1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4- cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II) - ≥98% , CAS No.104439-77-2

CAS: 104439-77-2 Cat. No.: H121109 Molecular Weight: 1085.13 EC Number: 817-875-7 PubChem CID: 56845452

GRADE & PURITY ≥98%

Synonyms

1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II) | 2,4-Cyclopentadien-1-one, 2,3,4,5-tetraphenyl-, ruthenium complex | Shvo’s Catalyst Tetracarbonyl-μ-hydro[(1,2,3,4,5-H)-1-hydroxylato-2,3,4,5

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

Has found numerous applications as a versatile catalyst in organic synthesis, including the reduction of aldehydes and ketones to alcohols, bimolecular disproportionation reaction of aldehydes to esters, isomerization of allylic alcohols and oxidation of alcohols.

Specifications

Synonyms

1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2, 4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II) | 2, 4-Cyclopentadien-1-one, 2, 3, 4, 5-tetraphenyl-, ruthenium complex | Shvo’s Catalyst Tetracarbonyl-μ-hydro[(1, 2, 3, 4, 5-H)-1-hydroxylato-2, 3, 4, 5

Specifications & Purity

≥98%

Storage

Store at 2-8°C, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥98%

Names and Identifiers

• Canonical Smiles: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)C2=C(C(=O)C(=C2C3=CC=CC=C3)C4=CC=CC=C4)C5=CC=CC=C5.C1=CC=C(C=C1)[C]2[C]([C]([C]([C]2C3=CC=CC=C3)O)C4=CC=CC=C4)C5=CC=CC=C5.[Ru].[Ru]
• InChIKey: LYADOKFHMFDLJK-UHFFFAOYSA-N
• INCHI: 1S/C29H21O.C29H20O.4CO.2Ru/c2*30-29-27(23-17-9-3-10-18-23)25(21-13-5-1-6-14-21)26(22-15-7-2-8-16-22)28(29)24-19-11-4-12-20-24;4*1-2;;/h1-20,30H;1-20H
• Isomeric SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)C2=C(C(=O)C(=C2C3=CC=CC=C3)C4=CC=CC=C4)C5=CC=CC=C5.C1=CC=C(C=C1)[C]2[C]([C]([C]([C]2C3=CC=CC=C3)O)C4=CC=CC=C4)C5=CC=CC=C5.[Ru].[Ru]
• WGK Germany: 3
• PubChem CID: 56845452
• Molecular Weight: 1085.13

Chemical and Physical Properties

• Solubility: Soluble in water and polar organic solvents.
• Sensitivity: air sensitive,Moisture sensitive
• Melt Point(°C): 223-227°C