Platinum oxide - Pt, 80-86% , CAS No.1314-15-4

CAS: 1314-15-4 Cat. No.: P141419 Formula: PtO₂ Molecular Weight: 227.08 EC Number: 215-223-0

GRADE & PURITY Pt, 80-86%

Synonyms

BCP21184 | O2Pt | Platinum( cento) oxide | Platinum(IV) oxide | Platinum(IV) oxide, anhydrous, Premion? | Platinic oxide | (6aR,10aR)-6,6,9-Trimethyl-3-pentyl-6a,7,10,10a-tetrahydro-6H-benzo[c]chromen-1-ol | platinum (IV)oxide | Platinum (1V) oxide | UNII

Storage

Store at 2-8°C

Shipped In

Wet ice

Overview

Prepared by Adams′ nitrate fusion method.
Catalyst for hydrogenation of various functional groups; used as dehydrogenation catalyst; used for selective oxidation of primary alcohols. Catalyst for: Hydrohydrazination reactions Oxidation of sugars Low-temperature oxidation of carbon monoxide Oxygen reduction reaction Hydrogenation reactions Hydrogenolysis of the cyclopropyl group into an isopropyl group Hydroxycyclopropanation reactions

Specifications

Synonyms

BCP21184 | O2Pt | Platinum( cento) oxide | Platinum(IV) oxide | Platinum(IV) oxide, anhydrous, Premion? | Platinic oxide | (6aR,10aR)-6,6,9-Trimethyl-3-pentyl-6a,7,10,10a-tetrahydro-6H-benzo[c]chromen-1-ol | platinum (IV)oxide | Platinum (1V) oxide | UNII

Specifications & Purity

Pt, 80-86%

Storage

Store at 2-8°C

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Names and Identifiers

Pubchem Sid

508814043

Canonical Smiles

O=[Pt]=O

IUPAC Name

dioxoplatinum

InChIKey

YKIOKAURTKXMSB-UHFFFAOYSA-N

INCHI

1S/2O.Pt

Isomeric SMILES

O=[Pt]=O

Molecular Weight

227.08

Reaxy-Rn

11322543

Reaxys-RN_link_address

https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=11322543&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Class Transition metal organides
      • Subclass Transition metal oxides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Class: Transition metal organides
• Subclass: Transition metal oxides
• Intermediate Tree Nodes: Not available
• Direct Parent: Transition metal oxides
• Alternative Parents: Inorganic oxides
• Molecular Framework: Not available
• Substituents: Transition metal oxide - Inorganic oxide
• Description: This compound belongs to the class of inorganic compounds known as transition metal oxides. These are inorganic compounds containing an oxygen atom of an oxidation state of -2, in which the heaviest atom bonded to the oxygen is a transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Moisture sensitive
• Melt Point(°C): 450℃
• Molecular Weight: 227.080 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 226.955 Da
• Monoisotopic Mass: 226.955 Da
• Topological Polar Surface Area: 34.100 Ų
• Heavy Atom Count: 3
• Formal Charge: 0
• Complexity: 18.300
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3