 β+=100%
106Inm 105.913463596 ± 0.000013125 5.2 m ± 0.1 1966 β+=100%
107In 106.910287497 ± 0.000010363 32.4 m ± 0.3 1949 β+=100%
107Inm 106.910287497 ± 0.000010363 50.4 s ± 0.6 1973 IT=100%
108In 107.909693654 ± 0.000009276 58.0 m ± 1.2 1949 β+=100%
108Inm 107.909693654 ± 0.000009276 39.6 m ± 0.7 1955 β+=100%
109In 108.907149679 ± 0.000004261 4.159 h ± 0.010 1948 β+=100%
109Inm 108.907149679 ± 0.000004261 1.34 m ± 0.06 1966 IT=100%
109Inn 108.907149679 ± 0.000004261 210.0 ms ± 0.9 1963 IT=100[gs=100,m=0]
110In 109.907170674 ± 0.000012402 4.92 h ± 0.08 1939 β+=100%
110Inm 109.907170674 ± 0.000012402 69.1 m ± 0.5 1962 β+=100%
111In 110.905107236 ± 0.000003675 2.8048 d ± 0.0001 1947 ε=100%
111Inm 110.905107236 ± 0.000003675 7.7 m ± 0.2 1966 IT=100%
112In 111.905538718 ± 0.000004563 14.88 m ± 0.15 1947 β+=62±0.4%; β-=38±0.4%
112Inm 111.905538718 ± 0.000004563 20.67 m ± 0.08 1953 IT=100%
112Inn 111.905538718 ± 0.000004563 690 ns ± 50 1976 IT=100%
112Inp 111.905538718 ± 0.000004563 2.81 us ± 0.03 1976 IT=100%
113In 112.904060451 ± 0.000000202 Stable 1934 IS=4.281±5.2%
113Inm 112.904060451 ± 0.000000202 1.6579 h ± 0.0004 1939 IT=100%
114In 113.904916405 ± 0.000000323 71.9 s ± 0.1 1937 β-=99.50±1.5%; β+=0.50±1.5%
114Inm 113.904916405 ± 0.000000323 49.51 d ± 0.01 1939 IT=96.75±2.4%; β+=3.25±2.4%
114Inn 113.904916405 ± 0.000000323 43.1 ms ± 0.6 1958 IT=100[gs=0,m=100]
115In 114.903878772 ± 0.000000012 441 Ty ± 25 1924 IS=95.719±5.2%; β-=100%
115Inm 114.903878772 ± 0.000000012 4.486 h ± 0.004 1961 IT=95.0±0.7%; β-=5.0±0.7%
116In 115.905259992 ± 0.000000236 14.10 s ± 0.03 1937 β-≈100%; ε=0.0237±4.3%
116Inm 115.905259992 ± 0.000000236 54.29 m ± 0.17 1945 β-=100%
116Inn 115.905259992 ± 0.000000236 2.18 s ± 0.04 1950 IT=100[gs=0,m=100]
117In 116.904515729 ± 0.000005239 43.2 m ± 0.3 1937 β-=100%
117Inm 116.904515729 ± 0.000005239 116.2 m ± 0.3 1940 β-=52.9±1.5%; IT=47.1±1.5%
118In 117.906356705 ± 0.000008322 5.0 s ± 0.5 1949 β-=100%
118Inm 117.906356705 ± 0.000008322 4.364 m ± 0.007 1964 β-=100%
118Inn 117.906356705 ± 0.000008322 8.5 s ± 0.3 1969 IT=98.6 3[gs=0,m=98.6]; β-=1.4±0.3%
119In 118.905851622 ± 0.000007847 2.4 m ± 0.1 1949 β-=100%
119Inm 118.905851622 ± 0.000007847 18.0 m ± 0.3 1973 β-=97.4±0.4%; IT=2.6±0.4%
119Inn 118.905851622 ± 0.000007847 130 ns ± 15 1974 IT=100%
119Inp 118.905851622 ± 0.000007847 265 ns ± 10 2002 IT=100%
120In 119.907967489 ± 0.000042953 3.08 s ± 0.08 1958 β-=100%
120Inm 119.907967489 ± 0.000042953 46.2 s ± 0.8 1960 β-=100%
120Inn 119.907967489 ± 0.000042953 47.3 s ± 0.5 1960 β-=100%
121In 120.907852778 ± 0.000029435 23.1 s ± 0.6 1960 β-=100%
121Inm 120.907852778 ± 0.000029435 3.88 m ± 0.10 1974 β-=98.8±0.2%; IT=1.2±0.2%
121Inn 120.907852778 ± 0.000029435 7.3 us ± 2 2002 IT=100%
122In 121.910282458 ± 0.000053741 1.5 s ± 0.3 1963 β-=100%
122Inm 121.910282458 ± 0.000053741 10.3 s ± 0.6 1979 β-=100%
122Inn 121.910282458 ± 0.000053741 10.8 s ± 0.4 1979 β-=100%
123In 122.910435252 ± 0.00002129 6.17 s ± 0.05 1960 β-=100%
123Inm 122.910435252 ± 0.00002129 47.4 s ± 0.4 1960 β-=100%
123Inn 122.910435252 ± 0.00002129 1.4 us ± 0.2 2004 IT=100%
123Inp 122.910435252 ± 0.00002129 >100 us 2010 IT=100%
124In 123.913184873 ± 0.000032808 3.12 s ± 0.09 1964 β-=100%
124Inm 123.913184873 ± 0.000032808 3.67 s ± 0.03 1974 β-≈100%; IT ?
125In 124.913673841 ± 0.0000019 2.36 s ± 0.04 1967 β-=100%
125Inm 124.913673841 ± 0.0000019 12.2 s ± 0.2 1974 β-=100%
125Inn 124.913673841 ± 0.0000019 9.4 us ± 0.6 1998 IT=100%
125Inp 124.913673841 ± 0.0000019 5.0 ms ± 1.5 1998 IT=100%
126In 125.916468202 ± 0.0000045 1.53 s ± 0.01 1974 β-=100%
126Inm 125.916468202 ± 0.0000045 1.64 s ± 0.05 1970 β-=100%
126Inn 125.916468202 ± 0.0000045 22 us ± 2 2003 IT=100%
127In 126.917466040 ± 0.000010736 1.086 s ± 0.007 1975 β-=100%; β-n<0.03%
127Inm 126.917466040 ± 0.000010736 3.618 s ± 0.021 1974 β-=100%; β-n=0.70±0.4%
127Inn 126.917466040 ± 0.000010736 1.04 s ± 0.10 2004 β-=100%; β-n ?
127Inp 126.917466040 ± 0.000010736 9 us ± 2 2004 IT=100%
128In 127.920353637 ± 0.000001419 816 ms ± 27 1975 β-=100%; β-n=0.038±0.3%
128Inm 127.920353637 ± 0.000001419 23 us ± 2 1988 IT=100%
128Inn 127.920353637 ± 0.000001419 720 ms ± 100 1986 β-=100%; IT ?; β-n ?
128Inp 127.920353637 ± 0.000001419 >0.3 s 2020 β-≈100%; IT ?; β-n ?
129In 128.921808534 ± 0.000002116 570 ms ± 10 1975 β-=100%; β-n=0.23±0.7%
129Inm 128.921808534 ± 0.000002116 1.23 s ± 0.03 1976 β-≈100%; IT ?; β-n=3.6±0.4%
129Inn 128.921808534 ± 0.000002116 11.2 us ± 0.2 2003 IT=100%
129Inp 128.921808534 ± 0.000002116 670 ms ± 100 2004 β-≈100%; IT ?
129Inq 128.921808534 ± 0.000002116 110 ms ± 15 2004 IT≈100%; β- ?
130In 129.924952257 ± 0.000001921 273 ms ± 5 1973 β-=100%; β-n=0.93±1.3%
130Inm 129.924952257 ± 0.000001921 540 ms ± 10 1973 β-=100%; β-n=1.80±0.7%
130Inn 129.924952257 ± 0.000001921 540 ms ± 10 1986 β-=100%; β-n=1.80±0.7%
130Inp 129.924952257 ± 0.000001921 4.6 us ± 0.2 2003 IT=100%
131In 130.926972839 ± 0.000002367 261.5 ms ± 2.8 1976 β-=100%; β-n=2.25±2.1%
131Inm 130.926972839 ± 0.000002367 328 ms ± 15 1984 β-=100%; β-n=2.25±2.1%; IT ?
131Inn 130.926972839 ± 0.000002367 322 ms ± 41 1984 β-=100%; β-n=12±0.7%; IT ?
131Inp 130.926972839 ± 0.000002367 669 ns ± 34 2009 IT=100%
132In 131.932998444 ± 0.000064447 202.2 ms ± 0.2 1973 β-=100%; β-n=12.3±0.4%; β-2n ?
133In 132.938067 ± 0.000215 [Estimated] 163.0 ms ± 1.6 1996 β-=100%; β-n=90±0.3%; β-2n ?
133Inm 132.938067 ± 0.000215 [Estimated] 167 ms ± 11 1996 β-=100%; β-n=93±0.3%
134In 133.944208 ± 0.000215 [Estimated] 136 ms ± 4 1996 β-=100%; β-n≈65%; β-2n<4%
134Inm 133.944208 ± 0.000215 [Estimated] 3.5 us ± 0.4 2019 IT=100%
135In 134.949425 ± 0.000322 [Estimated] 103 ms ± 3 2002 β-=100%; β-n= ?; β-2n ?
136In 135.956017 ± 0.000322 [Estimated] 86 ms ± 9 2015 β-=100%; β-n ?; β-2n ?
137In 136.961535 ± 0.000429 [Estimated] 70 ms ± 40 2015 β-=100%; β-n ?; β-2n ?

Information Sources

  1. 1.  PubChem
  2. 2.  Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
  3. 3.  IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
  4. 4.  Jefferson Lab, U.S. Department of Energy
    LICENSE
    Please see citation and linking information https https://www.jlab.org/privacy-and-security-notice
  5. 5.  Los Alamos National Laboratory, U.S. Department of Energy
  6. 6.  NIST Physical Measurement Laboratory
  7. 7.  IUPAC Periodic Table of the Elements and Isotopes (IPTEI)
    LICENSE
    Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
    https://creativecommons.org/licenses/by-nc-nd/4.0/
  8. 8.  PubChem Elements
    Indium

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