Lithium methoxide solution - 1.0 M in methanol , CAS No.865-34-9

CAS: 865-34-9 Cat. No.: L434281 Formula: CH₃OLi Molecular Weight: 37.97 Beilstein Registry Number: 3552389 EC Number: 212-737-7

GRADE & PURITY 1.0 M in methanol

Synonyms

AKOS015840118 | Q1226073 | BCP29450 | L0304 | Lithium methoxide | s11669 | FT-0627914 | JILPJDVXYVTZDQ-UHFFFAOYSA-N | EINECS 212-737-7 | Methanol, lithium salt | MFCD00036357 | lithium methylat | Lithium methylate | Lithium Methoxide (ca.10% in Methanol)

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Overview

Lithium methoxide solution, also known as lithium methylate, is an organolithium compound supplied as a colorless solution in methanol. It is highly soluble in polar solvents, making it suitable for solution-based applications. It serves as a strong base in organic reactions and is used in the production of polymers and specialty chemicals.

Advantages and Specific：

Lithium methoxide solution in methanol is significant in several applications due to its strong basicity and reactivity. Its solubility in methanol allows for easy handling and mixing with other reactants, facilitating reactions in a liquid medium.

Specifications

Synonyms

AKOS015840118 | Q1226073 | BCP29450 | L0304 | Lithium methoxide | s11669 | FT-0627914 | JILPJDVXYVTZDQ-UHFFFAOYSA-N | EINECS 212-737-7 | Methanol, lithium salt | MFCD00036357 | lithium methylat | Lithium methylate | Lithium Methoxide (ca.10% in Methanol)

Specifications & Purity

1.0 M in methanol

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Names and Identifiers

Canonical Smiles

[Li+].C[O-]

IUPAC Name

lithium;methanolate

InChIKey

JILPJDVXYVTZDQ-UHFFFAOYSA-N

INCHI

1S/CH3O.Li/c1-2;/h1H3;/q-1;+1

Isomeric SMILES

[Li+].C[O-]

WGK Germany

3

UN Number

3206

Packing Group

II

Molecular Weight

37.97

Beilstein

3552389

Reaxy-Rn

3552389

Reaxys-RN_link_address

https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=3552389&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic salts
    • Class Organic metal salts
      • Subclass Organic alkali metal salts

• Kingdom: Organic compounds
• Superclass: Organic salts
• Class: Organic metal salts
• Subclass: Organic alkali metal salts
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic lithium salts
• Alternative Parents: Organic zwitterions Organic oxides Hydrocarbon derivatives Alkoxides
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Organic lithium salt - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organic zwitterion - Alkoxide - Organooxygen compound - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as organic lithium salts. These are organic compounds containing a lithium ion.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Flash Point(°F): 68 °F
• Flash Point(°C): 20 °C
• Melt Point(°C): 204-206°C
• Molecular Weight: 38.000 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 38.0344 Da
• Monoisotopic Mass: 38.0344 Da
• Topological Polar Surface Area: 23.100 Ų
• Heavy Atom Count: 3
• Formal Charge: 0
• Complexity: 4.800
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

Frequently Asked Questions

How should this product be stored?

Store at 2–8 °C under argon. It is supplied under an argon blanket; reseal under inert gas after each use.

How is this product shipped?

This product ships chilled on wet ice. Unpack on arrival and transfer it to the storage condition stated above.

What are the CAS number, molecular formula and molecular weight?

The CAS Number is 865-34-9, the molecular formula is CH3OLi, and the molecular weight is 37.97 g/mol. InChIKey JILPJDVXYVTZDQ-UHFFFAOYSA-N.

What documentation is provided?

Available product documentation, including Certificates of Analysis (COA), Safety Data Sheets (SDS), and specification sheets, is shown in the product document area. Document availability and access follow the current site policy.