Triethoxymethylsilane - ≥98% , CAS No.2031-67-6

CAS: 2031-67-6 Cat. No.: T103634 Molecular Weight: 178.3 Beilstein Registry Number: 1742453 EC Number: 217-983-9 PubChem CID: 16241

GRADE & PURITY ≥98%

Synonyms

MTES | Triethoxy(methyl)silane | Methyl triethoxysilane | Triethoxymethylsilane | Methyltriethoxysilane | Methaneorthosiliconic acid, triethyl ester | Silane, triethoxymethyl- | SILANE, METHYLTRIETHOXY- | Triethoxysilylmethane | Union carbide A-162

Storage

Room temperature,Argon charged,Desiccated,Cool

Shipped In

FedEx DG Service

Overview

Triethoxymethylsilane is an organosilane that can be used to prepare:
An oxidizing catalyst known with excellent features such as selectivity, stability, and recyclability.
A hydrogel heterogeneous platinum catalyst applicable in the chemoselective hydrogenation of nitroarenes

Specifications

Synonyms

MTES | Triethoxy(methyl)silane | Methyl triethoxysilane | Triethoxymethylsilane | Methyltriethoxysilane | Methaneorthosiliconic acid, triethyl ester | Silane, triethoxymethyl- | SILANE, METHYLTRIETHOXY- | Triethoxysilylmethane | Union carbide A-162

Specifications & Purity

≥98%

Storage

Room temperature, Argon charged, Desiccated, Cool

Shipped In

FedEx DG Service

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥98%

Names and Identifiers

• Pubchem Sid: 504752737
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504752737
• Canonical Smiles: CCO[Si](C)(OCC)OCC
• IUPAC Name: triethoxy(methyl)silane
• InChIKey: CPUDPFPXCZDNGI-UHFFFAOYSA-N
• INCHI: 1S/C7H18O3Si/c1-5-8-11(4,9-6-2)10-7-3/h5-7H2,1-4H3
• Isomeric SMILES: CCO[Si](C)(OCC)OCC
• WGK Germany: 3
• RTECS: VV4640000
• PubChem CID: 16241
• UN Number: 1993
• Packing Group: III
• Molecular Weight: 178.3
• Beilstein: 1742453
• Reaxy-Rn: 1742453

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Class Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Alkoxysilanes
          • Level6 Trialkoxysilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Class: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Alkoxysilanes
• Direct Parent: Trialkoxysilanes
• Alternative Parents: Silyl ethers Organoheterosilanes Organic metalloid salts Organooxygen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkoxysilane - Silyl ether - Organoheterosilane - Organic metalloid salt - Organic oxygen compound - Hydrocarbon derivative - Organic salt - Organooxygen compound - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as trialkoxysilanes. These are organosilicon compounds with the general formula RO[Si](R')(OR'')OR''' (R-R''' = aliphatic organyl group).
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: Solubility in water: insoluble;Solubility in other solvents: soluble in most common organic solvents
• Sensitivity: Moisture Sensitive
• Refractive Index: 1.3835
• Flash Point(°C): 23 °C
• Boil Point(°C): 141-143 °C
• Molecular Weight: 178.300 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 178.103 Da
• Monoisotopic Mass: 178.103 Da
• Topological Polar Surface Area: 27.700 Ų
• Heavy Atom Count: 11
• Formal Charge: 0
• Complexity: 80.700
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

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66. Li Zhaorui, Li Zhiqiang, Wu Yonghong, Zhu Wenle, Nie Lifang, Liu Juncheng.  (2025)  Preparation of SiO2 Film with High Hardness and Antireflection with AEO.  Silicon,      [PMID:] [10.1007/s12633-025-03225-7]

67. Yan Liu, Qian Jiang, Ke Zhou, Qilin Gu, Zhaoxiang Zhong, Wenheng Jing, Yiqun Fan, Weihong Xing.  (2024)  Tailored surface wettability and pore structure of hydrophobic SiO2/SiC membranes for preparing monodisperse emulsion with high-efficiency.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2024.160364]

68. Chuhui Qin, Hangyu Zhong, Hongli Hu, Zhonglei Kang, Bo-xing Zhang.  (2025)  Ultrasonic sprayed hollow ceramic/carbon microspheres function as thermal insulation, ablative resistance, and electromagnetic shielding materials.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2025.01.579]

69. Shuaiwei Peng, Tianguan Wang, Guang Huang, Zhuofu Tang, Ziya Shao, Zhiyuan Feng, Bing Lei, Guozhe Meng, Honglei Guo.  (2024)  Unraveling the complex infiltration and repairing behaviors in defect coatings.  JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,      [PMID:] [10.1016/j.jmst.2023.11.037]

70. Shuhua Tu, Lele Zhang, Weizhen Zhang, Jie Feng.  (2025)  Waterborne Recoatable Transparent Superhydrophobic Coatings with Excellent Self-Cleaning and Anti-Dust Performance.  Small,      [PMID:39828594] [10.1002/smll.202410171]

71. Huajun Zhai, Shuaiheng Zhao, Na Liu, Ye Tian, Yue Liu, Wenqing Cao, Wei Yen, Lin Feng.  (2024)  Water-Enabled Electricity Generation by a Smooth Liquid-Like Semiconductor Coating Surface.  Small,      [PMID:39737678] [10.1002/smll.202410599]

72. Nana Xu, Jingyu Li, Danchi Zhou, Han Luo, Yuanbing Li.  (2025)  Scalable Fabrication of Y3+-Doped Silica-based Multiphase Nanofibers for High-Performance Thermal Insulation Applications.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2025.08.413]

73. Xiaoying Xin, Yuting Tian, Wanxiong Yong, Jun Hu, Miaomiao Liu, Weining Liu, Yanling Chen, Guodong Fu.  (2025)  Polysiloxane Coatings Based on Organic–Inorganic Interpenetrating Networks with High Transparency, Efficient Anti-Icing Properties, and Flame Retardancy.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.5c01793]

74. Ruirui Zhang, Junru Yao, Jinlong Lv, Tantan Liu, Yan Wang, Dongchuang Wu, Lei Zhang, Youyi Sun.  (2025)  Heat treatment of silica aerogel for enhanced mechanical properties, heat insulation, oil-water separation and self-cleaning.  JOURNAL OF NON-CRYSTALLINE SOLIDS,      [PMID:] [10.1016/j.jnoncrysol.2025.123788]

75. Ding Zhaodong, Tian Zhongjian, Ji Xingxiang, Dai Hongqi, Si Chuanling.  (2022)  Bio-inspired catalytic one-step prepared R-siloxane cellulose composite membranes with highly efficient oil separation.  Advanced Composites and Hybrid Materials,  5  (3): (2138-2153).  [PMID:] [10.1007/s42114-022-00517-z]

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77. Xiuying Liu, Keke Chen, Jiayan Wang, Yu Wang, Yiwei Tang, Xue Gao, Lijie Zhu, Xuepeng Li, Jianrong Li.  (2019)  An on-package colorimetric sensing label based on a sol-gel matrix for fish freshness monitoring.  FOOD CHEMISTRY,      [PMID:31634762] [10.1016/j.foodchem.2019.125580]

78. Ziyang Zhou, Zhengquan Wang, Xueling Fan.  (2025)  Enhanced corrosion and UV resistance of double-layer structural epoxy coatings reinforced with graphene oxide/carbon nanotubes hybrids.  CONSTRUCTION AND BUILDING MATERIALS,      [PMID:] [10.1016/j.conbuildmat.2025.142409]

79. Nanjing Zhong, Weilin Chen, Liyan Liu, Hongxiao Chen.  (2018)  Immobilization of Rhizomucor miehei lipase onto the organic functionalized SBA-15: Their enzymatic properties and glycerolysis efficiencies for diacylglycerols production.  FOOD CHEMISTRY,      [PMID:30236739] [10.1016/j.foodchem.2018.07.185]

80. Fenghuan Zhao, Xihong Zhao, Nanjing Zhong.  (2020)  Organic Modifications of SBA-15 Improves the Enzymatic Properties of its Supported TLL.  Journal of Oleo Science,      [PMID:32759550] [10.5650/jos.ess20020]

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82. Lixin Sun, Dong Tian, Kaiming Zhang, Yahui Wu, Yanan Sun, Yujie Jiang, Chuanhui Gao, Lei Liu, Yuetao Liu.  (2025)  Antimicrobial anticorrosive silicone resin coating with high adhesion and excellent mechanical properties.  POLYMER,      [PMID:] [10.1016/j.polymer.2025.128366]

83. Bing Yin, Youqing Hou, Xiaoyue Jia, Fangyu Fan, Pan Wang, Ditao Niu, Dongshuai Hou.  (2025)  Enhancing Adhesion and Corrosion Resistance of Epoxy Coatings on Steel Reinforcing Bars Through the Incorporation of Functional Interface Layers.  JOURNAL OF APPLIED POLYMER SCIENCE,      [PMID:] [10.1002/app.57116]

84. Chengdong Li, Yuxiang Wang.  (2025)  Iron/silicon oxy-hydroxide co-precipitate trace-incorporated [-Fe-O]m-[Si-O-]n colloids: A facile strategy for silica xerogel strengthening and toughening.  CONSTRUCTION AND BUILDING MATERIALS,      [PMID:] [10.1016/j.conbuildmat.2025.139895]

85. Yong Kong, Fangchen Tang, Zhiting Tan, Xiaodong Shen.  (2025)  Bifunctionalized hybrid silica aerogels for stable low-concentration CO2 capture and thermal insulation under humid and high-temperature conditions.  Green Chemical Engineering,      [PMID:] [10.1016/j.gce.2025.05.004]

86. Fanze Meng, Bi Wu, Xiaoguang Yang, Deli Duan.  (2025)  Yttrium tungstate/graphene nanosheets/silicone rubber ternary nanocomposites with intensifiedpositive temperature coefficient effect applied to self-limiting heaters.  COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING,      [PMID:] [10.1016/j.compositesa.2025.109134]

87. Xiaolei Zhang, Tingshuo Kang, Jianchen Sun, Jianxin Liu, Gulizhaina Habudula, Guogang Sun.  (2025)  Wettability modification and region optimization of PEMCs porous transport layer: A comparative study utilizing PDMS and MTMS/HDTMS hybrid solutions.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2025.150087]

88. Yuxia Zhong, Zhihua Zhang, Min Zhang, Yujie Liao, Shudong Shi, Wenyao Chen, Liang Wang, Xinggui Zhou, Xuezhi Duan.  (2025)  Engineering the surface hydrophobicity of Au/TS-1 catalyst to promote the selective oxidation of propane.  CHEMICAL ENGINEERING SCIENCE,      [PMID:] [10.1016/j.ces.2025.122122]

89. Chunjing Liu, Guoqiang Xu, Yangyang Xie, Chenghua Zhang, Xin Hu, Hongxu Chen, Botao Teng.  (2025)  Tuning hydrophobicity and microporosity of NaY zeolite for greatly enhanced adsorption of alcohols and acids from Fischer-Tropsch wastewater.  JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,      [PMID:] [10.1016/j.jiec.2025.10.055]

90. Chenhao Wu, Kunfeng Li, Zhifang Fei, Zhen Zhang, Shuang Zhao, Guobing Chen, Zichun Yang.  (2025)  Preparation of high-performance SiO₂ aerogel using organic bases as catalysts and surfactants.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2025.138950]

91. Qing Li, Songping Mo, Yuxuan Lin, Lisi Jia, Zhi Yang, Yanping Du, Ying Chen.  (2025)  Enhancing thermal properties and moisture resistance of eutectic molten salts via nanoencapsulation for medium-temperature thermal energy storage.  Journal of Energy Storage,      [PMID:] [10.1016/j.est.2025.119634]

92. Haoran Li, Tianqi Ma, Yanchao Wu, Huimin Qi, Ga Zhang, Huijing Li.  (2025)  MOF/IL-hybridized polysiloxane with rapid room-temperature self-healing and dual antibacterial properties.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2025.109894]

93. Liying Pan, Qiu Zhang, Xueyue Lyu, Chenyang Zhang, Xinrui Wang, Jiawei Qi, Guangdong Zhao.  (2026)  Synergistic promotion of sound absorption high-temperature stability and moisture resistance for SiO₂/C/SiBOC ceramic composites.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2026.186127]

94. Mingmei Ding, Ho Kyong Shon, Li Gao, Chengzhi Hu.  (2026)  Enhanced permeability and resistance to scaling-induced wetting performance for solar-driven desalination membrane with octopus arm-sucker structure.  DESALINATION,      [PMID:] [10.1016/j.desal.2026.119973]

95. Gang Xu, Baojun Sun, Xiaowei Zhang, Jie Gao, Xiaomei Li, Limin Bai, Ying Zhang, Shihan Li, Yang Wang.  (2026)  Fabrication of a highly sensitive and stable fluorinated xerogel/cellulose acetate film optical sensor for application in dissolved oxygen detection.  Analytical Methods,      [PMID:] [10.1039/D6AY00197A]

96. Yu Xia, Zhiguang Guo.  (2026)  Durable Bionic Honeycomb Superhydrophobic Coating with Anti-Corrosion Properties.  Surfaces and Interfaces,      [PMID:] [10.1016/j.surfin.2026.108988]

97. Liu Qidong, Wu Xiumei, Peng Yukang, Li Yunping, Yu Shu, Xiao Zian.  (2026)  Biocompatibility and Bioactivity of Zn-Modified SiOC Ceramic Coating on C/C Composite Substrate.  JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE,      [PMID:] [10.1007/s11665-026-13713-5]