Lithium aluminum hydride solution(LAH) - 2.3 M in 2-methyltetrahydrofuran , CAS No.16853-85-3

CAS: 16853-85-3 Cat. No.: L432198 Molecular Weight: 37.95 EC Number: 240-877-9 PubChem CID: 21226445

GRADE & PURITY 2.3 M in 2-methyltetrahydrofuran

Synonyms

AKOS025404931 | aluminum-lithium hydride | lithium- aluminium hydride | AKOS015901019 | SY029553 | lithium aluminium tetrahydride | Lithium Aluminum Hydride (1M in THF) | lithim aluminum hydride | lithum aluminium hydride | litium aluminum hydride | BJKLP

Storage

Room temperature

Shipped In

FedEx DG Service

Overview

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 2.3 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.

Application

Reactant or reagent for: The preparation of thermoplastic polyester polyamides from oleic acid Lithium-polymer batteries Hydrodefluorination of gem -difluoromethylene derivatives Asymmetric aldol reactions Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols Powerful reducing agent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF). 2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Specifications

Synonyms

AKOS025404931 | aluminum-lithium hydride | lithium- aluminium hydride | AKOS015901019 | SY029553 | lithium aluminium tetrahydride | Lithium Aluminum Hydride (1M in THF) | lithim aluminum hydride | lithum aluminium hydride | litium aluminum hydride | BJKLP

Specifications & Purity

2.3 M in 2-methyltetrahydrofuran

Storage

Room temperature

Shipped In

FedEx DG Service

This product requires cold chain shipping. Ground and other economy services are not available.

Names and Identifiers

• Canonical Smiles: [H-].[H-].[H-].[H-].[Li+].[Al+3]
• IUPAC Name: aluminum;lithium;hydride
• InChIKey: BJKLPLABXHXMIM-UHFFFAOYSA-N
• INCHI: 1S/Al.Li.4H/q+3;+1;4*-1
• Isomeric SMILES: [H-].[H-].[H-].[H-].[Li+].[Al+3]
• WGK Germany: 1
• PubChem CID: 21226445
• UN Number: 1410
• Packing Group: I
• Molecular Weight: 37.95

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Class Post-transition metal organides
      • Subclass Post-transition metal hydrides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Class: Post-transition metal organides
• Subclass: Post-transition metal hydrides
• Intermediate Tree Nodes: Not available
• Direct Parent: Post-transition metal hydrides
• Alternative Parents: Post-transition metal salts Inorganic lithium salts Inorganic hydrides
• Molecular Framework: Not available
• Substituents: Post-transition metal hydride - Inorganic lithium salt - Inorganic post-transition metal salt - Inorganic hydride - Inorganic salt
• Description: This compound belongs to the class of inorganic compounds known as post-transition metal hydrides. These are inorganic hydride compounds in which the heaviest metal atom is a post-transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Molecular Weight: 38.000 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 38.0288 Da
• Monoisotopic Mass: 38.0288 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 2
• Formal Charge: 0
• Complexity: 0.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 6

XLogP3

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